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Biodegradable taro stem cellulose aerogel: A simple approach for adsorbing microplastics and dyestuffs contaminants
Summary
Scientists created a biodegradable aerogel from waste taro stems that can effectively absorb both microplastics and dye pollutants from water. The material maintained strong performance across different water conditions and could be reused for at least five cycles, offering a green solution for removing multiple contaminants from water simultaneously.
Water pollution and agricultural waste are pressing global issues. Herein, a biomass aerogel derived from waste taro stem microcrystalline cellulose (TS-MCC) was fabricated, in which, the effects of cellulose amount, cross-linker content, pre-freezing protocols on the aerogel's property were studied. The optimized TS-MCC aerogel exhibited a hierarchical porous structure with good mechanical property (65.04 kPa) and adsorption capacities, with the q towards microplastics (Polystyrene, PS) and dye (Congo red, CR) being 418.6 mg/g and 951.51 mg/g at 298 K, respectively. Meanwhile, it exhibited good applicability under different pH (3-11) and ionic strength environments, as well as the retained notably simultaneous adsorption ability even under mixed contaminant systems. The mathematical models suggested that the adsorption of PS and CR both fitted pseudo-second-order kinetics, and the adsorption isotherms could be described by the Langmuir and Freundlich models, respectively. Hydrogen bonding, electrostatic attraction, and π-π interactions were inferred as the main adsorption mechanisms towards PS and CR according to Fourier transform infrared spectrometer and X-ray photoelectron spectroscopy analysis. Moreover, the adsorption efficiencies were 92.37 % for PS and 88.34 % for CR after 5 reuse cycles. Therefore, this study provides a green aerogel sorbent for adsorbing microplastics and dyes contaminants.