Adsorption properties and influencing factors of Cu(II) on polystyrene and polyethylene terephthalate microplastics in seawater

As an emerging contamination in the ocean, microplastics can act as effective vectors of pollutants, the ecological risks caused by the combined pollution of microplastics and other pollutants have attracted growing attention. In this work, Copper (Cu(II)) was chosen as the classic pollutant, polystyrene (PS) and polyethylene terephthalate (PET) pellets were used as the typical marine microplastics, the adsorption performance of Cu(II) on PS and PET beads was investigated by adsorption kinetics and isotherm experiments, and other influencing conditions, such as pH, salinity, coexisting heavy metals ions and aging treatment, were evaluated. The results indicated that the adsorption behavior of Cu(II) on PS and PET was spontaneous and endothermic in the simulated seawater environment, and the batch experimental data can be effectively described by pseudo-second-order model and Freundlich isothermal model. Besides, the adsorption capacity of microplastics for Cu(II) was the best at pH 7, the change of salinity had no obvious effect on the adsorption in the natural marine environment. Moreover, co-existence of lead (Pb(II)) exhibited evident impacts on Cu(II) sorption onto PS and PET, which confirmed the adsorption competition effect between them. Additionally, high temperature aging treatment of microplastics in different environments for different duration time could obviously affect the properties of microplastics. It was found that the microplastics after being exposed to high temperature environment in the air for 168 h showed relatively stronger adsorption amount for Cu(II). In summary, these findings suggested that electrostatic interaction and distributed diffusion mechanisms may be the main mechanisms of adsorption, while no new functional groups were generated after the adsorption, indicating that physisorption may dominate the adsorption performance of PS and PET pellets for Cu(II). This study provides supplementary insights into the role of microplastics as carriers of heavy metals in the marine environment.