Optimization of polypropylene microplastics removal using conventional coagulants in drinking water treatment plants via response surface methodology

BACKGROUND AND PURPOSE: The ubiquitous presence of microplastics (MPs) in aquatic environments has been studied widely. Due to toxicological impacts of MPs and associated contaminants, it is crucial to understand the performance of MPs removal in drinking water treatment plants (DWTPs). Few studies have investigated removal characteristics of MPs via coagulation/flocculation processes, yet removal characterization of polypropylene microplastics (PPMPs) in this process is poorly understood. This study aims to optimize coagulation of virgin PPMPs in conventional DWTPs. METHODS: In this study, samples were synthesized through response surface methodology (RSM), polyaluminium chloride (PACl) was applied as a conventional coagulant to remove PPMPs in the coagulation/flocculation process, which has the least density among common polymers and is one of the most abundant manufactured polymers worldwide. A particle size analyzer (PSA) was used to measure floc size at different pH levels. Additionally, a zeta potential analyzer was used to measure stability of the flocs at different pH. RESULTS: Base on the experimental range in Design-Expert, results revealed that the optimum removal rate was predicted to be at pH 9, PACl concentration of 200 ppm, polyacrylamide (PAM) concentration of 21 ppm, and PPMPs size of d < 0.25 mm. According to the predicted optimum condition, actual and predicted removal rates were 18.00 ± 1.43% and 19.69%, respectively. CONCLUSION: According to this study, PACl is not capable of efficiently removing virgin PPMPs in DWTPs, thereby exposing humans to eco-toxicological impacts of PPMPs through tap water.