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61,005 resultsShowing papers similar to The role of microplastic aging on chlorpyrifos adsorption-desorption and microplastic bioconcentration
ClearAdsorption behaviors of chlorpyrifos on UV aged microplastics
Researchers investigated how UV aging affects the adsorption of the pesticide chlorpyrifos on biodegradable and non-degradable microplastics, finding that UV irradiation significantly modified plastic surfaces and enhanced their capacity to carry organic pollutants.
Laboratory Studies about Microplastic Aging and Its Effects on the Adsorption of Chlorpyrifos
Researchers simulated the aging of six types of microplastics in freshwater and seawater to study how weathering affects their ability to adsorb the pesticide chlorpyrifos. The study found that UV-driven aging caused surface cracks, pores, and chemical changes in the microplastics, and the aging process increased their capacity to adsorb chlorpyrifos, suggesting that weathered microplastics in the environment may carry higher concentrations of pesticide pollutants.
Behavior and mechanism of atrazine adsorption on pristine and aged microplastics in the aquatic environment: Kinetic and thermodynamic studies
Researchers systematically explored how the pesticide atrazine adsorbs onto both pristine and aged microplastics in aquatic environments. The study found that aged microplastics had higher adsorption capacities than pristine ones, with the aging process and pH significantly affecting surface charge and adsorption behavior, suggesting that weathered microplastics may carry greater loads of chemical contaminants.
Mechanistic interpretation of the sorption of terbuthylazine pesticide onto aged microplastics
Scientists studied how environmental aging changes the ability of polyethylene microplastics to absorb a common pesticide called terbuthylazine. Aged microplastics absorbed less pesticide than fresh ones because weathering made their surfaces less water-repellent and more negatively charged. This matters for understanding real-world risks because it suggests that the ability of microplastics to carry pesticides and other chemicals may change over time as the particles weather in the environment.
A comparative study on the adsorption behavior of pesticides by pristine and aged microplastics from agricultural polyethylene soil films
Researchers compared how pristine and aged agricultural polyethylene film microplastics adsorb pesticides. They found that aged films, which develop rougher surfaces, more cracks, and oxygen-containing chemical groups, adsorb pesticides more readily than pristine ones. The study suggests that weathered agricultural microplastics in soil may act as carriers for pesticide contamination, potentially increasing environmental and human health risks.
Photoaging of polyethylene microplastic and its effect on the chlorpyrifos adsorption
This study examined how UV-B radiation ages polyethylene microplastics over time and how that aging changes their ability to adsorb the pesticide chlorpyrifos. Photoaging modified the surface chemistry and structure of the plastic, altering its interaction with the pesticide, suggesting that weathered microplastics in aquatic environments may carry different — and potentially higher — loads of toxic chemicals than fresh particles. This "Trojan horse" effect is important for understanding how microplastics contribute to broader chemical contamination of waterways.
Photoaging effects on polyethylene microplastics: Structural changes and chlorpyrifos adsorption
Researchers studied how UVB-induced photoaging changes the properties of polyethylene microplastics and their ability to absorb the pesticide chlorpyrifos. They found that aged microplastics absorbed nearly 18% more pesticide than pristine ones, due to the formation of oxygen-containing surface groups, increased surface roughness, and reduced crystallinity. The findings suggest that weathered microplastics in the environment may pose greater risks as carriers of harmful pesticides.
Adsorption behavior of triazine pesticides on polystyrene microplastics aging with different processes in natural environment
Researchers found that microplastics that have aged in the environment absorb pesticides more effectively and quickly than fresh microplastics, and the pesticide-loaded particles are more toxic to bacteria. This means that as microplastics weather outdoors, they become better carriers for agricultural chemicals, potentially increasing the combined health risks when these contaminated particles enter food or water supplies.
Sorption of organic compounds by aged polystyrene microplastic particles
Researchers tested the sorption of organic compounds by aged polystyrene microplastic particles and found that weathering increased their sorption capacity, meaning environmental aging makes microplastics more effective at accumulating and transporting pollutants.
Adsorption behaviors of atrazine and imidacloprid on high temperature aged microplastics: Mechanism and influencing factors
Researchers investigated how aged polyethylene microplastics — the kind that have been weathered by UV light and heat in the environment — adsorb common agricultural pesticides, finding that microplastics can accumulate pesticides like atrazine and imidacloprid at high concentrations through hydrophobic (water-avoiding) interactions. This "Trojan horse" effect means microplastics can carry and potentially concentrate pesticides as they move through water environments.
Impact of UV-B Photoaging on Chlorpyrifos Adsorption by PET Microplastics: Insights from Experimental and DFT Analysis
Researchers studied how UV-B light aging changes the ability of PET microplastics to absorb the pesticide chlorpyrifos, combining laboratory experiments with computational modeling. They found that aging created new surface functional groups on the microplastics that significantly increased their capacity to bind the pesticide. The findings suggest that weathered microplastics in the environment may carry higher loads of harmful chemicals than fresh plastic particles.
Adsorption of micropollutants onto realistic microplastics: Role of microplastic nature, size, age, and NOM fouling
Researchers measured adsorption of diclofenac and metronidazole onto four realistic microplastic types under varying size, aging, and natural organic matter conditions, finding that aged MPs with smaller size and without NOM fouling showed the highest pollutant adsorption capacity.
Mechanistic interpretation of the sorption of terbuthylazine pesticide onto aged microplastics
Researchers investigated how accelerated weathering — using UV irradiation, hydrogen peroxide, and ultrasonic treatment — alters the surface properties of polyethylene microplastics and affects their sorption of the herbicide terbuthylazine. Aged polyethylene particles showed measurably different sorption kinetics and capacities compared to pristine particles, providing mechanistic insight into how environmental aging changes microplastic interactions with organic pollutants like pesticides.
Adsorption of Alachlor, Lindane, And Methomyl onto Polystyrene Microplastics: Effects of Aging Treatments
Researchers studied how laboratory aging treatments affect the ability of polystyrene microplastics to absorb three common pesticides. They found that UV-aged and chemically oxidized microplastics adsorbed significantly more pesticides than unaged particles due to increased surface area and chemical changes. The findings indicate that weathered microplastics in the environment may act as more potent carriers of agricultural chemicals.
Microplastics and organic contaminants: Investigation of the sorption process on different polymer types
Researchers investigated sorption of organic contaminants onto microplastics collected from environmental samples, finding that real-world MPs had different sorption capacities than laboratory-prepared particles due to surface aging, biofouling, and co-sorption of natural organic matter.
Soil health risks caused by interactions of microplastics and pesticides
Chlorpyrifos adsorption and desorption on pristine and UV-aged LDPE and biodegradable microplastics derived from plastic mulch films was investigated in laboratory experiments, along with bioconcentration in earthworms. Aging altered the adsorption-desorption behavior of both plastic types and affected pesticide bioavailability to earthworms, highlighting risks from pesticide-microplastic interactions in agricultural soils.
Influence of aging on the affinity between microplastics and organic contaminants
Researchers investigated how UV and UV+H2O2 aging affects the capacity of polystyrene microplastics to adsorb and release pesticides and other organic contaminants, finding that aging-induced surface changes significantly altered adsorption affinity and desorption behavior compared to unaged controls.
Polypropylene microplastics aging under natural conditions in winter and summer and its effects on the sorption and desorption of nonylphenol
Researchers found that naturally aged polypropylene microplastics, especially those weathered in summer, showed significantly enhanced sorption capacity for the pollutant nonylphenol compared to pristine microplastics, due to surface property changes from environmental aging.
Adsorption behaviour and interaction of organic micropollutants with nano and microplastics – A review
This review analyzed the adsorption behavior of organic micropollutants — including pharmaceuticals, pesticides, and industrial chemicals — onto nano- and microplastics, finding that adsorption is governed by pollutant hydrophobicity, particle surface area, and aging state, and that microplastics can act as vectors delivering co-contaminants to aquatic organisms.
Effect of Polymer Aging on Uptake/Release Kinetics of Metal Ions and Organic Molecules by Micro- and Nanoplastics: Implications for the Bioavailability of the Associated Compounds
Researchers developed a theoretical framework to describe how aging and degradation of plastic particles in the environment changes their ability to absorb and release metals and organic contaminants. They found that as plastics weather and break down, their capacity to pick up and later release pollutants increases significantly. The study suggests that the age and condition of microplastics are important factors in determining how much contamination they carry and deliver to living organisms.
Adsorption of some hazardous aromatic hydrocarbons by various pristine and heat-activated aged microplastics as potential pollutant carriers in aquatic environment
Researchers examined how pristine and heat-aged microplastics of four polymer types adsorb hazardous aromatic hydrocarbons, finding that aging significantly altered adsorption capacity. The results demonstrate that weathered microplastics may act as more effective pollutant vectors than pristine particles in aquatic environments.
Sorption and dissipation of current-use pesticides and personal-care products on high-density polyethylene microplastics in seawater
Researchers characterized how three pesticides and three personal care products sorb onto high-density polyethylene microplastics in seawater. They found that more hydrophobic compounds accumulated more readily on the plastic, and that significant desorption (over 30%) occurred within 24 hours, especially at higher contaminant concentrations. The study confirms that microplastics can act as both carriers and releasers of chemical pollutants in marine environments.
A comparative study on the adsorption behavior and mechanism of pesticides on agricultural film microplastics and straw degradation products
Researchers compared how agricultural film microplastics and straw-derived cellulose particles adsorb pesticides in farmland soils, finding that both materials sorb pesticides but through different mechanisms, with microplastics showing higher affinity for hydrophobic compounds, potentially altering pesticide mobility and bioavailability.
Effect of PVC microplastics on pesticide sorption behavior in soil: Key roles of particle size and aging
Researchers studied how PVC microplastics of different sizes and aging states affect pesticide behavior in agricultural soil. They found that smaller and aged microplastics significantly enhanced pesticide adsorption and made it harder to release back into the soil, primarily through hydrogen bonding mechanisms. The study highlights the need to account for microplastic contamination when assessing how pesticides move through and persist in agricultural soils.