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61,005 resultsShowing papers similar to Abiotic degradation and accelerated ageing of microplastics from biodegradable and recycled materials in artificial seawater
ClearDegradation of polyethylene microplastics in seawater: Insights into the environmental degradation of polymers
Researchers studied how polyethylene microplastics degrade in artificial seawater and found that exposure led to surface oxidation, cracking, and fragmentation over time. The study suggests that environmental degradation of microplastics in marine settings may generate progressively smaller particles, including nanoplastics, while also releasing chemical additives into surrounding waters.
The fate of biodegradable polyesters in the marine environment
Researchers tracked the degradation of five biodegradable plastics in simulated marine environments over nearly a year, including materials like polylactic acid and polyhydroxybutyrate. While all materials showed signs of degradation such as surface cracking and weight loss from hydrolysis, they also released polymer fragments into surrounding sand, indicating that even biodegradable plastics can generate microplastic pollution. The findings suggest that labeling a plastic as biodegradable does not guarantee it will fully break down in ocean conditions.
Generation of biodegradable microplastics from commercially available PBAT and PLA-based plastic bags in water: Impacts of UVA and water medium
Researchers tested how commercially available biodegradable plastic bags made from PBAT and PLA degrade in water under UVA light and dark conditions over 12 weeks. They found that both materials degraded faster in pure water than seawater, and UVA light significantly accelerated breakdown, but neither fully decomposed. The study confirms that biodegradable plastics generate microplastic fragments during incomplete degradation in aquatic environments.
Photodegradation of biobased polymer blends in seawater: A major source of microplastics in the marine environment
Researchers investigated microplastic formation from the photodegradation of three biobased polymer blends -- non-biodegradable polyethylene/thermoplastic starch (PE/TPS) and polypropylene/thermoplastic starch (PP/TPS) blends, and biodegradable polylactic acid/thermoplastic starch (PLA/TPS) -- after exposure to seawater in simulated marine conditions. They found that photodegradation of these biobased blends generates microplastics and causes significant changes in physicochemical properties, identifying them as a potential source of marine microplastic pollution despite their eco-friendly positioning.
Degradation of Biodegradable Microplastics under Artificially Controlled Aging Conditions with UV Radiation
Researchers subjected biodegradable plastics to controlled UV aging and found that they fragmented into microplastics faster than conventional plastics under simulated outdoor conditions. Biodegradable plastics are promoted as an eco-friendly alternative, but this study shows they may actually create microplastic pollution more rapidly in real-world environments. The findings raise important questions about whether biodegradable plastics are a genuine solution to plastic pollution.
An In Situ Experiment to Evaluate the Aging and Degradation Phenomena Induced by Marine Environment Conditions on Commercial Plastic Granules
Researchers designed two experimental setups to monitor the aging and degradation of commercial plastic granules (HDPE, PP, PLA, and PBAT) in marine conditions over three years. The first six months of results showed measurable changes in plastic properties from exposure to seawater and beach conditions. The study provides real-world data on how different plastic types degrade in marine environments, with biodegradable plastics showing faster changes than conventional polymers.
Monitoring polymer degradation under different conditions in the marine environment
Researchers simulated four marine environmental conditions over one year and found that biobased plastics like polylactic acid degrade up to five times faster in seafloor sediment than in the water column, while conventional plastics showed little degradation difference across conditions.
The fate of microplastics in the environment: Systematic studies to determine release rates of secondary micro- and nanoplastics and water-soluble organics induced by photolysis and hydrolysis
Researchers conducted systematic studies on the photolytic and hydrolytic degradation of microplastics using three photolysis protocols and multiple polymer types to determine release rates of secondary micro- and nanoplastics and water-soluble organics, providing mechanistic data needed for environmental fate and risk assessment.
The fate of microplastics in the environment: Systematic studies to determine release rates of secondary micro- and nanoplastics and water-soluble organics induced by photolysis and hydrolysis
Researchers conducted systematic studies on the photolytic and hydrolytic degradation of microplastics using three photolysis protocols and multiple polymer types to determine release rates of secondary micro- and nanoplastics and water-soluble organics, providing mechanistic data needed for environmental fate and risk assessment.
Aging of plastics in aquatic environments: Pathways, environmental behavior, ecological impacts, analyses and quantifications
This review examines how plastics age and degrade in aquatic environments through photo-oxidation, mechanical abrasion, and biodegradation. Researchers discuss the physicochemical changes that occur in aging plastics and the release of potentially harmful oxidation products during degradation. The study suggests that understanding these complex aging dynamics is essential for assessing the environmental and ecological risks posed by microplastics.
Comprehensive Understanding on the Aging Process and Mechanism of Microplastics in the Sediment–Water Interface: Untangling the Role of Photoaging and Biodegradation
Researchers examined how microplastics break down at the boundary between water and sediment in coastal wetlands, comparing the roles of sunlight-driven aging and biological degradation. They found that photoaging was the dominant process, accounting for over 55% of surface changes, and that biodegradable plastics aged faster than conventional ones. The study provides important insights into how microplastics transform in real-world coastal environments.
Bioplastics in the Sea: Rapid In-Vitro Evaluation of Degradability and Persistence at Natural Temperatures
Researchers evaluated the marine degradability of multiple bioplastic materials at natural seawater temperatures, finding that most bioplastics persist in ocean environments rather than degrading quickly, challenging assumptions that bioplastics represent a straightforward solution to marine plastic pollution.
Influence of UV exposure time and simulated marine environment on different microplastic degradation
Researchers examined how UV radiation and saltwater conditions affect the degradation of polypropylene, polystyrene, and ethylene-vinyl acetate microplastics. The study found that each polymer type responded differently to photodegradation, with changes in surface properties, crystallinity, and chemical bond formation varying by material. Evidence indicates that saline marine conditions can intensify certain degradation processes, suggesting that multiple environmental factors must be considered when assessing microplastic breakdown.
Comprehensive assessment of photo-oxidative degradation and biofilm colonization on microplastic pellets in simulated marine environment
Researchers exposed polyethylene, polypropylene, and nylon-6 microplastics to artificial UV aging and chemical oxidation in seawater to study photo-oxidative degradation and subsequent biofilm colonization. Aging altered surface chemistry and enabled biofilm formation, with degradation rates and biofilm composition varying by polymer type.
Photo aging and fragmentation of polypropylene food packaging materials in artificial seawater
Photo-aging and fragmentation of two common polypropylene (PP) food packaging materials with different additive contents were studied under artificial accelerated weathering. Additive composition significantly influenced the rate of photochemical aging and fragmentation into microplastic particles, with implications for how packaging design affects microplastic generation in the marine environment.
Photo-Aging of Biodegradable Polylactic Acid Microplastics
Researchers investigated the photo-aging of polylactic acid (PLA) microplastics, finding that UV exposure caused fragmentation that increased total particle numbers while decreasing average particle size. The study provides quantitative data on how biodegradable PLA plastics generate secondary microplastics through photoaging, a previously poorly characterized degradation pathway for this widely used industrial bioplastic.
Aging behavior of biodegradable polylactic acid microplastics accelerated by UV/H2O2 processes
Researchers used UV and hydrogen peroxide to simulate environmental aging of biodegradable polylactic acid (PLA) microplastics, finding that PLA microplastics undergo significant surface and structural changes during weathering that alter their environmental behavior and persistence.
Decomposition and fragmentation of conventional and biobased plastic wastes in simulated and real aquatic systems
Researchers tracked the decomposition and fragmentation of conventional and biobased plastics in simulated and real aquatic environments over six months. They found that while biobased materials showed faster initial surface changes, all tested plastics eventually generated micro- and nanoplastic fragments in water. The study provides evidence that even plastics marketed as more environmentally friendly still contribute to microplastic pollution once they enter waterways.
Insights into the Characteristics, Adsorption, and Desorption Behaviors of Polylactic Acid Aged with or without Salinities
Researchers studied how salinity affects the aging process and pollutant adsorption behavior of polylactic acid (PLA) microplastics — a biodegradable plastic increasingly used as a conventional plastic substitute. Seawater aged PLA differently than freshwater, and aged particles adsorbed more contaminants than fresh ones. The study shows that even biodegradable plastics can become environmental pollutants through aging and contaminant accumulation.
Degradation and Fragmentation of Microplastics
This review examines the degradation and fragmentation mechanisms that generate secondary microplastics from ocean plastic debris, covering photo-oxidation chemistry, environmental weathering rates, and how different polymer types break down under marine conditions.
Biodegradable Plastics: Biodegradation Percentage and Potential Microplastic Contamination in Seawater
This study tested the biodegradation of several commercially available biodegradable plastics in seawater, finding that most broke down incompletely and could still generate microplastic fragments. The findings challenge marketing claims about biodegradable plastics and highlight the risk that these materials pose as microplastic sources in marine environments.
Photo aging of polyester microfiber in freshwater and seawater environments: kinetics, mechanisms, and influencing factors
UV aging of polyester (PET) microfibers accelerates faster in seawater than in freshwater, driven by reactive ions like nitrate, bromide, and chloride. This matters because faster aging in marine environments means PET microfibers — the most abundant microplastic in aquatic systems — break down more rapidly into smaller, potentially more bioavailable nanoplastic fragments in the ocean.
Insights into the photoaging behavior of biodegradable and nondegradable microplastics: Spectroscopic and molecular characteristics of dissolved organic matter release
Researchers compared how biodegradable and conventional microplastics break down under ultraviolet light and what dissolved substances they release. They found that biodegradable PLA microplastics released more protein-like organic matter during UV exposure than conventional polystyrene, and this matter was more readily used by microorganisms. The study suggests that biodegradable plastics, while designed to be better for the environment, may introduce different ecological risks as they break down.
Quantitative study of microplastic degradation in urban hydrosystems: Comparing in situ environmentally aged microplastics vs. artificially aged materials generated via accelerated photo-oxidation
Researchers compared how polyethylene microplastics degrade in real urban water environments versus under controlled laboratory UV exposure. They found that lab-aged plastics showed primarily physical and chemical changes from UV light, while microplastics collected from stormwater and sediments also showed signs of biological degradation and hydrolysis. The study demonstrates that artificial aging alone does not fully replicate the complex degradation processes microplastics undergo in actual urban water systems.