We can't find the internet
Attempting to reconnect
Something went wrong!
Hang in there while we get back on track
Adsorption of metals on aged microplastics in intensive mariculture areas: Aggravating the potential ecological risks to marine organisms
Summary
Researchers used passive samplers in a subtropical mariculture area in China to measure how aged microplastics adsorb metals like iron, manganese, copper, and lead from seawater. They found that PVC microplastics had the highest metal adsorption capacity, and that aging increased the plastics' ability to accumulate metals on their surfaces. The findings suggest that weathered microplastics in aquaculture zones may concentrate toxic metals and pose elevated ecological risks to marine organisms.
Field determination of the metal adsorption capacity of microplastics (MPs) by using a passive sampler had been done in typical subtropical mariculture area in China. The adsorption of eight metals (Fe, Mn, Cu, Zn, As, Pb, Cr and Cd) by five types of MPs (low-density polyethylene, polypropylene, polystyrene, poly(ethylene terephthalate) and poly(vinyl chloride) (PVC) was compared, including metal types, mariculture types (cage and longline culture), metal residue content in ambient environment, polymer types and particle sizes of MPs. The results showed that Cu, Zn, As, Cd, Pb and Cr in the mariculture environment were contaminated compared with the quality criteria. The concentrations of these six metals adsorbed on five MPs increased linearly with those in seawater. More enriched Cu and As in MPs in marine cage culture than in longline culture, due to the obvious endogenous pollution emissions for the artificial diets, fish medicine and disinfectants. Aged PVC with more cracks and pores showed higher metal adsorption capacity than any other polymers. MPs with a smaller size range of 50-74 μm tended to accumulate higher amounts of metals than those with a larger size range of 74-178 μm, consisting with the surface characteristics of MPs. The significant positive relationship between the concentrations of nutrients in seawater and the adsorption amounts of Cu, Zn and As on MPs implies that the eutrophication would promote their pollution. Based on the ecological risk assessment, the occurrence of MPs could aggravate the potential risk of metals to marine organisms in intensive mariculture areas. This is the first time to reveal the impacts of the adsorption of metals on aged MPs on the potential ecological risks of metals to organisms under the realistic environmental condition.
Sign in to start a discussion.
More Papers Like This
Study on the capability and characteristics of heavy metals enriched on microplastics in marine environment
Laboratory and field experiments examined heavy metal adsorption on five plastic types (PVC, PP, PE, PA, POM), finding that PVC and PP had the highest adsorption capacity for lead and manganese, with field results showing that PP adsorbed metals at concentrations orders of magnitude higher than co-adsorbed PAHs. The study provides direct comparative data on microplastic-metal interactions across polymer types in marine environments.
Study on the Adsorption Behavior and Mechanism of Heavy Metals in Aquatic Environment before and after the Aging of Typical Microplastics
Researchers investigated the adsorption behavior and mechanisms of heavy metals by typical microplastics before and after environmental aging, finding that aging significantly alters microplastics' surface properties and capacity to bind metals such as cadmium and lead in aquatic systems.
Metals' Adsorption Onto Environmental Microplastics at Shoreline Sediments
Metal adsorption onto microplastics collected from shoreline environments was measured, revealing that weathered plastic particles accumulate heavy metals like lead, copper, and zinc. The results confirm that shoreline microplastics act as metal-enriched vectors that could pose risks to organisms ingesting them.
Metal adsorption by microplastics in aquatic environments under controlled conditions: exposure time, pH and salinity
Scientists systematically varied pH, salinity, and exposure time during metal adsorption experiments on different microplastic types, finding that pH had the greatest influence on metal uptake, with higher pH favoring adsorption of copper, lead, and cadmium onto most tested polymers.
How aging microplastics influence heavy metal environmental fate and bioavailability: A systematic review
This systematic review found that environmental aging (UV, weathering) degrades microplastics into smaller particles with higher surface reactivity, increasing their capacity to adsorb heavy metals. These aged microplastic-heavy metal complexes bioaccumulate through the food chain, posing greater ecological and human health risks than either pollutant alone.