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Dialdehyde modified and cationic aerogel for efficient microplastics adsorption from environmental waters

International Journal of Biological Macromolecules 2023 32 citations

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Scientists developed a plant-based aerogel material that can efficiently absorb microplastics from water, achieving removal rates above 90% across a wide range of water conditions. The material maintained its effectiveness after eight reuse cycles, making it a practical and eco-friendly solution. This type of technology could help reduce microplastic levels in rivers, lakes, and reservoirs that supply drinking water.

Polymers
Study Type Environmental

Recent reports had shown that microplastics could be transferred to organisms through various channels, severely and adversely affecting organisms' health and their physiological functions. Therefore, there remained an urgency to adopt an effective and environmentally friendly method to extract microplastics from water. In this paper, a cationic-modified d-DCPG aerogel with a three-dimensional network structure was successfully prepared by a directional freeze-drying technology in which double-aldehyde-modified cellulose nanofiber (CNF) was used as the matrix, betaine chloride hydrazide (GT) provided modification, and polyvinyl alcohol (PVA) provided cross-linking function. Aerogels had an excellent adsorption capacity (145.05 mg/g) for microplastics in aqueous environment, and when the pH was from 10 to 4, it exhibited an excellent adsorption efficiency from 90.01 % to 97.61 %; an excellent adsorption efficiency after 8 cycles (>89 %); pseudo-second-order kinetics and Freundlich adsorption isotherm had a high fitting effects on the adsorption process and adsorption results, respectively. And ultraviolet analysis also verified the occurrence of adsorption behavior. These results showed that d-DCPG aerogels had an excellent application prospects in microplastics removal in river, lake, reservoir, and marine environments.

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