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61,005 resultsShowing papers similar to Adsorption of heavy metals by microplastics in aquatic environments: mechanism, multi-factor regulation and ecological risks
ClearAdsorption of heavy metals by biofilm-coated microplastics in aquatic environments: Mechanisms, isotherm and kinetic processes, and influencing factors
This review synthesizes research on how biofilms—microbial coatings that naturally form on microplastics in water—alter the particles' ability to absorb heavy metals like lead, copper, and cadmium, finding that biofilmed microplastics generally adsorb more metal than bare plastic and that electrostatic forces and surface complexation are the dominant mechanisms. This matters because microplastics coated in both biofilm and toxic metals may deliver a double dose of contamination to organisms that ingest them. The review identifies key gaps, including how competitive metal mixtures and shifting biofilm composition over time affect this combined pollution risk.
Microplastics as a vehicle of heavy metals in aquatic environments: A review of adsorption factors, mechanisms, and biological effects
This review summarizes how microplastics in water can absorb and carry toxic heavy metals like lead and cadmium, making them more dangerous to aquatic life than either pollutant alone. Environmental factors such as water acidity, salinity, and organic matter influence how much metal sticks to microplastic surfaces. Since contaminated seafood is a major source of human exposure, understanding these interactions is important for assessing health risks.
Adsorption behavior of UV aged microplastics on the heavy metals Pb(II) and Cu(II) in aqueous solutions
Researchers examined how UV aging affects the adsorption of lead and copper onto polypropylene, polyethylene, and polystyrene microplastics, finding that aging creates new oxidation functional groups that enhance heavy metal adsorption capacity.
Adsorption properties and mechanism of Cu(II) on virgin and aged microplastics in the aquatic environment
Researchers examined how UV aging changes the surface properties of polyamide and polylactic acid microplastics and affects their ability to adsorb copper ions in water. The study found that UV irradiation altered the physical and chemical characteristics of both plastic types, increasing their capacity to bind heavy metals. Evidence indicates that weathered microplastics may act as more effective carriers of heavy metal contaminants in aquatic environments compared to virgin plastics.
Adsorption Characteristics of Heavy Metals onto Functionalized Microplastics
This study tested how three types of functionalized microplastics—polyacrylate, biobased polyurethane, and petroleum-based polyurethane—absorb toxic heavy metals including lead, copper, and cadmium. Smaller particles and UV-weathered plastic showed higher adsorption, meaning aged microplastics in the environment can act as concentrated carriers of heavy metal contamination, amplifying ecological risk.
Study on the Adsorption Behavior and Mechanism of Heavy Metals in Aquatic Environment before and after the Aging of Typical Microplastics
Researchers investigated the adsorption behavior and mechanisms of heavy metals by typical microplastics before and after environmental aging, finding that aging significantly alters microplastics' surface properties and capacity to bind metals such as cadmium and lead in aquatic systems.
The evolving interface of aged microplastics and heavy metals: implications for environmental fate and toxicity
This review examined how microplastics interact with heavy metals in the environment, focusing on how plastics serve as carriers that increase metal mobility and bioavailability. Researchers found that factors like polymer aging, biofilm formation, and water chemistry significantly affect how efficiently microplastics absorb metals, and that the combined exposure creates compounded toxicity including oxidative stress and organ damage in organisms. The findings highlight the need for more research on the long-term and multigenerational effects of these combined pollutants.
Adsorption behavior of Cu(II) on UV-aged polyethylene terephthalate and polypropylene microplastics in aqueous solution
Researchers studied how UV aging changes the ability of PET and polypropylene microplastics to adsorb copper ions from water. UV exposure altered the surface properties of both plastics, increasing their capacity to bind heavy metals compared to pristine particles. The findings suggest that weathered microplastics in the environment may be more effective at concentrating toxic metals, potentially increasing ecological risks in contaminated waterways.
Adsorption properties and mechanism of Cu(Ⅱ) on virgin and aged microplastics in the aquatic environment
This study examined how UV aging of polyamide (PA) and polylactic acid (PLA) microplastics affects their ability to adsorb copper (Cu II) from water. UV aging increased surface area and altered surface chemistry, making aged microplastics better carriers of copper contamination — raising concerns that weathered plastics in the environment may concentrate and transport heavy metals more effectively than fresh plastics.
Interactions of microplastics with heavy metals in the aquatic environment: Mechanisms and mitigation
This review synthesized mechanisms of heavy metal adsorption onto microplastics in aquatic environments and evaluated strategies for removing both contaminants simultaneously. The authors found that temperature, salinity, and plastic surface aging govern metal binding, and identified hybrid adsorbent materials as the most promising approach for co-removal of metals and microplastics from water.
How aging microplastics influence heavy metal environmental fate and bioavailability: A systematic review
This systematic review found that environmental aging (UV, weathering) degrades microplastics into smaller particles with higher surface reactivity, increasing their capacity to adsorb heavy metals. These aged microplastic-heavy metal complexes bioaccumulate through the food chain, posing greater ecological and human health risks than either pollutant alone.
Adsorption behavior of heavy metals onto microplastics derived from conventional and biodegradable commercial plastic products
Researchers tested how well different types of microplastics, including both conventional and biodegradable plastics, absorb heavy metals like lead, nickel, copper, zinc, and cadmium from water. They found that all microplastic types could pick up significant amounts of heavy metals, with biodegradable plastics sometimes absorbing even more than conventional ones. This is concerning because microplastics carrying heavy metals could deliver a double dose of contamination to organisms that ingest them.
Adsorption of Cadmium, Copper and Lead on Polypropylene and Polyethylene Microplastics
This laboratory study measured how cadmium, copper, and lead adsorb onto polypropylene and polyethylene microplastic particles in seawater, finding that microplastics concentrate these toxic metals at levels well above surrounding water concentrations. The results reinforce concerns that microplastics act as carriers of heavy metal contamination in marine ecosystems.
Enhanced copper adsorption by polyamide and polylactic acid microplastics: The role of biofilm development and chemical aging
Researchers studied how chemical aging and biofilm growth on polyamide and polylactic acid microplastics changed their ability to absorb copper from water. Both processes significantly increased the surface area and chemical reactivity of the plastics, making them absorb substantially more copper than fresh microplastics. The study suggests that as microplastics age and develop biofilms in natural waterways, they become increasingly effective at concentrating heavy metals, potentially altering how these contaminants move through aquatic environments.
Effects of particle size and aging on heavy metal adsorption by polypropylene and polystyrene microplastics under varying environmental conditions
This study found that smaller and weathered microplastics absorb significantly more lead and copper from water than larger or newer particles. Since microplastics in the real world are constantly aging and breaking into smaller pieces, they may become increasingly effective at concentrating toxic metals that can then enter the food chain and potentially affect human health.
Adsorption behavior of organic pollutants and metals on micro/nanoplastics in the aquatic environment
This review examines how micro- and nanoplastics in aquatic environments adsorb organic pollutants and metals onto their surfaces, effectively acting as carriers for other contaminants. Researchers found that environmental factors like pH, salinity, and aging of the plastic significantly influence this sorption behavior. The findings raise concerns that microplastics may increase the bioavailability and toxicity of chemical pollutants in waterways.
Unraveling Complexation and Contaminant Vector Potential in Aged Polyamide-Heavy Metal Interactions
Researchers found that heat-aged polyamide microplastics exhibit enhanced adsorption capacity for cadmium and copper compared to virgin material, with copper showing higher adsorption efficiency due to its smaller hydrated ionic radius and strong coordination with oxygen- and nitrogen-containing surface groups on the aged polymer.
Adsorption of Pb(II) by UV-aged microplastics and cotransport in homogeneous and heterogeneous porous media
Researchers found that microplastics aged by UV sunlight are better at absorbing and carrying lead (a toxic heavy metal) through soil and water than fresh microplastics. The aging process changes the microplastic surface in ways that make it grab onto more lead, potentially spreading this toxic metal further through the environment. This is relevant to human health because aged microplastics in the real world may be transporting more heavy metals into water supplies and food-growing soil than previously thought.
Adsorption Behavior of Microplastics as a Carrier of Various Contaminants and Their Ecotoxicity in Aquatic Environment
This review examines how microplastics in aquatic environments act as "Trojan horse" carriers, adsorbing other pollutants (heavy metals, pesticides, pharmaceuticals) onto their surfaces through hydrophobic, electrostatic, and hydrogen-bond interactions. Co-exposure of microplastics plus adsorbed contaminants has been shown to amplify oxidative stress, reduce reproduction rates, and impair photosynthesis in aquatic organisms — suggesting the combined risk of microplastics plus hitchhiking chemicals is greater than either alone.
The interfacial interaction between typical microplastics and Pb2+ and their combined toxicity to Chlorella pyrenoidosa
Researchers found that microplastics in freshwater can absorb lead (a toxic heavy metal) onto their surfaces, especially after being weathered by UV light. When combined, the microplastics and lead were more toxic to freshwater algae than either pollutant alone, with PET plastic showing the highest capacity to bind lead. This means microplastics in rivers and lakes may concentrate heavy metals and deliver higher doses of toxins to aquatic life and potentially to people through the water supply.
Factors Affecting the Adsorption of Heavy Metals by Microplastics and Their Toxic Effects on Fish
This review examines how microplastics absorb heavy metals from water and how the combined pollution harms fish. Factors like water pH, temperature, and the age of the plastic all affect how much metal sticks to the surface. Since fish are a major protein source for humans, the combination of microplastics and heavy metals entering fish tissue is a potential pathway for these pollutants to reach people through their diet.
Insights into adsorption behavior and mechanism of Cu(II) onto biodegradable and conventional microplastics: Effect of aging process and environmental factors
Researchers compared how biodegradable and conventional microplastics adsorb copper ions from water, examining how aging processes and environmental factors influence this interaction. The study found that aged microplastics had a greater capacity to bind copper than fresh ones, suggesting that weathered plastic debris in the environment may serve as carriers for heavy metal contaminants.
Metals' Adsorption Onto Environmental Microplastics at Shoreline Sediments
Metal adsorption onto microplastics collected from shoreline environments was measured, revealing that weathered plastic particles accumulate heavy metals like lead, copper, and zinc. The results confirm that shoreline microplastics act as metal-enriched vectors that could pose risks to organisms ingesting them.
Study on Adsorption of Heavy Metals Cu and Zn by Microplastics Under Different Aged Factors
Researchers examined how aging of polyethylene microplastics under different conditions -- varying pH, dissolved organic matter, and hydrogen peroxide -- affects their adsorption of Cu and Zn, finding that H2O2-induced aging most strongly enhanced heavy metal sorption capacity.