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Amino–MIL-101(Fe)/Chitosan–Graphene Oxide Cross-Linked Nanocomposite for High-Performance Adsorptive Remediation of Wastewater Microplastics from Environmental Samples
Summary
This research documented plastic ingestion by shearwater seabirds, analyzing stomach contents to quantify plastic loads and identify polymer types. The study found widespread plastic consumption in shearwater populations, providing evidence of the pervasiveness of ocean plastic contamination in pelagic food webs.
One of the main sources of microplastic pollution in aquatic ecosystems is municipal wastewater, and preserving the ecological security of water depends on its effective removal. In this study, a potential multi-functionalized nanocomposite (NH2-MIL-101(Fe)/CS/GO), which consists of an iron-based metal–organic framework (NH2-MIL-101(Fe)) integrated with chitosan (CS) as a biopolymer matrix and graphene oxide (GO) as a conductive support, was exploited to enhance microplastic removal via different adsorptive hydrophilic/hydrophobic interactions. According to adsorption tests, the removal efficiencies of NH2-MIL-101(Fe)/CS/GO for polyethylene terephthalate (PET) and polystyrene (PS) microplastics (25–30 μm) were 93.8% and 89.7%, respectively, at pH 6.2 and for 40 min of contact time. Adsorption isotherms were well fitted to both the Langmuir and the Freundlich models, and the maximum adsorption capacities of PET and PS were 321.4 and 255.1 mg·g−1, respectively. The removal efficiency reached 92.5% after six cycles. The proposed MOF-based CS/GO nanocomposite provides an efficient and durable method of controlling microplastic contamination in urban wastewater. The developed multi-functionalized nanocomposite offers excellent electrostatic and hydrophobic synergy through a large surface area and π–π interactions for GO, positively charged CS, and a very high surface area with tunable porosity for the amino–MIL-101 (Fe) moiety. The proposed MOF-based nanocomposite provides an effective and persistent method of reducing microplastic contamination in constructed wetlands and water/wastewater treatment plants.