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61,005 resultsShowing papers similar to Interface behavior changes of weathered polystyrene with ciprofloxacin in seawater environment
ClearAdsorption characteristics of ciprofloxacin hydrochloride on polystyrene microplastics in freshwater
Researchers studied how polystyrene microplastics adsorb the antibiotic ciprofloxacin in freshwater, comparing pristine and aged particles. They found that aging treatment, particularly Fenton oxidation over seven days, significantly enhanced the adsorption capacity of the microplastics for the antibiotic. The study suggests that as microplastics weather in the environment, they may become increasingly effective carriers of pharmaceutical contaminants in water systems.
Adsorption-desorption behaviors of ciprofloxacin onto aged polystyrene fragments in aquatic environments
Researchers investigated how UV and chemical aging of polystyrene microplastic fragments affects their adsorption and desorption of the antibiotic ciprofloxacin in aquatic environments, finding that aging increased surface area and altered surface chemistry, thereby enhancing adsorption capacity. The study identified key physicochemical properties controlling antibiotic-microplastic interactions and their potential to affect antibiotic bioavailability in contaminated waters.
Tetracycline adsorption trajectories on aged polystyrene in a simulated aquatic environment: A mechanistic investigation
Researchers found that aging of polystyrene microplastics in simulated aquatic environments progressively altered their surface properties and enhanced tetracycline antibiotic adsorption over time, with pseudo-second-order kinetics best describing the process, highlighting how weathered microplastics may increase antibiotic transport in aquatic systems.
Adsorption of Macrolide Antibiotics by Aged Microplastics of Different Sizes: Mechanisms and Effects
Researchers investigated how aging affects the ability of polystyrene microplastics to adsorb macrolide antibiotics in water, testing two particle sizes under simulated natural aging conditions. They found that aging increased surface roughness and oxygen-containing functional groups on the microplastics, significantly enhancing their ability to adsorb azithromycin, clarithromycin, and erythromycin. The findings suggest that weathered microplastics in the environment may carry higher loads of antibiotic contaminants than pristine particles.
Behavior and mechanisms of ciprofloxacin adsorption on aged polylactic acid and polyethlene microplastics
Researchers investigated how aging affects the adsorption of the antibiotic ciprofloxacin on polylactic acid and polyethylene microplastics, finding that aged plastics showed significantly enhanced adsorption capacity due to physicochemical surface changes.
Enhanced adsorption of oxytetracycline to weathered microplastic polystyrene: Kinetics, isotherms and influencing factors
Researchers compared how weathered and new polystyrene foam particles absorb the antibiotic oxytetracycline from water. They found that beached foam that had been exposed to environmental conditions absorbed roughly twice as much of the drug as virgin material, due to increased surface area and chemical changes from weathering. The study suggests that aged microplastics in the environment are more effective at picking up and transporting pharmaceutical contaminants.
Effect of aging on adsorption behavior of polystyrene microplastics for pharmaceuticals: Adsorption mechanism and role of aging intermediates
Photo-Fenton-accelerated aging of polystyrene microplastics was found to shift the dominant adsorption mechanism for pharmaceuticals from hydrophobic/π-π interactions in pristine PS to electrostatic and hydrogen bonding in aged PS, while high concentrations of aging intermediates suppressed adsorption capacity. The study reveals how environmental weathering fundamentally changes how microplastics interact with pharmaceutical pollutants.
Sorption behavior and mechanism of hydrophilic organic chemicals to virgin and aged microplastics in freshwater and seawater
UV-accelerated aging of polystyrene and PVC microplastics increased surface oxidation and introduced microcracks, and aged MPs showed significantly increased adsorption of the hydrophilic antibiotic ciprofloxacin compared to virgin MPs. The findings demonstrate that even hydrophilic organic chemicals can accumulate on aged microplastics, expanding the range of compounds that microplastics may carry and deliver to organisms.
Enhanced biotoxicity by co-exposure of aged polystyrene and ciprofloxacin: the adsorption and its influence factors
This study found that polystyrene microplastics aged by sunlight absorbed significantly more of the antibiotic ciprofloxacin than fresh microplastics, and the combination was more toxic to organisms than either pollutant alone. The aging process created more surface area and chemical binding sites on the plastic particles. This is important because it means weathered microplastics in the real world can concentrate antibiotics and deliver higher toxic doses to organisms, potentially contributing to both direct toxicity and antibiotic resistance.
Impact of the hydrated functional zone on the adsorption of ciprofloxacin to microplastics under the influence of UV aging
Researchers investigated how UV aging of polyethylene and polystyrene microplastics affects their adsorption of the antibiotic ciprofloxacin, finding that UV-aged particles developed rougher surfaces with increased hydrophilicity due to the formation of a hydrated functional zone. Adsorption isotherm and kinetic modelling showed that this surface transformation significantly altered the binding capacity and mechanisms for ciprofloxacin, with pH also playing a key role in adsorption efficiency.
Quantitative assessment of interactions of hydrophilic organic contaminants with microplastics in natural water environment
Researchers quantified how microplastics interact with common antibiotic pollutants in natural water conditions, comparing virgin and environmentally aged polystyrene particles. They found that aged microplastics absorbed significantly more antibiotics than new ones due to increased surface area and chemical changes from weathering. The study suggests that as microplastics age in the environment, they become more effective at concentrating and transporting other harmful pollutants.
Behavior and mechanisms of ciprofloxacin adsorption on aged Polylactic Acid and Polyethylene microplastics
This study examined how aged polylactic acid (PLA) and polyethylene (PE) microplastics absorb the antibiotic ciprofloxacin in water. Aging changes the surface chemistry of microplastics, affecting how they pick up and carry antibiotics — which could deliver higher doses of these drugs to organisms that ingest the particles.
Sorption of antibiotics onto aged microplastics in freshwater and seawater
Aged microplastics were found to sorb antibiotics from fresh and saltwater, with aging processes altering the surface properties of the plastic and increasing antibiotic binding capacity in some cases. The adsorption of antibiotics onto aged microplastics could facilitate their transport and delivery to aquatic organisms, potentially contributing to antibiotic resistance in environmental bacteria.
New insights into adsorption mechanism of pristine and weathered polyamide microplastics towards hydrophilic organic compounds
Adsorption of four hydrophilic organic compounds including antibiotics sulfamethoxazole and ciprofloxacin onto pristine and weathered polyamide microplastics was studied, finding that weathering introduced oxygen-containing surface groups that significantly altered adsorption capacity and mechanisms. The results improve predictions of how microplastics transport co-occurring pollutants in aquatic environments.
Adsorption behavior of levofloxacin hydrochloride on non‐degradable microplastics aging with H 2 O 2
This study explored how microplastics act as carriers for the antibiotic levofloxacin in water, finding that chemically aged plastics (simulating environmental weathering) adsorb significantly more of the drug than fresh plastics. All three plastics tested — PVC, polystyrene, and PET — showed increased drug-binding capacity after aging, primarily through pore-filling. This matters because microplastics in rivers and lakes don't just pose a physical hazard; they can pick up and concentrate pharmaceutical contaminants, potentially delivering them to aquatic organisms at higher doses.
Aging of Polystyrene Micro/Nanoplastics Enhances Cephalosporin Phototransformation via Structure-Sensitive Interfacial Hydrogen Bonding
Researchers found that aged polystyrene micro and nanoplastics significantly speed up the breakdown of common antibiotics (cephalosporins) in water when exposed to sunlight. The aged plastic surfaces generate reactive chemicals that attack the antibiotics, and the effect depends on how the antibiotic molecule binds to the plastic surface. This is important because it shows microplastics can actively change the chemical environment around them, potentially affecting how pollutants behave in waterways.
Adsorption of levofloxacin by ultraviolet aging microplastics
Researchers studied how ultraviolet aging changes the ability of common microplastics to adsorb the antibiotic levofloxacin. The study found that UV-aged polystyrene, polyamide, and polyethylene microplastics all showed significantly enhanced adsorption capacity compared to their unaged counterparts, suggesting that weathered microplastics in the environment may carry higher pollutant loads.
Aging characteristics of degradable and non-biodegradable microplastics and their adsorption mechanism for sulfonamides
Researchers investigated how aging processes affect the ability of degradable and non-biodegradable microplastics to adsorb sulfonamide antibiotics in aquatic environments. The study found that aging increased the hydrophilicity and polarity of microplastics, boosting the adsorption capacity of polylactic acid by up to 3.18 times, suggesting that weathered microplastics may pose greater ecological risks as carriers of co-existing contaminants.
Photochemically induced aging of polystyrene nanoplastics and its impact on norfloxacin adsorption behavior
Researchers accelerated aging of polystyrene nanoplastics via photo-Fenton reactions and found that aging increases surface roughness, oxygen content, and specific surface area — boosting norfloxacin antibiotic adsorption by over fivefold compared to virgin particles and adding new polar interaction and pore-filling mechanisms.
The sorption behavior of triclosan on microplastics: aging effects and mechanisms
Researchers investigated how environmental aging processes change the ability of polyethylene, polypropylene, and polystyrene microplastics to absorb the antimicrobial compound triclosan. They found that aging increased sorption capacity for polyethylene but decreased it for polypropylene, with polystyrene showing mixed results depending on the aging method. The changes were driven by modifications to surface chemistry, particularly the introduction of oxygen-containing functional groups that alter hydrophobic and electrostatic interactions.
Impact of sequential UV-aging of microplastics on the fate of antibiotic (tetracycline) in riverine, estuarine, and marine systems
Researchers studied how sequential UV aging of polystyrene, polypropylene, and polyethylene microplastics, which mimics natural weathering, affects their ability to adsorb the antibiotic tetracycline under different water chemistry conditions. They found that aged microplastics adsorbed significantly more tetracycline than pristine particles, with the effect varying by water type and plastic polymer. The study suggests that as microplastics weather in the environment, they may become increasingly effective at carrying antibiotic contaminants.
Interactive effects of microplastics and selected pharmaceuticals on red tilapia: Role of microplastic aging
Researchers compared how aged versus virgin polystyrene microplastics interact with the antibiotic sulfamethoxazole and the beta-blocker propranolol in red tilapia. They found that aged microplastics, which have rougher surfaces from UV weathering, adsorbed more pharmaceuticals and altered their bioavailability to the fish. The study demonstrates that environmental aging of microplastics changes their capacity to carry and release pharmaceutical contaminants in aquatic systems.
Effect of polystyrene microplastics on the degradation of sulfamethazine: The role of persistent free radicals
Polystyrene microplastics exposed to photoaging generated persistent free radicals on their surfaces, which then accelerated the breakdown of the antibiotic sulfamethazine in surrounding water. The study identifies a previously underappreciated chemical interaction in which aged plastic particles can transform co-occurring pharmaceutical pollutants.
Insights into the interaction mechanism of ofloxacin and functionalized nano-polystyrene.
This study investigated how the antibiotic ofloxacin interacts with functionalized polystyrene nanoplastics, finding that surface charge and functional groups on the nanoplastics strongly influenced binding strength and mechanisms. The results improve understanding of how nanoplastics can act as carriers for antibiotics in the environment, potentially altering their fate and biological effects.