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Effect of Fe and Al based coagulants and disinfectants on polyethylene microplastics removal in coagulation process through response surface methodology
Summary
Researchers optimized polyethylene microplastic (PEMP) removal from drinking water using response surface methodology (RSM) with Box-Behnken Design, testing pH, PEMP size, coagulant dosage, and polyacrylamide dosage as independent variables. Comparing ferric chloride and poly aluminum chloride as coagulants, they identified optimal conditions for maximizing PEMP removal efficiency, providing guidance for improving microplastic removal at drinking water treatment plants.
Microplastic (MP) pollution has been rising as a threatening risk and recently has appealed to the attention of more researchers. In this study, influential parameters affecting the removal rate of polyethylene microplastics (PEMPs) were optimized through response surface methodology (RSM). In Box Behnken Design (BBD), independent parameters were pH, PEMP size, coagulant dosage and polyacrylamide dosage. Two experimental sets were conducted, one with ferric chloride and the second with poly aluminum chloride as two commonly applied coagulants in drinking water treatment plants (DWTPs). Comparing the results of optimized parameters, PAC was a better coagulant with the predicted removal rate of 58.19%, while the removal rate with ferric chloride as a coagulant was predicted to be 56.37%. Moreover, some experiments were conducted to analyze the effect of ozone gas and sodium hypochlorite as disinfectants on removal rate. The highest removal rate was observed when 2 ppm of O3 was added to the solution coagulated with optimal dosage of PAC, reaching the removal rate of 76.8%.