Papers

61,005 results
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Article Tier 2

New insights into the photo-degraded polystyrene microplastic: Effect on the release of volatile organic compounds

Researchers investigated how ultraviolet light breaks down polystyrene microplastics and what volatile organic compounds are released during the process. They found that while the physical properties of the microplastics changed only slightly during UV exposure, the particles released a variety of potentially harmful volatile chemicals. The study provides new insights into the secondary pollution risks posed by microplastics as they degrade in the environment.

2022 Journal of Hazardous Materials 96 citations
Article Tier 2

Gaseous products generated from polyethylene and polyethylene terephthalate during ultraviolet irradiation: Mechanism, pathway and toxicological analyses

Researchers identified more than 50 different volatile organic compounds released from polyethylene and polyethylene terephthalate microplastics during ultraviolet irradiation in water. The study found that UV-C produced more gaseous byproducts than UV-A, and toxicological analysis suggested that some of these volatile compounds could pose risks to humans and the environment, highlighting an often-overlooked pathway of microplastic degradation.

2023 The Science of The Total Environment 22 citations
Article Tier 2

Releasing characteristics of toxic chemicals from polystyrene microplastics in the aqueous environment during photoaging process

This study revealed that as polystyrene microplastics age under UV light, they release a growing number of toxic chemicals including organic compounds and heavy metals into surrounding water. The rate of chemical release increased dramatically with aging time, meaning that weathered microplastics in the environment are more chemically hazardous than fresh ones, with implications for water quality and human exposure.

2024 Water Research 26 citations
Article Tier 2

Photoaging of Polyvinyl Chloride and Polystyrene Under UVA Radiation in Diverse Environmental Conditions

Researchers exposed polyvinyl chloride and polystyrene plastics to UVA radiation under diverse environmental conditions and tracked their photoaging and fragmentation, finding that UVA exposure accelerates microplastic generation in ways that vary with environmental context.

2025 University of Alberta Library
Article Tier 2

Volatile organic compounds generation pathways and mechanisms from microplastics in water: Ultraviolet, chlorine and ultraviolet/chlorine disinfection

Researchers examined how UV, chlorine, and combined UV/chlorine disinfection treatments cause microplastics to release volatile organic compounds, identifying distinct degradation pathways for polypropylene, polystyrene, and PVC that generate diverse chemical byproducts in treated water.

2022 Journal of Hazardous Materials 36 citations
Article Tier 2

Photoaging process and mechanism of four commonly commercial microplastics

Researchers exposed four common commercial microplastic types to UV light to simulate photoaging on soil surfaces and studied changes in their properties and chemical leachates. The study found that PVC and polystyrene underwent more dramatic physical and chemical changes than polypropylene and polyethylene, with aging creating cracks that facilitated the release of dissolved organic matter and chemical additives. These findings suggest that aged microplastics may pose greater environmental risks to soil and groundwater than pristine ones due to increased leaching of complex organic compounds.

2023 Journal of Hazardous Materials 110 citations
Article Tier 2

Plastic breeze: Volatile organic compounds (VOCs) emitted by degrading macro- and microplastics analyzed by selected ion flow-tube mass spectrometry

This study used mass spectrometry to analyze volatile organic compounds (VOCs) released by degrading macro- and microplastics of different polymer types, finding that weathered plastics emit a complex mixture of potentially toxic gases. Plastic pollution not only contaminates ecosystems through particles but also through the release of harmful chemical vapors as plastics age and break down.

2020 Chemosphere 55 citations
Article Tier 2

Molecular characteristics and plastic additives in dissolved organic matter derived from polystyrene microplastics: Effects of cumulative irradiation and microplastic concentrations

This study investigated how ultraviolet light breaks down polystyrene microplastics and releases dissolved organic matter, including plastic additives, into the surrounding water. Greater UV exposure produced more complex chemical mixtures with higher levels of potentially toxic compounds. The findings are important because sunlight-driven breakdown of microplastics in the environment may release harmful chemicals into water sources that people use for drinking and recreation.

2025 Water Research 23 citations
Article Tier 2

Elucidating the characteristic of leachates released from microplastics under different aging conditions: Perspectives of dissolved organic carbon fingerprints and nano-plastics

Researchers investigated how different aging conditions affect the release of dissolved organic carbon and nanoplastics from PVC and polystyrene microplastics over 130 days. The study found that UV aging and high temperatures promoted the release of nanoplastics and altered the chemical characteristics of leached substances, with UV-aged treatments producing smaller, rougher nanoparticles that may pose greater ecological risks.

2023 Water Research 76 citations
Article Tier 2

Linking UV aging of polymers and microplastics formation: An assessment employing various characterization techniques

Researchers examined the link between UV aging of plastic polymers and the generation of microplastics in marine environments, using environmental assessment tools to model the process. The study clarifies how photodegradation rates and polymer type influence the rate and quantity of microplastic formation.

2024 Zenodo (CERN European Organization for Nuclear Research)
Article Tier 2

Molecular-level insights into the heterogeneous variations and dynamic formation mechanism of leached dissolved organic matter during the photoaging of polystyrene microplastics

Researchers investigated the molecular-level changes that occur when polystyrene microplastics break down under light exposure and release dissolved organic matter into water. They found that the released molecules were highly diverse and changed dynamically over the course of aging, with different chemical classes appearing at different stages. The study provides new insight into how degrading microplastics introduce complex mixtures of organic chemicals into aquatic environments.

2023 Water Research 64 citations
Article Tier 2

Multi-Analytical Approach to Characterize the Degradation of Different Types of Microplastics: Identification and Quantification of Released Organic Compounds

Researchers studied how temperature and light exposure cause five common types of plastic to degrade and release organic chemical compounds. Using a solar simulation chamber, they tracked the breakdown products over time with multiple analytical techniques. The findings help identify which chemicals are released as plastics weather in the environment, which is important for understanding the secondary pollution caused by microplastic degradation.

2023 Molecules 35 citations
Article Tier 2

Contaminant release from aged microplastic

Researchers exposed recycled plastic granules of polyethylene, PVC, and polystyrene to simulated aging conditions including UV radiation and high temperatures. They found that aging significantly increased the rate at which chemical additives leached from the plastic particles into water, with UV exposure having the greatest effect. The study highlights that weathered microplastics in the environment may release harmful chemicals at much higher rates than fresh plastic materials.

2017 Environmental Chemistry 285 citations
Article Tier 2

Degradation of polypropylene : proportion of microplastics formed and assessment of their density.

Researchers quantified the proportion of microplastics generated during UV-driven degradation of polypropylene and assessed changes in chemical composition caused by photooxidation. The study found that UV exposure progressively fragments polypropylene and alters its surface chemistry, affecting subsequent environmental behavior and toxicity.

2024 Zenodo (CERN European Organization for Nuclear Research)
Article Tier 2

Influence of polystyrene microplastics on the volatilization, photodegradation and photoinduced toxicity of anthracene and pyrene in freshwater and artificial seawater

Researchers found that polystyrene microplastics altered the volatilization, photodegradation, and photoinduced toxicity of anthracene and pyrene in both freshwater and seawater, with effects varying by pollutant type and driven by changes in reactive oxygen species generation.

2021 The Science of The Total Environment 35 citations
Article Tier 2

Insight into chain scission and release profiles from photodegradation of polycarbonate microplastics

Researchers studied how sunlight breaks down polycarbonate microplastics in water and what chemicals are released in the process. The study found that UV exposure caused the plastics to fragment into smaller pieces while releasing bisphenol A (BPA) and other potentially harmful organic compounds. Importantly, BPA accounted for only a small fraction of the total chemicals released, suggesting that many unknown degradation products are also entering aquatic environments.

2021 Water Research 228 citations
Article Tier 2

Investigation of Surface Alteration of Microplastics by Using UV Irradiation

UV radiation causes polystyrene and other plastic microparticles to undergo photooxidative degradation, changing their surface chemistry and potentially making them more likely to adsorb or release chemical pollutants. Understanding these weathering processes is important for predicting the environmental behavior and toxicity of microplastics.

2020 4 citations
Article Tier 2

Analysis of ultraviolet and thermal degradations of four common microplastics and evidence of nanoparticle release

Researchers studied how UV light and elevated temperature break down four common plastics and found that weathering releases nanoscale plastic particles. Polystyrene and polypropylene were particularly susceptible to UV degradation, generating significant numbers of nanoparticles. The findings confirm that environmental conditions actively fragment microplastics into even smaller, potentially more harmful nanoplastics.

2023 Journal of Hazardous Materials Letters 49 citations
Article Tier 2

Characterization of microplastic-derived dissolved organic matter in freshwater: Effects of light irradiation and polymer types

Researchers examined how different types of microplastics release dissolved organic matter into freshwater under light and dark conditions. They found that polypropylene released the most organic compounds after UV exposure, while protein-like substances were the main material released by most plastics in the dark. The study indicates that microplastics may have ongoing, long-term effects on water chemistry and microbial activity in natural water bodies.

2024 Environment International 30 citations
Article Tier 2

Photolysis of microplastics under ultraviolet radiation : greenhouse gas emissions.

Researchers investigated the photodegradation of microplastics under UV radiation, measuring greenhouse gas emissions produced during polymer breakdown. The study found that microplastic photolysis releases carbon-based gases, adding a previously underappreciated contribution to atmospheric greenhouse gas budgets.

2024 Zenodo (CERN European Organization for Nuclear Research)
Article Tier 2

From Macro to Micro Plastics; Influence of Photo-oxidative Degradation

This study used simulated UV aging to investigate how photo-oxidative degradation of common plastics drives fragmentation from macro to micro scale, characterizing the surface property changes and structural breakdown that generate microplastic particles in the environment.

2023 Kemija u industriji 4 citations
Article Tier 2

A Review of Weathering Studies in Plastics and Biocomposites—Effects on Mechanical Properties and Emissions of Volatile Organic Compounds (VOCs)

This review summarizes how plastics and bio-based composite materials degrade when exposed to sunlight, heat, and moisture over time. Researchers found that weathering causes surface cracking, loss of strength, and release of volatile organic compounds, with different polymer types degrading through distinct chemical pathways. The study highlights that understanding these degradation processes is important for predicting the environmental impact and lifespan of both conventional and bio-based plastic materials.

2024 Polymers 34 citations
Article Tier 2

Photolysis of microplastics under ultraviolet radiation : greenhouse gas emissions.

Researchers investigated how ultraviolet radiation drives the photolytic degradation of microplastics ranging from 1 micron to 5 mm, measuring greenhouse gas emissions produced as plastics fragment and oxidize under UV exposure. Photolysis was shown to both fragment microplastics and release gases including methane and ethylene, linking plastic degradation to climate-relevant emissions.

2024 Zenodo (CERN European Organization for Nuclear Research)
Article Tier 2

Molecular fingerprints of dissolved organic matter leached from microplastics over prolonged photochemical aging: Implications for aquatic carbon cycling

Researchers used ultra-high-resolution mass spectrometry to identify the dissolved organic molecules that leach from polypropylene, polyethylene, and polystyrene microplastics after prolonged exposure to sunlight. They found that polystyrene released the most diverse array of molecules, many of which could persist in water systems. The study suggests that as microplastics degrade in sunlight, they release non-natural organic compounds that may affect the aquatic carbon cycle from rivers to oceans.

2025 Water Research 4 citations