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Surface-enhanced Raman spectroscopy for the detection of microplastics

Applied Surface Science 2022 140 citations ? Citation count from OpenAlex, updated daily. May differ slightly from the publisher's own count. Score: 50 ? 0–100 AI score estimating relevance to the microplastics field. Papers below 30 are filtered from public browse.
Lara Mikac, István Rigó, L. Himics, Ana Tolić, Mile Ivanda, M. Vereš

Summary

Researchers developed a surface-enhanced Raman spectroscopy method using gold nanoparticles to detect polystyrene microplastics at concentrations as low as 6.5 micrograms per milliliter, offering a new tool for detecting sub-micron plastic pollutants in water.

Polymers

Detection of microplastics is still challenging due to limitations of current methods, instrumentation, and particle size. In this work, surface-enhanced Raman spectroscopy (SERS) was used to detect polystyrene (PS, 350 nm) and polyethylene (PE, 1–4 µm) particles in pure water. Gold nanoparticles (Au NPs) of four different sizes were synthesized, characterized, and used as SERS active substrate for microplastic detection. The Au NPs obtained had a spherical shape with diameters of 33.2, 67.5, and 93.7 nm and an elliptical shape with shorter and longer diameters (nanorods) of 23.5 and 35.5 nm, respectively. The optimal conditions (volume ratio of sample to gold colloid, aggregating agent and its concentration) were determined. The efficient and stable SERS signals were observed on the PS microparticles, while the PE signal was difficult to obtain. The developed SERS method allows the detection of polystyrene microparticles at concentrations as low as 6.5 μg mL−1. The described method can be a useful tool for the detection of microplastic pollutants of this particular size.

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