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Fracture test to accelerate the prediction of polymer embrittlement during aging – Case of PET hydrolysis

Polymer Degradation and Stability 2022 16 citations

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This study is actually about materials science, not direct human health research, it's focused on how PET plastic (used in water bottles and food packaging) breaks down and becomes brittle over time when exposed to moisture and heat. The researchers developed a faster testing method to predict when this plastic degradation happens, which matters because brittle, degrading plastic is more likely to crack, flake, and shed microplastic particles into food, water, or the environment. While this paper doesn't test human health effects directly, better tools for predicting plastic breakdown could help manufacturers design more durable products and identify when packaging might start releasing more microplastics.

Polymers

Depending on the nature of a given polymer and the environment, the rate of degradation can vary significantly, from a few hours up to tens of decades. In the polymer aging community, it is therefore a true challenge to obtain an understanding of the loss in properties of a given polymer within a reasonable time frame. The present work presents a novel approach to decrease that time. Within this study the decrease in mechanical properties of the polyethylene terephthalate under hydrolysis process has been followed via the Essential Work of Fracture method (EWF-m) and compared to the more classical tensile test. The degradation has been accelerated by increasing temperature, (from 60 °C up to 110 °C). Results show a rapid decrease in the non-essential work of fracture compared to the maximal stress at break obtained by tensile test. It appears that fracture properties can be used for both time/temperature superposition as well as the determination of the critical molar mass. Moreover, as fracture properties are very sensitive to degradation, it appears that it is possible to decrease aging time/temperature using EWF.

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