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61,005 resultsShowing papers similar to Sorption and bioacessibility of 17β-Estradiol on Environmental Microplastics: Particle Size, Aging, Competitive Interactions and Co-exposure
ClearHydrophobic sorption behaviors of 17β-Estradiol on environmental microplastics
Researchers studied the sorption behavior of the estrogen 17beta-estradiol onto five types of microplastics in marine water, finding hydrophobic interactions dominated and that microplastics could serve as vectors concentrating this endocrine disruptor.
Interfacial sorption of 17β-E2 on nano-microplastics: Effects of particle size, functional groups and hydrochemical conditions
This study examined how nanoscale polystyrene particles — a form of nanoplastic — bind to 17β-estradiol, a natural estrogen that is also an emerging environmental contaminant. Smaller particles adsorbed more of the hormone due to their larger surface area, and surface chemistry played a key role: hydrophobic (water-repelling) surfaces bound more estrogen than particles modified with polar chemical groups. The findings suggest that nanoplastics in water bodies could act as vectors, concentrating and transporting hormones to fish and other aquatic life, potentially amplifying endocrine disruption.
Adsorption and Desorption of Steroid Hormones by Microplastics in Seawater
Researchers evaluated the adsorption and desorption of the steroid hormones 17β-estradiol (E2) and 17α-ethynylestradiol (EE2) onto microplastics in seawater, finding that polymer type, particle size, salinity, pH, and humic acid concentration all influenced sorption behavior. The study provides mechanistic data relevant to assessing microplastics as vectors for endocrine-disrupting compounds in marine environments.
Sorption kinetics, isotherms and molecular dynamics simulation of 17β-estradiol onto microplastics
Researchers investigated the adsorption of the endocrine disruptor 17-beta-estradiol onto three common microplastics using kinetic experiments and molecular dynamics simulations, finding that hydrophobic interactions drive sorption and that polymer type significantly influences adsorption capacity.
Sorption of alkylphenols and estrogens on microplastics in marine conditions
Researchers investigated the sorption of six endocrine-disrupting chemicals — including alkylphenols and estrogens — onto microplastics under marine conditions, supporting the hypothesis that microplastics act as a secondary contamination vector for aquatic organisms by concentrating pollutants.
Potential Adsorption Affinity of Estrogens on LDPE and PET Microplastics Exposed to Wastewater Treatment Plant Effluents
Researchers investigated whether LDPE and PET microplastics recovered from wastewater treatment plant effluents can adsorb estrogen compounds, finding that these common plastic types bind endocrine-disrupting estrogens and may transport them through aquatic ecosystems.
Sorption of endocrine disrupting compounds onto polyamide microplastics under different environmental conditions: Behaviour and mechanism
Polyamide microplastics sorbed the synthetic estrogens EE2, E2, and estriol with affinity influenced by pH, ionic strength, and temperature, with sorption capacity decreasing under alkaline conditions that mimic some aquatic environments, suggesting that water chemistry governs how effectively polyamide MPs concentrate endocrine-disrupting compounds.
Influence of microplastics occurrence on the adsorption of 17β-estradiol in soil
Researchers investigated how the presence of microplastics in soil affects the adsorption behavior of the hormone 17-beta-estradiol. The study found that common greenhouse soil microplastics including polyethylene, polyvinyl chloride, and polystyrene influenced how estrogen compounds bind to soil, suggesting that microplastic contamination may alter the environmental fate of hormonal pollutants.
[Sorption Characteristics and Site Energy Distribution Theory of Typical Estrogens on Microplastics].
This study examined how polyethylene microplastics adsorb six types of estrogens — hormones that can disrupt reproduction and development in animals and humans. Researchers found that PE microplastics readily bind multiple estrogens, with adsorption behavior depending on estrogen structure and water chemistry. These findings confirm that microplastics can act as carriers for hormone-disrupting chemicals in the environment.
Adsorption of di (2-ethylhexyl) phthalate (DEHP) to microplastics in seawater: a comparison between pristine and aged particles
Natural aging of polyethylene and polystyrene microplastics in seawater over three months increased their adsorption capacity for the plasticizer DEHP compared to pristine particles, due to surface oxidation and biofilm formation. The results indicate that environmentally aged MPs are stronger vectors for hydrophobic contaminants than fresh MPs used in most laboratory studies.
Effect of aging on polyethylene microfiber surface properties and its consequence on adsorption characteristics of 17alpha-ethynylestradiol
Researchers found that aging alters the surface properties of polyethylene microfibers and changes their consequences for aquatic organisms. Weathered microfibers exhibited different surface chemistries and caused different biological effects compared to pristine fibers, highlighting the importance of considering plastic aging in environmental risk assessments.
Interactions between microplastics and phthalate esters as affected by microplastics characteristics and solution chemistry
The sorption of two phthalate esters onto polystyrene, polyethylene, and polypropylene microplastics was studied under varying conditions, finding that sorption was influenced by polymer type, phthalate structure, temperature, salinity, and dissolved organic matter. The results provide mechanistic insight into how microplastics accumulate endocrine-disrupting phthalates from the environment.
Insights into sorption and molecular transport of atrazine, testosterone, and progesterone onto polyamide microplastics in different aquatic matrices
This study measured the sorption of two hormones and the pesticide atrazine onto polyamide microplastics in different aquatic matrices including freshwater and seawater, finding that water composition significantly affected sorption kinetics and equilibrium, with implications for microplastic roles as contaminant carriers.
Mechanistic insights into the adsorption of endocrine disruptors onto polystyrene microplastics in water
Researchers studied the mechanisms by which polystyrene microplastics adsorb endocrine-disrupting compounds from aquatic environments, finding that hydrophobic interactions and surface chemistry govern the binding. The results clarify how microplastics act as vectors for co-transporting endocrine disruptors through aquatic ecosystems.
Adsorption of progesterone onto microplastics and its desorption in simulated gastric and intestinal fluids
Progesterone adsorbed readily to polyethylene, polypropylene, and polystyrene microplastics (up to 357 µg/g), and desorption experiments in simulated gastric and intestinal fluids showed substantial release under digestive conditions, suggesting a pathway for hormonal contaminant transfer via ingested MPs.
Adsorption behaviour and interaction of organic micropollutants with nano and microplastics – A review
This review analyzed the adsorption behavior of organic micropollutants — including pharmaceuticals, pesticides, and industrial chemicals — onto nano- and microplastics, finding that adsorption is governed by pollutant hydrophobicity, particle surface area, and aging state, and that microplastics can act as vectors delivering co-contaminants to aquatic organisms.
Studies on competitive adsorption characteristics of bisphenol A and 17α-ethinylestradiol on thermoplastic polyurethane by site energy distribution theory
This study examined how two common endocrine-disrupting chemicals — bisphenol A (BPA) and the synthetic hormone 17α-ethinylestradiol (EE2) — adsorb onto thermoplastic polyurethane microplastics in both single and mixed solutions, finding that BPA and EE2 compete for adsorption sites in ways that alter each compound's uptake. The findings matter because microplastics act as carriers for hazardous chemicals, and understanding competitive adsorption helps predict how contaminated plastics transport hormone-disrupting pollutants through aquatic environments.
Microplastics as potential bisphenol carriers: role of adsorbents, adsorbates, and environmental factors
Laboratory experiments showed that four common microplastic types — polystyrene, polypropylene, polyamide, and PVC — all readily adsorb bisphenols (BPA, BPB, BPF, BPS), with polyamide showing the highest capacity. Adsorption was strongly influenced by polymer surface chemistry, bisphenol hydrophobicity, temperature, and salinity. Because bisphenols are potent endocrine disruptors, microplastics acting as their environmental carriers could amplify human and wildlife exposure through contaminated seafood and drinking water.
Aging dominated effects of environmental microplastics on the sorption and toxic potential of typical pharmaceutical
This study examined how aging alters microplastic surface properties and their sorption of pharmaceuticals (including naproxen) and effects on aquatic toxicity. Aged MPs showed different sorption behavior and toxicity compared to pristine MPs, with aging-dominated effects shifting the risk profile of pharmaceutical-MP co-exposure.
Adsorption and Desorption Behaviour of Polychlorinated Biphenyls onto Microplastics’ Surfaces in Water/Sediment Systems
Researchers evaluated the adsorption and desorption behavior of polychlorinated biphenyls (PCBs) onto polystyrene, polyethylene, and polyethylene terephthalate microplastics of varying sizes in marine water/sediment systems. Results showed that polymer type and particle size influenced PCB binding capacity, with microplastics acting as potential vectors for transferring persistent organic pollutants to marine biota through the food chain.
A Comparison of the Adsorption Behavior of Bisphenol A by Microplastics From Different Sources
Lab experiments showed that UV weathering of four common microplastic types — PVC, polypropylene, polyethylene, and polyolefin resin — consistently increased their ability to adsorb the endocrine-disrupting chemical bisphenol A (BPA) by up to 19%, and in some cases changed the fundamental mechanism of adsorption. Acidic conditions and warmer temperatures amplified uptake, while higher plastic doses diluted it. Since weathered microplastics are what actually exist in the environment, these results suggest that aged particles are more potent BPA carriers than fresh plastic, worsening hormonal disruption risks in aquatic ecosystems.
Sorption of selected pharmaceutical compounds on polyethylene microplastics: Roles of pH, aging, and competitive sorption
Researchers found that polyethylene microplastics adsorb pharmaceutical compounds including an antibiotic, a beta-blocker, and an antidepressant, with sorption capacity influenced by pH, aging of the plastic, and competition between compounds — raising concern about microplastics as carriers of pharmaceuticals in aquatic environments.
Interactions of microplastics with contaminants in freshwater systems: a review of characteristics, bioaccessibility, and environmental factors affecting sorption
This review examined how microplastics act as vectors for environmental contaminants in freshwater systems, analyzing the characteristics, bioaccessibility, and environmental factors that influence pollutant sorption onto plastic particles and their potential transfer to organisms including humans.
Effect of microplastics on the environmental behavior of emerging contaminants in aquatic matrices
This study examines how microplastics affect the environmental behavior of emerging contaminants in aquatic systems. Microplastics can adsorb other pollutants and alter their bioavailability, potentially increasing or decreasing toxic effects depending on the chemicals and environmental conditions.