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61,005 resultsShowing papers similar to Effect of weathering on the release of secondary microplastic fragments and dissolved organics from microplastics
ClearElucidating the characteristic of leachates released from microplastics under different aging conditions: Perspectives of dissolved organic carbon fingerprints and nano-plastics
Researchers investigated how different aging conditions affect the release of dissolved organic carbon and nanoplastics from PVC and polystyrene microplastics over 130 days. The study found that UV aging and high temperatures promoted the release of nanoplastics and altered the chemical characteristics of leached substances, with UV-aged treatments producing smaller, rougher nanoparticles that may pose greater ecological risks.
Secondary microplastics formation and colonized microorganisms on the surface of conventional and degradable plastic granules during long-term UV aging in various environmental media
Researchers compared how biodegradable and conventional plastics generate secondary microplastics and develop bacterial biofilms during long-term UV aging. Biodegradable PBAT plastic produced significantly more secondary microplastic fragments than conventional PVC after 90 days of weathering. The study also found that aged microplastics harbored genes related to human pathogens, raising concerns that biodegradable plastics may actually pose greater ecological risks than expected.
Photochemical transformation of microplastics-derived dissolved organic matter altered the photoaging of microplastics
Researchers investigated how dissolved organic matter released from different microplastics (polystyrene, polyethylene, and biodegradable PBAT) affects the aging of polystyrene microplastics under UV irradiation, finding that PBAT-derived organic matter most strongly accelerated plastic photoaging.
The fate of microplastics in the environment: Systematic studies to determine release rates of secondary micro- and nanoplastics and water-soluble organics induced by photolysis and hydrolysis
Researchers conducted systematic studies on the photolytic and hydrolytic degradation of microplastics using three photolysis protocols and multiple polymer types to determine release rates of secondary micro- and nanoplastics and water-soluble organics, providing mechanistic data needed for environmental fate and risk assessment.
The fate of microplastics in the environment: Systematic studies to determine release rates of secondary micro- and nanoplastics and water-soluble organics induced by photolysis and hydrolysis
Researchers conducted systematic studies on the photolytic and hydrolytic degradation of microplastics using three photolysis protocols and multiple polymer types to determine release rates of secondary micro- and nanoplastics and water-soluble organics, providing mechanistic data needed for environmental fate and risk assessment.
Environmental Degradation and Fragmentation of Microplastics: Dependence on Polymer Type, Humidity, UV Dose and Temperature
A systematic study of UV dose, humidity, and temperature effects on six polymer types found that photo-oxidation is the primary driver of microplastic fragmentation and release of secondary nano-sized particles, with the relationship between weathering conditions and fragmentation rates varying by polymer type.
Environmental degradation and fragmentation of microplastics: dependence on polymer type, humidity, UV dose and temperature
Researchers systematically tested how UV light, temperature, and humidity cause five common plastic types to break apart into secondary microplastics and nanoplastics. They found that the type of plastic — not the aging conditions — was the main factor determining how quickly it fragmented and what byproducts it released, data that can improve models predicting how plastics break down in the environment.
NewInsights into the Long-Term Leaching Process ofDissolved Organic Matter from Microplastics: Dynamic Formation andTransformation Mechanism
Researchers studied the long-term photoaging process and dissolved organic matter (DOM) release from conventional polystyrene and biodegradable PBAT microplastics, finding distinct molecular transformation pathways for each polymer type. Biodegradable PBAT released more labile DOM that altered aquatic carbon cycling differently than conventional PS-derived DOM.
Abiotic degradation of PBAT and LDPE: quantification of generated products by carbon assessment
Researchers exposed industrial PBAT and LDPE plastic beads to UV radiation and water agitation to generate microplastics, nanoplastics, soluble compounds, and volatile products, then quantified all degradation products using total organic carbon analysis coupled with elemental analysis for a comprehensive carbon budget assessment. They found that PBAT degraded very differently from LDPE under abiotic conditions, with LDPE producing significantly more microplastics while PBAT's complete environmental behavior remains incompletely described despite its efficiency in industrial composting.
Emerging investigator series: microplastic-based leachate formation under UV irradiation: the extent, characteristics, and mechanisms
Six common microplastic types were exposed to UV irradiation to characterize surface changes and leachate chemical profiles, finding that UV treatment generated oxidized surface groups and released diverse organic compounds. Leachate composition varied by polymer type, highlighting the role of weathering in generating secondary chemical pollution from microplastics.
Physicochemical and biological ageing processes of (micro)plastics in the environment: a multi-tiered study on polyethylene
Researchers applied a multi-tiered approach combining laboratory aging, field deployment, and environmental simulation to study how polyethylene plastic undergoes physicochemical and biological weathering in natural settings. The study found that UV radiation and microbial colonization act synergistically to accelerate surface oxidation and fragmentation of PE into smaller particles.
Microplastic-DerivedCarbon Emissions: From GranularCarbon to Dissolved Organic Carbon and Carbon Dioxide under UltravioletRadiation
Researchers investigated microplastic-derived carbon emissions under ultraviolet radiation, tracking the transformation pathway from granular carbon to dissolved organic carbon and ultimately carbon dioxide, finding that UV aging drives significant carbon release from hydrocarbon polymer microplastics.
Linking UV aging of polymers and microplastics formation: An assessment employing various characterization techniques
Researchers examined the link between UV aging of plastic polymers and the generation of microplastics in marine environments, using environmental assessment tools to model the process. The study clarifies how photodegradation rates and polymer type influence the rate and quantity of microplastic formation.
Characterization of the degradation products of biodegradable and traditional plastics on UV irradiation and mechanical abrasion
Researchers compared how biodegradable plastic (PBAT/PLA) and traditional polyethylene break down under UV light and mechanical wear over nine months. The biodegradable plastic degraded faster but released more nanoplastics and dissolved molecules under UV light, while traditional plastic mainly produced larger microplastic fragments. This suggests that biodegradable plastics, while breaking down more quickly, may generate more of the smallest and potentially most harmful plastic particles.
Linking UV aging of polymers and microplastics formation: An assessment employing various characterization techniques
This study used environmental assessment tools to model how UV aging of plastic polymers drives microplastic formation in marine environments. The analysis identified polymer-specific degradation rates and environmental conditions that accelerate the conversion of plastic debris into microplastics.
Thermal oxidation, ultraviolet radiation, and mechanical abrasion - understanding mechanisms of microplastic generation and chemical transformation
Researchers evaluated how consumer-derived polymers fragment and chemically transform when exposed to UV radiation or thermal oxidation followed by soil abrasion. The study found that these combined weathering processes, which mimic real-world environmental conditions, significantly affect the rate and type of microplastic generation. The results highlight how everyday use and environmental exposure work together to break down plastics into microplastic particles.
Abiotic Long-Term Simulation of Microplastic Weathering Pathways under Different Aqueous Conditions
Laboratory weathering experiments simulated long-term microplastic degradation under UV, thermal, and mechanical stress to characterize how environmental exposure alters plastic surface chemistry, fragmentation, and additive release. The results provide insight into the formation pathways of secondary microplastics under realistic environmental conditions.
The importance of both physical aging and chemical weathering for the environmental fate of plastic
Researchers investigated the interplay between physical aging and chemical weathering in plastics and their combined effects on microplastic generation, finding that physical aging processes — distinct from photo-oxidation — play an underappreciated role in determining the environmental fate of plastic materials.
Molecular properties of dissolved organic matter leached from microplastics during photoaging process
Researchers studied the molecular properties of dissolved organic matter that leaches from polyethylene, polypropylene, and PET microplastics during UV-driven photoaging. They found that PET released the most dissolved organic carbon, and that aging transformed protein-like components into humic-like substances. The leachate contained antioxidants, plasticizers, and antimicrobial agents, suggesting that aging microplastics release a complex mix of chemicals into aquatic environments.
Contaminant release from aged microplastic
Researchers exposed recycled plastic granules of polyethylene, PVC, and polystyrene to simulated aging conditions including UV radiation and high temperatures. They found that aging significantly increased the rate at which chemical additives leached from the plastic particles into water, with UV exposure having the greatest effect. The study highlights that weathered microplastics in the environment may release harmful chemicals at much higher rates than fresh plastic materials.
Experimental parameterization of microplastic fragmentation and degradation to develop a mechanistic model of micro- and nanoplastic fragmentation in the environment
Researchers subjected seven plastic types (LDPE, PP, HIPS, PU, PET, PLA, and PA) to controlled UV irradiation and hydrolysis under varying temperature, humidity, salinity, and pH conditions, using multiple analytical methods including the NanoRelease/ISO22293 protocol, ATR-FTIR, TOC, GPC, and particle counting to quantify fragmentation rates from micro- to nanoscale. Preliminary results showed HIPS and LDPE fragmented most under UV stress, generating the largest counts of particles in the 1-2 µm size class, providing parameterization data for mechanistic models of environmental microplastic fragmentation.
New Insights into the Long-Term Leaching Process of Dissolved Organic Matter from Microplastics: Dynamic Formation and Transformation Mechanism
This study tracked how polystyrene and a biodegradable plastic (PBAT) release dissolved organic compounds as they age under ultraviolet light over 94 days. Polystyrene released chemicals much more slowly but with steadily increasing toxicity over time, while the biodegradable plastic released compounds faster but with less overall toxic buildup. These findings are important because they show that microplastics in the environment continuously leach potentially harmful chemicals, and so-called biodegradable plastics may not be as safe an alternative as assumed.
Progress on the photo aging mechanism of microplastics and related impact factors in water environment
This review examined the photo-aging mechanisms of microplastics in aquatic environments, finding that solar UV radiation drives oxidation reactions that alter surface chemistry, fragment particles further, and enhance their capacity to adsorb and release co-occurring pollutants.
Micro- and nanoplastics released from biodegradable and conventional plastics during degradation: Formation, aging factors, and toxicity
Researchers compared how biodegradable and conventional plastics break down into micro- and nanoplastics during degradation, testing the effects of UV light and mechanical forces. They found that biodegradable plastics like PLA and PBS can produce significant quantities of secondary microplastics, challenging the assumption that they are entirely safe alternatives. The study highlights the need for risk assessments of biodegradable plastics, particularly the tiny fragments generated as they break down.