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61,005 resultsShowing papers similar to Change in adsorption behavior of aquatic humic substances on microplastic through biotic and abiotic aging processes
ClearInteractions between polypropylene microplastics (PP-MPs) and humic acid influenced by aging of MPs
Researchers examined how aging affects polypropylene microplastic interactions with humic acid, finding that aged microplastics with increased surface oxygen groups showed stronger adsorption of humic acid compared to pristine particles, altering their environmental behavior.
Insights into the characteristics, adsorption and desorption behaviors of microplastics aged with or without fulvic acid
Researchers investigated how fulvic acid, a key component of dissolved organic matter, influences the aging, adsorption, and desorption behavior of microplastics under UV radiation, finding that water environmental factors significantly alter the surface properties and contaminant-binding capacity of aged microplastics.
UV aging induces colloidal-like behavior in microplastics, mediating contaminant fluxes across interfaces
Researchers showed that UV aging and mechanical stress transform polyethylene microplastics into reactive porous particles with colloidal behavior, developing surface oxidation, increased roughness, and trace metal accumulation — changes that alter how they transport contaminants across water-sediment interfaces.
Aging characteristics of polylatic acid microplastics and their adsorption on hydrophilic organic pollutants: mechanistic investigations and theoretical calculations
Researchers characterized how polylactic acid microplastics undergo UV and thermal aging in aquatic environments, finding that aging altered surface chemistry, increased hydrophilicity, and enhanced adsorption of heavy metal pollutants—raising concerns about aged biodegradable plastics as carriers of co-contaminants.
Aging of microplastics increases their adsorption affinity towards organic contaminants
Researchers found that microplastics that have been weathered by sunlight and environmental exposure absorb significantly more chemical pollutants than fresh microplastics, with up to a 4.7-fold increase in adsorption. Ultraviolet exposure changes the surface chemistry of the plastics, making them stickier for contaminants. This matters because most microplastics in nature are weathered, meaning they may be carrying more toxic chemicals into the food chain than laboratory studies using new plastics would suggest.
Laboratory simulation of microplastics weathering and its adsorption behaviors in an aqueous environment: A systematic review
UV photo-oxidation and physical abrasion are the most practical laboratory methods for simulating microplastic weathering; aging increases surface area and oxygen-containing functional groups, altering pollutant adsorption behavior and potentially increasing environmental risks.
Surface characteristics and adsorption properties of polypropylene microplastics by ultraviolet irradiation and natural aging
This study examined how aging and UV light change the surface properties of polypropylene microplastics and their ability to absorb other pollutants. UV-aged microplastics absorbed significantly more of a common dye pollutant, while naturally aged particles absorbed less due to biological film buildup. Understanding how microplastics change over time in the environment matters because aged particles may carry different levels of harmful chemicals than fresh ones.
The sorption behaviour of amine micropollutants on polyethylene microplastics – impact of aging and interactions with green seaweed
Researchers studied how long-term aging of polyethylene microplastics changes their ability to bind organic pollutants (amine micropollutants), and how interactions with green seaweed affect this process. Aged microplastics showed different sorption behavior than fresh ones, which has implications for how effectively they transport contaminants through aquatic food webs.
Photoaging mechanisms of microplastics mediated by dissolved organic matter in an iron-rich aquatic environment
Researchers investigated how dissolved organic matter and iron mediate the photoaging of PVC and PET microplastics, finding that humic acid and iron accelerate surface degradation and alter the environmental behavior and risks of aged microplastics.
The role of humic substances’ hydrophobicity in heterogeneous adsorption onto microplastics: Insights from two-dimensional correlation hydrophilic interaction chromatography
Researchers investigated how the hydrophobic properties of humic substances influence their adsorption onto pristine and aged polyethylene microplastics. Using chromatography techniques, they found that more hydrophobic humic molecules preferentially adsorb onto microplastics, with this trend being stronger for aged plastics and under acidic conditions. The study highlights the critical role of hydrophobicity in determining how natural organic matter interacts with microplastics in aquatic environments.
Aging mechanism of microplastics with UV irradiation and its effects on the adsorption of heavy metals
Researchers aged polystyrene microplastics using UV irradiation under three conditions (air, pure water, seawater) and found that aging changed surface chemistry and increased the microplastics' capacity to adsorb heavy metals, with seawater aging producing the most pronounced surface oxidation.
Induced aging, structural change, and adsorption behavior modifications of microplastics by microalgae
Researchers found that microalgal biofouling caused more significant aging and surface degradation of microplastics compared to river microbial biofouling over a 30-day period. The study suggests that algae-induced aging substantially enhances the ability of polyethylene and PVC microplastics to adsorb organic pollutants like bisphenol analogues, increasing their potential to transport contaminants in the environment.
Progress on the photo aging mechanism of microplastics and related impact factors in water environment
This review examined the photo-aging mechanisms of microplastics in aquatic environments, finding that solar UV radiation drives oxidation reactions that alter surface chemistry, fragment particles further, and enhance their capacity to adsorb and release co-occurring pollutants.
Influence of aging on the affinity between microplastics and organic contaminants
Researchers investigated how UV and UV+H2O2 aging affects the capacity of polystyrene microplastics to adsorb and release pesticides and other organic contaminants, finding that aging-induced surface changes significantly altered adsorption affinity and desorption behavior compared to unaged controls.
Process analysis of microplastic aging during the photochemical oxidation process and its effect on the adsorption behavior of dissolved organic matter
Accelerated UV/persulfate and UV/chlorine oxidation experiments showed that both processes aged microplastics in distinct ways — altering surface chemistry and morphology — which in turn changed how the MPs adsorb dissolved organic matter (DOM) from water. Because aged MPs in real environments bind organic contaminants differently than pristine plastics, these findings are essential for predicting the long-range transport and ecological risk of weathered microplastics in natural water systems.
Influencing Mechanisms of Exogenous and Endogenous Dissolved Organic Matter on the Adsorption of Tetracycline on UV ‐Light Aged Microplastics
Researchers investigated how humic acid and microplastic-derived dissolved organic matter (MP-DOM) influence tetracycline adsorption onto UV-aged polyethylene and polystyrene microplastics, finding that UV aging increased surface area and functional groups on the plastics while dissolved organic matter altered adsorption capacity through competitive and facilitative mechanisms.
Environmental behaviors of microplastics in aquatic systems: A systematic review on degradation, adsorption, toxicity and biofilm under aging conditions
Aging processes like UV irradiation and physical abrasion alter microplastic surface properties, increasing their capacity to adsorb environmental pollutants while also enhancing leaching of toxic additives like phthalates, collectively amplifying the environmental toxicity of weathered microplastics.
Effects of Weathering on Microplastic Dispersibility and Pollutant Uptake Capacity
This study examined how environmental weathering changes the surface properties of microplastics and their ability to absorb co-pollutants, finding that weathered MPs bind more contaminants than pristine particles due to surface oxidation and cracking. The results emphasize that the environmental fate and toxicity of microplastics change dynamically as they age in the environment.
Adsorption behaviors of microplastics from packaging materials subjected to ultraviolet irradiation and microbial colonization
Researchers studied how UV irradiation and microbial colonization alter the surface properties of microplastics from discarded packaging materials and their ability to adsorb pollutants. They found that aging processes changed surface chemistry and hydrophilicity, affecting how microplastics interact with contaminants like crystal violet dye through hydrogen bonding, electrostatic attraction, and hydrophobic interactions.
Sorption behavior and mechanism of hydrophilic organic chemicals to virgin and aged microplastics in freshwater and seawater
UV-accelerated aging of polystyrene and PVC microplastics increased surface oxidation and introduced microcracks, and aged MPs showed significantly increased adsorption of the hydrophilic antibiotic ciprofloxacin compared to virgin MPs. The findings demonstrate that even hydrophilic organic chemicals can accumulate on aged microplastics, expanding the range of compounds that microplastics may carry and deliver to organisms.
Multi-mechanistic adsorption of pharmaceuticals and personal care products on oxidized microplastics: Oxidation processes, mechanisms, and environmental implications
Researchers reviewed how weathering and oxidation change microplastic surfaces, making them better at absorbing pharmaceuticals and personal care product chemicals from water. The modified surfaces attract these contaminants through multiple chemical forces, meaning aged microplastics in the environment act as enhanced carriers for drug and cosmetic pollutants.
Microplastics and organic contaminants: Investigation of the sorption process on different polymer types
Researchers investigated sorption of organic contaminants onto microplastics collected from environmental samples, finding that real-world MPs had different sorption capacities than laboratory-prepared particles due to surface aging, biofouling, and co-sorption of natural organic matter.
The effects of environmental conditions on the enrichment of antibiotics on microplastics in simulated natural water column
Researchers investigated how environmental ageing conditions affect the ability of microplastics to adsorb the antibiotic tetracycline, finding that pH, ionic strength, and temperature had little effect, but humic acid significantly reduced adsorption capacity. The reduction was attributed to humic acid covering plastic surfaces, altering hydrophobicity, and competing for adsorption sites via electrostatic repulsion.
Untangling the role of biotic and abiotic ageing of various environmental plastics toward the sorption of metals
Using factorial experiments, researchers disentangled the contributions of UV weathering, microbial biofilm colonization, and their interaction to metal sorption onto five types of environmental plastic, finding that both biotic and abiotic aging independently and synergistically enhance metal binding to plastic surfaces.