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61,005 resultsShowing papers similar to Impact of the hydrated functional zone on the adsorption of ciprofloxacin to microplastics under the influence of UV aging
ClearAdsorption performance and mechanisms of ciprofloxacin onto microplastics: effects of different textures and aging degrees.
Researchers examined ciprofloxacin adsorption onto pristine and UV-aged polypropylene, polyvinyl chloride, and polyamide 6 microplastics, finding that UV aging increased oxygen-containing surface functional groups and raised maximum adsorption capacity by up to 40%, with density functional theory calculations identifying hydrogen bonding, electrostatic attraction, and π interactions as primary binding mechanisms.
Adsorption-desorption behaviors of ciprofloxacin onto aged polystyrene fragments in aquatic environments
Researchers investigated how UV and chemical aging of polystyrene microplastic fragments affects their adsorption and desorption of the antibiotic ciprofloxacin in aquatic environments, finding that aging increased surface area and altered surface chemistry, thereby enhancing adsorption capacity. The study identified key physicochemical properties controlling antibiotic-microplastic interactions and their potential to affect antibiotic bioavailability in contaminated waters.
Behavior and mechanisms of ciprofloxacin adsorption on aged polylactic acid and polyethlene microplastics
Researchers investigated how aging affects the adsorption of the antibiotic ciprofloxacin on polylactic acid and polyethylene microplastics, finding that aged plastics showed significantly enhanced adsorption capacity due to physicochemical surface changes.
Adsorption of levofloxacin by ultraviolet aging microplastics
Researchers studied how ultraviolet aging changes the ability of common microplastics to adsorb the antibiotic levofloxacin. The study found that UV-aged polystyrene, polyamide, and polyethylene microplastics all showed significantly enhanced adsorption capacity compared to their unaged counterparts, suggesting that weathered microplastics in the environment may carry higher pollutant loads.
Adsorption of Macrolide Antibiotics by Aged Microplastics of Different Sizes: Mechanisms and Effects
Researchers investigated how aging affects the ability of polystyrene microplastics to adsorb macrolide antibiotics in water, testing two particle sizes under simulated natural aging conditions. They found that aging increased surface roughness and oxygen-containing functional groups on the microplastics, significantly enhancing their ability to adsorb azithromycin, clarithromycin, and erythromycin. The findings suggest that weathered microplastics in the environment may carry higher loads of antibiotic contaminants than pristine particles.
Adsorption characteristics of ciprofloxacin hydrochloride on polystyrene microplastics in freshwater
Researchers studied how polystyrene microplastics adsorb the antibiotic ciprofloxacin in freshwater, comparing pristine and aged particles. They found that aging treatment, particularly Fenton oxidation over seven days, significantly enhanced the adsorption capacity of the microplastics for the antibiotic. The study suggests that as microplastics weather in the environment, they may become increasingly effective carriers of pharmaceutical contaminants in water systems.
Behavior and mechanisms of ciprofloxacin adsorption on aged Polylactic Acid and Polyethylene microplastics
This study examined how aged polylactic acid (PLA) and polyethylene (PE) microplastics absorb the antibiotic ciprofloxacin in water. Aging changes the surface chemistry of microplastics, affecting how they pick up and carry antibiotics — which could deliver higher doses of these drugs to organisms that ingest the particles.
Reduced adsorption of norfloxacin on UV aging microplastics in anoxic environment
UV aging of four common microplastics (PS, PP, PA, PE) in anoxic conditions reduced their adsorption capacity for the antibiotic norfloxacin, with decreases attributed to reduced hydrophobicity and increased crystallinity, while adsorption capacity decreased with increasing temperature.
[Effect of Aging on Adsorption of Tetracycline by Microplastics and the Mechanisms].
Researchers aged polyethylene and polystyrene microplastics under UV-254 irradiation and analyzed changes in color, surface morphology, and functional groups, finding that UV aging altered the physical and chemical properties of both MPs and significantly affected their adsorption capacity and mechanism for the antibiotic tetracycline.
Tetracycline adsorption trajectories on aged polystyrene in a simulated aquatic environment: A mechanistic investigation
Researchers found that aging of polystyrene microplastics in simulated aquatic environments progressively altered their surface properties and enhanced tetracycline antibiotic adsorption over time, with pseudo-second-order kinetics best describing the process, highlighting how weathered microplastics may increase antibiotic transport in aquatic systems.
UV-induced aging creates adsorption hotspots: Oxygen-containing functional groups on nanoplastics dictate the adsorption behavior of ciprofloxacin
When nanoplastics are exposed to UV light, the resulting oxidized surface groups — especially carbonyl and carboxyl groups — dramatically increase their ability to adsorb the common antibiotic ciprofloxacin. This matters because aged nanoplastics in waterways can act as Trojan horses, concentrating antibiotics and potentially delivering them to organisms that ingest the particles.
Adsorption behavior of levofloxacin hydrochloride on non‐degradable microplastics aging with H 2 O 2
This study explored how microplastics act as carriers for the antibiotic levofloxacin in water, finding that chemically aged plastics (simulating environmental weathering) adsorb significantly more of the drug than fresh plastics. All three plastics tested — PVC, polystyrene, and PET — showed increased drug-binding capacity after aging, primarily through pore-filling. This matters because microplastics in rivers and lakes don't just pose a physical hazard; they can pick up and concentrate pharmaceutical contaminants, potentially delivering them to aquatic organisms at higher doses.
Sorption behavior and mechanism of hydrophilic organic chemicals to virgin and aged microplastics in freshwater and seawater
UV-accelerated aging of polystyrene and PVC microplastics increased surface oxidation and introduced microcracks, and aged MPs showed significantly increased adsorption of the hydrophilic antibiotic ciprofloxacin compared to virgin MPs. The findings demonstrate that even hydrophilic organic chemicals can accumulate on aged microplastics, expanding the range of compounds that microplastics may carry and deliver to organisms.
The sorption behavior of triclosan on microplastics: aging effects and mechanisms
Researchers investigated how environmental aging processes change the ability of polyethylene, polypropylene, and polystyrene microplastics to absorb the antimicrobial compound triclosan. They found that aging increased sorption capacity for polyethylene but decreased it for polypropylene, with polystyrene showing mixed results depending on the aging method. The changes were driven by modifications to surface chemistry, particularly the introduction of oxygen-containing functional groups that alter hydrophobic and electrostatic interactions.
Interface behavior changes of weathered polystyrene with ciprofloxacin in seawater environment
Polystyrene microplastics were artificially weathered using a Fenton oxidation method and their interactions with the antibiotic ciprofloxacin in seawater were characterized, showing that weathering altered surface chemistry and modified adsorption behavior. The study reveals that the aging state of microplastics significantly affects their interactions with co-occurring pharmaceutical pollutants.
Influencing Mechanisms of Exogenous and Endogenous Dissolved Organic Matter on the Adsorption of Tetracycline on UV ‐Light Aged Microplastics
Researchers investigated how humic acid and microplastic-derived dissolved organic matter (MP-DOM) influence tetracycline adsorption onto UV-aged polyethylene and polystyrene microplastics, finding that UV aging increased surface area and functional groups on the plastics while dissolved organic matter altered adsorption capacity through competitive and facilitative mechanisms.
Investigation on the adsorption and desorption behaviors of antibiotics by degradable MPs with or without UV ageing process
Scientists compared how original and UV-aged polylactic acid (PLA) — a biodegradable plastic — adsorbs and desorbs the antibiotics tetracycline and ciprofloxacin relative to PVC, finding that UV aging changed PLA's surface more dramatically and increased its capacity to carry and release these drugs.
New insights into adsorption mechanism of pristine and weathered polyamide microplastics towards hydrophilic organic compounds
Adsorption of four hydrophilic organic compounds including antibiotics sulfamethoxazole and ciprofloxacin onto pristine and weathered polyamide microplastics was studied, finding that weathering introduced oxygen-containing surface groups that significantly altered adsorption capacity and mechanisms. The results improve predictions of how microplastics transport co-occurring pollutants in aquatic environments.
Aging characteristics of degradable and non-biodegradable microplastics and their adsorption mechanism for sulfonamides
Researchers investigated how aging processes affect the ability of degradable and non-biodegradable microplastics to adsorb sulfonamide antibiotics in aquatic environments. The study found that aging increased the hydrophilicity and polarity of microplastics, boosting the adsorption capacity of polylactic acid by up to 3.18 times, suggesting that weathered microplastics may pose greater ecological risks as carriers of co-existing contaminants.
Effects of biofilm formation on triclosan adsorption by UV-aged and pristine polystyrene microplastics in aquatic environments
Researchers investigated how biofilm formation on UV-aged versus pristine polystyrene microplastics affected triclosan adsorption, finding that biofilm-colonized aged microplastics had altered surface properties that changed triclosan uptake compared to unaged particles.
Sorption of antibiotics onto aged microplastics in freshwater and seawater
Aged microplastics were found to sorb antibiotics from fresh and saltwater, with aging processes altering the surface properties of the plastic and increasing antibiotic binding capacity in some cases. The adsorption of antibiotics onto aged microplastics could facilitate their transport and delivery to aquatic organisms, potentially contributing to antibiotic resistance in environmental bacteria.
Impact of sequential UV-aging of microplastics on the fate of antibiotic (tetracycline) in riverine, estuarine, and marine systems
Researchers studied how sequential UV aging of polystyrene, polypropylene, and polyethylene microplastics, which mimics natural weathering, affects their ability to adsorb the antibiotic tetracycline under different water chemistry conditions. They found that aged microplastics adsorbed significantly more tetracycline than pristine particles, with the effect varying by water type and plastic polymer. The study suggests that as microplastics weather in the environment, they may become increasingly effective at carrying antibiotic contaminants.
Enhanced adsorption of oxytetracycline to weathered microplastic polystyrene: Kinetics, isotherms and influencing factors
Researchers compared how weathered and new polystyrene foam particles absorb the antibiotic oxytetracycline from water. They found that beached foam that had been exposed to environmental conditions absorbed roughly twice as much of the drug as virgin material, due to increased surface area and chemical changes from weathering. The study suggests that aged microplastics in the environment are more effective at picking up and transporting pharmaceutical contaminants.
Microplastic aging alters the adsorption-desorption behaviors of sulfamethoxazole in marine animals: A study in simulated biological liquids
Researchers tested how UV aging of polyhydroxyalkanoate (PHA) and polyethylene (PE) microplastics affects their adsorption and desorption of the antibiotic sulfamethoxazole in simulated fish intestinal and mammalian stomach fluids. Aging increased adsorption capacity for sulfamethoxazole, while desorption in digestive fluids was higher for aged PHA than aged PE, with implications for antibiotic bioavailability in organisms that ingest microplastics.