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A Review of Weathering Studies in Plastics and Biocomposites—Effects on Mechanical Properties and Emissions of Volatile Organic Compounds (VOCs)

Polymers 2024 34 citations ? Citation count from OpenAlex, updated daily. May differ slightly from the publisher's own count. Score: 55 ? 0–100 AI score estimating relevance to the microplastics field. Papers below 30 are filtered from public browse.
Monwabisi Cyril Nzimande, Asanda Mtibe, Shepherd M. Tichapondwa, Maya Jacob John

Summary

This review summarizes how plastics and bio-based composite materials degrade when exposed to sunlight, heat, and moisture over time. Researchers found that weathering causes surface cracking, loss of strength, and release of volatile organic compounds, with different polymer types degrading through distinct chemical pathways. The study highlights that understanding these degradation processes is important for predicting the environmental impact and lifespan of both conventional and bio-based plastic materials.

Polymeric materials undergo degradation when exposed to outdoor conditions due to the synergistic effects of sunlight, air, heat, and moisture. The degradation can lead to a decline in mechanical properties, fading, surface cracking, and haziness, attributed to the cleavage of the polymer chains and oxidation reactions. Accelerated weathering testing is a useful technique to evaluate the comparative photodegradation of materials within a reasonable timeframe. This review gives an overview of the different degradation mechanisms occurring in conventional plastics and bio-based materials. Case studies on accelerated weathering and its effect on the mechanical properties of conventional plastics and biocomposites are discussed. Different techniques for analysing volatile organic emissions (VOCs) have been summarized and studies highlighting the characterization of VOCs from aged plastics and biocomposites after aging have been cited.

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