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Article Tier 2 Detection Methods Environmental Sources Marine & Wildlife Nanoplastics Sign in to save

Nanoplastics and ultrafine microplastic in the Dutch Wadden Sea – The hidden plastics debris?

The Science of The Total Environment 2022 117 citations

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Researchers applied a novel analytical method to detect nanoplastics and ultrafine microplastics smaller than 10 micrometers in Dutch Wadden Sea sediments, revealing a previously hidden fraction of plastic debris that conventional methods miss.

Study Type Environmental

Plastic pollution in the marine environment has been identified as a global problem; different polymer types and fragment sizes have been detected across all marine regions, from sea ice to the equator and the surface to the deep sea. However, quantification of marine plastics debris in the size range of nanoplastics (<1 μm) and ultrafine microplastics (<10 μm) is not constrained, because such minuscule particles are challenging to measure. In this work, we applied a novel analytical assay using Thermal Desorption - Proton Transfer Reaction - Mass Spectrometry (TD-PTR-MS), which is suitable to detect and identify plastics in the nanogram range. From two stations in the Wadden Sea (the Netherlands), we measured nanoplastics directly from seawater aliquots, and from filters with different mesh sizes. Our results show the presence of Polystyrene (PS) and Polyethylene terephthalate (PET) nanopalstics as well as ultrafine microplastics in the Wadden Sea water column. The mass concentration of PS nanoplastics was 4.2 μg/L on average, indicating a substantial contribution of nanoplastics to the Wadden Sea's total plastic budget.

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