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61,005 resultsShowing papers similar to Characterization of the microplastic photoaging under the action of typical salt ions of biological nitrogen removal processes
ClearInorganic anions influenced the photoaging kinetics and mechanism of polystyrene microplastic under the simulated sunlight: Role of reactive radical species
Researchers found that common inorganic anions in natural water significantly influence the photoaging of polystyrene microplastics under sunlight, with nitrate and bicarbonate accelerating degradation while chloride and bromide had varying effects on aging mechanisms.
Photo aging of polyester microfiber in freshwater and seawater environments: kinetics, mechanisms, and influencing factors
UV aging of polyester (PET) microfibers accelerates faster in seawater than in freshwater, driven by reactive ions like nitrate, bromide, and chloride. This matters because faster aging in marine environments means PET microfibers — the most abundant microplastic in aquatic systems — break down more rapidly into smaller, potentially more bioavailable nanoplastic fragments in the ocean.
The fate, impacts and potential risks of photoaging process of the microplastics in the aqueous environment
This review examines how ultraviolet light from sunlight causes microplastics in water to age and change their physical and chemical properties, including surface texture, chemical structure, and water-repelling ability. Researchers found that photoaged microplastics become better at carrying other pollutants and may pose greater environmental risks than fresh plastics. The study highlights that aged microplastics can also increase biological toxicity and human exposure risks compared to their original form.
Elucidating the characteristic of leachates released from microplastics under different aging conditions: Perspectives of dissolved organic carbon fingerprints and nano-plastics
Researchers investigated how different aging conditions affect the release of dissolved organic carbon and nanoplastics from PVC and polystyrene microplastics over 130 days. The study found that UV aging and high temperatures promoted the release of nanoplastics and altered the chemical characteristics of leached substances, with UV-aged treatments producing smaller, rougher nanoparticles that may pose greater ecological risks.
The Aging Behavior of Polyvinyl Chloride Microplastics by UV/Sodium Percarbonate Oxidation: Efficiency and Mechanism
Researchers investigated how UV-activated sodium percarbonate breaks down PVC microplastics, finding effective dechlorination and fragmentation after 35 hours of treatment. The study identified hydroxyl and carbonate radicals as the primary agents driving the aging process, providing insights into how advanced oxidation could be used to treat microplastic-contaminated wastewater.
Progress on the photo aging mechanism of microplastics and related impact factors in water environment
This review examined the photo-aging mechanisms of microplastics in aquatic environments, finding that solar UV radiation drives oxidation reactions that alter surface chemistry, fragment particles further, and enhance their capacity to adsorb and release co-occurring pollutants.
Co-existing inorganic anions influenced the Norrish I and Norrish II type photoaging mechanism of biodegradable microplastics
Researchers studied how common inorganic anions like bromide, chloride, and nitrate influence the photoaging of biodegradable PBAT microplastics in aquatic environments. The study found that nitrate promoted degradation while other anions had varying effects, revealing that the breakdown of biodegradable plastics in natural waters is more complex than previously understood.
Non-Negligible Effects of UV Irradiation on Transformation and Environmental Risks of Microplastics in the Water Environment
This review examines how UV irradiation drives photoaging of microplastics in aquatic environments, altering their surface chemistry, mechanical properties, and adsorption capacity for co-pollutants, and thereby amplifying their ecotoxicological risks beyond those of virgin plastic particles.
Contaminant release from aged microplastic
Researchers exposed recycled plastic granules of polyethylene, PVC, and polystyrene to simulated aging conditions including UV radiation and high temperatures. They found that aging significantly increased the rate at which chemical additives leached from the plastic particles into water, with UV exposure having the greatest effect. The study highlights that weathered microplastics in the environment may release harmful chemicals at much higher rates than fresh plastic materials.
Photo-aging of polyvinyl chloride microplastic in the presence of natural organic acids
Researchers described a new photo-aging pathway for polyvinyl chloride microplastics in aquatic environments involving low-molecular-weight organic acids. The study found that natural organic acids and their iron complexes significantly accelerated the degradation of PVC microplastics under sunlight through hydroxyl radical generation, revealing how environmental conditions influence microplastic weathering.
Accelerated aging of polyvinyl chloride microplastics by UV irradiation: Aging characteristics, filtrate analysis, and adsorption behavior
Researchers systematically investigated how UV irradiation ages polyvinyl chloride microplastics, characterizing changes in their physical and chemical properties and the organic matter they release. The study established quantitative relationships between the degree of aging and the capacity of microplastics to adsorb environmental pollutants like malachite green and sulfamethoxazole, providing a tool for predicting contaminant accumulation on weathered microplastics in natural environments.
Wastewater preinteraction accelerates the photoaging of disposable box-derived polystyrene microplastics in water
Researchers found that pre-exposure of polystyrene microplastics to real wastewater significantly accelerated their subsequent photoaging under UV light — doubling oxidation rates — with fulvic acid identified as the primary wastewater constituent driving this enhancement.
Study on the photo-aging process and mechanism of polystyrene microplastics under different salinities mediated by humic acid
This study examined how sunlight breaks down polystyrene microplastics in water with different salt levels and dissolved organic matter. The combination of salt and humic acid accelerated the aging of microplastics, making them smaller and more chemically reactive. This matters because aged microplastics can more easily absorb toxic pollutants and are small enough to be taken up by organisms, increasing potential health risks.
Increased bio-toxicity of leachates from polyvinyl chloride microplastics during the photo-aging process in the presence of dissolved organic matter
Researchers investigated how photo-aging of polyvinyl chloride microplastics is affected by the presence of dissolved organic matter in surface waters. They found that humic acid, a common component of dissolved organic matter, enhanced the degradation of PVC microplastics under light exposure and significantly increased the toxicity of the resulting chemical leachates. The study highlights the importance of considering dissolved organic matter when assessing the ecological risks of microplastic pollution in natural waters.
Photoaging process and mechanism of four commonly commercial microplastics
Researchers exposed four common commercial microplastic types to UV light to simulate photoaging on soil surfaces and studied changes in their properties and chemical leachates. The study found that PVC and polystyrene underwent more dramatic physical and chemical changes than polypropylene and polyethylene, with aging creating cracks that facilitated the release of dissolved organic matter and chemical additives. These findings suggest that aged microplastics may pose greater environmental risks to soil and groundwater than pristine ones due to increased leaching of complex organic compounds.
Response of wastewater treatment performance and bacterial community to original and aged polyvinyl chloride microplastics in sequencing batch reactors
This study found that PVC microplastics, both fresh and aged, severely harmed wastewater treatment processes by reducing the removal of harmful chemicals like ammonia and organic pollutants. The microplastics shifted the bacterial communities in the treatment system, reducing helpful nitrogen-removing bacteria while promoting other types. This means microplastic contamination of wastewater plants could lead to poorer water treatment quality, allowing more pollutants to reach rivers and drinking water sources.
Molecular properties of dissolved organic matter leached from microplastics during photoaging process
Researchers studied the molecular properties of dissolved organic matter that leaches from polyethylene, polypropylene, and PET microplastics during UV-driven photoaging. They found that PET released the most dissolved organic carbon, and that aging transformed protein-like components into humic-like substances. The leachate contained antioxidants, plasticizers, and antimicrobial agents, suggesting that aging microplastics release a complex mix of chemicals into aquatic environments.
UV aging of microplastic polymers promotes their chemical transformation and byproduct formation upon chlorination
Researchers studied how UV aging of different microplastic polymers affects their behavior during water chlorination treatment. They found that UV aging significantly increased the reactivity of polyamide and polyester microplastics, promoting the release of harmful organic compounds and the formation of disinfection byproducts by more than 10-fold. The study reveals that weathered microplastics in drinking water systems may generate more toxic byproducts during standard chlorination than their pristine counterparts.
Effects of photochlorination on the physicochemical transformation of polystyrene nanoplastics: Mechanism and environmental fate
Researchers studied how sunlight combined with chlorine in water treatment changes the properties of polystyrene nanoplastics. They found that solar irradiation significantly accelerated the chemical breakdown of the nanoplastics, including surface oxidation and the release of organic compounds. The study reveals that nanoplastics leaving wastewater treatment plants undergo rapid transformation in the environment, which could alter both their fate and toxicity.
The aging behavior of polyvinyl chloride microplastics promoted by UV-activated persulfate process
Researchers investigated UV-activated persulfate as an accelerated aging process for PVC microplastics, finding significant dechlorination and surface changes that help predict long-term weathering behavior of microplastics in the environment.
Surface characteristics and adsorption properties of polypropylene microplastics by ultraviolet irradiation and natural aging
This study examined how aging and UV light change the surface properties of polypropylene microplastics and their ability to absorb other pollutants. UV-aged microplastics absorbed significantly more of a common dye pollutant, while naturally aged particles absorbed less due to biological film buildup. Understanding how microplastics change over time in the environment matters because aged particles may carry different levels of harmful chemicals than fresh ones.
The role of abiotic and biotic aging in the elimination of polyethylene microplastics by coagulation
This study investigated how the natural weathering and biological aging of polyethylene microplastics — through sunlight, temperature, mechanical wear, and bacterial biofilm formation — affects how well water treatment plants can remove them using a coagulation process. Biologically aged plastics coated with bacterial biofilm were removed most efficiently, reaching up to 67% removal compared to around 30% for fresh plastics. Understanding how aging changes microplastic behavior in treatment plants is important for improving removal strategies, since most real-world plastics entering water systems have already been weathered.
Study on the impact of photoaging on the generation of very small microplastics (MPs) and nanoplastics (NPs) and the wettability of plastic surface
Experiments using UV light to artificially age six common plastic types showed that sunlight (photoaging) accelerates the breakdown of plastics into very small microplastics and nanoplastics and makes plastic surfaces rougher and more chemically reactive. Understanding how different polymer structures respond to light aging is important for predicting which plastics will fragment fastest in the environment and generate the most hazardous small particles.
Photo-aging promotes the inhibitory effect of polystyrene microplastics on microbial reductive dechlorination of a polychlorinated biphenyl mixture (Aroclor 1260)
Researchers found that photo-aging of polystyrene microplastics enhances their inhibitory effect on microbial activity in the environment. UV weathering alters the surface chemistry of microplastics in ways that increase toxicity to microorganisms, with implications for nutrient cycling in plastic-contaminated ecosystems.