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Contaminant release from aged microplastic
Summary
Researchers exposed recycled plastic granules of polyethylene, PVC, and polystyrene to simulated aging conditions including UV radiation and high temperatures. They found that aging significantly increased the rate at which chemical additives leached from the plastic particles into water, with UV exposure having the greatest effect. The study highlights that weathered microplastics in the environment may release harmful chemicals at much higher rates than fresh plastic materials.
Environmental context Increasing global plastic production adds plastic debris to the environment. We show that potentially harmful additives present in plastic particles are released to water at an increased rate when material properties change by aging due to exposure to high temperature and especially to UV radiation. For risk assessment of such plastic additives, more information on their degradation products and their toxicity is needed. Abstract Recycled plastic granules of high-density polyethylene, polyvinyl chloride and polystyrene the size of microplastics were exposed to artificial aging conditions (2000 h; photooxidative and thermo-oxidative) to simulate their fate outdoors. Their potential to leach into water during the aging process was investigated using column percolation tests. Aging-related changes on the surface of the material were characterised by IR measurements indicating oxidation reactions with the formation of new adsorption bands (C=O, C–O and OH), especially in the case of photooxidative aging. These findings were confirmed by the identification of leachable organic compounds. Leaching of total organic carbon, Cl, Ca, Cu and Zn is clearly affected by changes due to aging, and their release is increased after photooxidative aging. In general, exposure to photooxidative conditions shows a greater influence on aging and thus on leaching and seems to be the more important mechanism for the aging of microplastic in the environment. Comparison with the total content of inorganic species revealed that, for most elements, less than 3% of the total content is released after 2000 h of photooxidative aging.
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