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20 resultsShowing papers similar to Arsenic adsorption by carboxylate and amino modified polystyrene micro- and nanoplastics: kinetics and mechanisms
ClearAdsorption of arsenite to polystyrene microplastics in the presence of humus
Polystyrene microplastics adsorb arsenic more effectively when humic acid is present in the water, because the organic matter forms a coating on the plastic surface that attracts more arsenic ions. This finding suggests that microplastics can serve as vectors for the toxic metalloid arsenic in natural water environments.
As(III) adsorption onto different-sized polystyrene microplastic particles and its mechanism
Researchers studied how arsenic adsorbs onto polystyrene microplastic particles of different sizes prepared by ball milling. They found that smaller particles with greater surface area adsorbed more arsenic, with hydrogen bonding and electrostatic attraction driving the process. The study indicates that microplastics in the environment could serve as carriers for arsenic contamination, with adsorption influenced by pH, temperature, and the presence of other ions.
Polystyrene and low-density polyethylene pellets are less effective in arsenic adsorption than uncontaminated river sediment
Researchers found that polystyrene and low-density polyethylene microplastic pellets adsorb significantly less arsenic than natural river sediment, suggesting microplastics may actually reduce arsenic mobility when mixed with contaminated sediments.
[Adsorption Characteristics of Arsenic on UV-aged Polypropylene Microplastics in Aqueous Solution].
This study examined how UV weathering (aging) changes the ability of polypropylene microplastics to adsorb arsenic from water, finding that aged plastic had rougher surfaces and more oxygen-containing groups, which enhanced arsenic adsorption. Environmental factors like pH and dissolved organic matter also influenced how much arsenic stuck to the plastic. Because aged microplastics bind more arsenic, they could carry this toxic heavy metal into aquatic food webs more effectively than pristine plastic particles.
Interface adsorption characteristics of microplastics on multiple morphological arsenic compounds
Researchers studied how polystyrene and PET microplastics adsorb different forms of arsenic, a toxic element commonly found in contaminated water. They found that polystyrene had a much higher capacity to bind arsenic compounds than PET, and that the arsenic-loaded microplastics were more toxic to organisms than either pollutant alone. The study highlights that microplastics can act as carriers for toxic heavy metals, amplifying their environmental harm.
Effects of microplastic on arsenic accumulation in Chlamydomonas reinhardtii in a freshwater environment
Researchers found that polystyrene microplastics of two sizes disrupted phospholipid membrane structure in the microalga Chlamydomonas reinhardtii, reducing its ability to accumulate and detoxify arsenic in freshwater. Smaller 100 nm particles caused greater inhibition of arsenic uptake and the detoxification pathway than 5 µm particles, indicating that nanoplastic size amplifies toxicological impacts on arsenic biogeochemical cycling.
Toxicity effects of polystyrene nanoplastics and arsenite on Microcystis aeruginosa
Researchers studied how two types of polystyrene nanoplastics with different surface properties interact with arsenic to affect freshwater algae. They found that nanoplastics with a sulfonic acid surface modification caused more severe growth inhibition and metabolic disruption in the algae, while both types reduced arsenic uptake by the organisms. The study highlights that the specific surface chemistry of nanoplastics significantly influences their environmental toxicity.
Impact of Microplastics on the Fate and Behaviour of Arsenic in the Environment and Their Significance for Drinking Water Supply
This review highlights a largely overlooked problem: microplastics in the environment can adsorb arsenic — one of the world's most dangerous water contaminants — onto their surfaces and potentially transport it to new locations or make it harder to remove during drinking water treatment. The authors call for urgent research into how the presence of microplastics affects the performance of arsenic removal technologies, since both pollutants now co-occur in water sources globally.
The role of microplastics in altering arsenic fractionation and microbial community structures in arsenic-contaminated riverine sediments
The addition of microplastics to arsenic-contaminated riverine sediments altered arsenic fractionation and shifted microbial community structures, with biodegradable plastics producing different effects compared to conventional polymers. The study demonstrates that microplastics can modify the environmental behavior of co-existing toxic metals in sediment ecosystems.
The influence of humic and fulvic acids on polytetrafluoroethylene-adsorbed arsenic: a mechanistic study
Researchers investigated how PTFE microplastics adsorb arsenic in water in the presence of humic and fulvic acids, finding that humic acid forms π-complexes with PTFE that increase oxygen-bearing surface functional groups, substantially enhancing arsenic adsorption through hydrogen bonding and pore-filling mechanisms.
Adsorption of As(III) by microplastics coexisting with antibiotics
This study examined how microplastics absorb arsenic, a toxic metal, from water, especially when antibiotics are also present. Smaller and more aged microplastic particles absorbed more arsenic, and environmental factors like pH and dissolved organic matter significantly changed absorption rates. This is relevant to human health because microplastics in contaminated water can concentrate toxic metals like arsenic on their surface and potentially carry them into drinking water or the food chain.
Effect and mechanism of coexistence of microplastics on arsenate adsorption capacity in water
Researchers examined how the presence of microplastics affects the ability of different materials to adsorb arsenate from contaminated water. They found that microplastics can interfere with the adsorption process, particularly by competing for binding sites on adsorbent materials like ZIF-8. The study highlights that co-contamination of water with both microplastics and heavy metals may complicate pollution remediation efforts.
Regulatory mechanism of microplastics on arsenic bioavailability in a subtropical estuary, China
Researchers investigated the regulatory mechanisms by which microplastics influence arsenic bioavailability in sediments of the Min River estuary, a subtropical estuary in China, finding that microplastic pollution alters the dynamics of bioavailable arsenic through interactions with sediment geochemistry and microbial communities.
The adsorption of arsenic on micro- and nano-plastics intensifies the toxic effect on submerged macrophytes
Researchers investigated how arsenic adsorbs onto microplastics of varying types and sizes, and how those particles affect underwater plants. They found that nanoplastics increased arsenic absorption in aquatic macrophytes by 36-47%, causing more severe leaf damage and oxidative stress than either contaminant alone.
Nanoplastic stimulates metalloid leaching from historically contaminated soil via indirect displacement
Researchers found that negatively charged polystyrene nanoplastics unexpectedly enhanced arsenic leaching from historically contaminated soil by displacing arsenic from soil binding sites rather than through direct adsorption, challenging assumptions about nanoplastic contaminant co-transport.
Adsorption behavior of aniline pollutant on polystyrene microplastics
Researchers investigated how polystyrene microplastics adsorb the pollutant aniline in aquatic environments, finding that particle size, temperature, and solution chemistry significantly influence adsorption behavior, highlighting microplastics' role as carriers of toxic organic compounds.
Effects of polystyrene microplastics on the distribution behaviors and mechanisms of metalloid As(III) and As(V) on pipe scales in drinking water distribution systems
Researchers examined how polystyrene microplastics affect the distribution and adsorption mechanisms of arsenic species As(III) and As(V) onto pipe scales in drinking water distribution systems under varying water conditions. The study found that polystyrene microplastics competed with pipe scale surfaces for arsenic adsorption, altering the partitioning of metalloid contaminants and raising concerns about microplastic-mediated changes to drinking water quality.
Co-transport of arsenic and micro/nano-plastics in saturated soil
Column experiments found that 100 nm nanoplastic particles reduced arsenic transport in saturated sand by adsorbing arsenic ions, while 5 micron microplastics enhanced arsenic transport through electrostatic adsorption and pore plugging, demonstrating size-dependent and opposing effects of micro- and nanoplastics on co-contaminant mobility.
Polystyrene microplastic alters the redox state and arsenic metabolization in the freshwater bivalve Limnoperna fortunei
Researchers exposed the freshwater mussel Limnoperna fortunei to polystyrene microplastics in combination with arsenic, finding that microplastics altered the bivalve's redox state and interfered with arsenic metabolization pathways. The results suggest microplastics can impair an organism's ability to convert toxic forms of arsenic to less toxic metabolites, worsening arsenic toxicity.
Insight into interactions of polystyrene microplastics with different types and compositions of dissolved organic matter
Researchers investigated how polystyrene microplastics interact with different types of dissolved organic matter, finding that fulvic acid and humic acid adsorb onto microplastics through distinct mechanisms, which influences microplastic transport and transformation in the environment.