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Enhanced adsorption of oxytetracycline to weathered microplastic polystyrene: Kinetics, isotherms and influencing factors
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Researchers compared how weathered and new polystyrene foam particles absorb the antibiotic oxytetracycline from water. They found that beached foam that had been exposed to environmental conditions absorbed roughly twice as much of the drug as virgin material, due to increased surface area and chemical changes from weathering. The study suggests that aged microplastics in the environment are more effective at picking up and transporting pharmaceutical contaminants.
Microplastic polystyrene foam has been found widely in the environment and is readily transported by wind or water. Beached and virgin foams of size 0.45-1 mm were prepared as sorbents to study oxytetracycline sorption. Enhanced adsorption were found in the beached foams compared to the virgin foams, corresponding to the higher specific surface area, micropore area and the degree of oxidation of the former. The Freundlich K value was 894 ± 84 ((mg kg) (mg L)) for oxytetracycline adsorption on the beached foams, approximately twice as high as on the virgin foams. Effects of solution pH on adsorption to the beached foams were more pronounced to the virgin foams. Maximum adsorption occurred at pH 5 at which electrostatic repulsion between the microplastic surface and the oxytetracycline zwitterion was minimal, indicating that electrostatic interaction may have regulated adsorption. Moreover, H-bonding and multivalent cationic bridging mechanisms may also have affected the adsorption of oxytetracycline to the beached foams as reflected by the ionic effects. Adsorption was promoted more in the presence of humic acid than of fulvic acid, perhaps owing to π-π conjugation between the humic acid and the microplastic surface which led to enhanced electrostatic attraction for oxytetracycline. This study suggests that weathered polystyrene foams may act as carriers of antibiotics in the environment and their potential risks to ecosystem and human health merit further investigation.
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Researchers found that aging of polystyrene microplastics in simulated aquatic environments progressively altered their surface properties and enhanced tetracycline antibiotic adsorption over time, with pseudo-second-order kinetics best describing the process, highlighting how weathered microplastics may increase antibiotic transport in aquatic systems.
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Researchers quantified how microplastics interact with common antibiotic pollutants in natural water conditions, comparing virgin and environmentally aged polystyrene particles. They found that aged microplastics absorbed significantly more antibiotics than new ones due to increased surface area and chemical changes from weathering. The study suggests that as microplastics age in the environment, they become more effective at concentrating and transporting other harmful pollutants.
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Researchers investigated how UV and chemical aging of polystyrene microplastic fragments affects their adsorption and desorption of the antibiotic ciprofloxacin in aquatic environments, finding that aging increased surface area and altered surface chemistry, thereby enhancing adsorption capacity. The study identified key physicochemical properties controlling antibiotic-microplastic interactions and their potential to affect antibiotic bioavailability in contaminated waters.
Adsorption of Macrolide Antibiotics by Aged Microplastics of Different Sizes: Mechanisms and Effects
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Researchers investigated how aging affects the ability of polystyrene microplastics to adsorb macrolide antibiotics in water, testing two particle sizes under simulated natural aging conditions. They found that aging increased surface roughness and oxygen-containing functional groups on the microplastics, significantly enhancing their ability to adsorb azithromycin, clarithromycin, and erythromycin. The findings suggest that weathered microplastics in the environment may carry higher loads of antibiotic contaminants than pristine particles.
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Researchers studied how polystyrene microplastics adsorb the antibiotic ciprofloxacin in freshwater, comparing pristine and aged particles. They found that aging treatment, particularly Fenton oxidation over seven days, significantly enhanced the adsorption capacity of the microplastics for the antibiotic. The study suggests that as microplastics weather in the environment, they may become increasingly effective carriers of pharmaceutical contaminants in water systems.
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