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61,005 resultsShowing papers similar to Interaction characteristics and mechanism of Cr(VI)/Cr(III) with microplastics: Influence factor experiment and DFT calculation
ClearPolyamide microplastics as better environmental vectors of Cr(VI) in comparison to polyethylene and polypropylene microplastics
Researchers found that polyamide microplastics adsorb more hexavalent chromium (Cr(VI)) than polyethylene or polystyrene microplastics, with UV aging increasing adsorption capacity, making polyamide particles potentially more dangerous environmental vectors for this toxic heavy metal.
Comparison of Hexavalent Chromium Adsorption Behavior on Conventional and Biodegradable Microplastics
Researchers compared hexavalent chromium adsorption behavior on conventional versus biodegradable microplastics, finding that polymer chemistry and surface aging significantly affect chromium binding capacity and the risk of co-transport in contaminated environments.
Sorptive behaviour of chromium on polyethylene microbeads in artificial seawater
This laboratory study examined how chromium — a toxic heavy metal — adsorbs onto polyethylene microbeads in artificial seawater, finding that microplastics can accumulate chromium at concentrations far above those in surrounding water. The results support the concern that microplastics act as vectors concentrating heavy metal pollutants in marine environments.
Aging amplifies synergistic adsorption and reduction of Cr(VI) by polyamide microplastics
Researchers found that UV and chemical aging of polyamide microplastics amplified their adsorption and reduction of hexavalent chromium Cr(VI), increasing oxygen-containing functional groups while reducing amide bonds, with Cr(VI) binding driven by electrostatic forces and hydrogen bonds and the aged microplastics able to reduce Cr(VI) to less toxic Cr(III) even under UV light and oxygen-depleted conditions.
Adsorption behaviour of microplastics on the heavy metal Cr(VI) before and after ageing
Researchers studied how UV aging affects the adsorption of hexavalent chromium onto PE, PS, and PA microplastics, finding that aged microplastics had significantly enhanced adsorption capacity due to increased surface area and functional group changes from weathering.
Sorption Behavior, Speciation, and Toxicity of Microplastic-Bound Chromium in Multisolute Systems
Researchers investigated how UV filters affect chromium sorption and toxicity on polystyrene microplastics, finding that UV irradiation and co-contaminants alter metal speciation and increase the ecological risk of microplastic-bound heavy metals.
Microplastics as an emerging vector of Cr(VI) in water: Correlation of aging properties and adsorption behavior
Researchers studied the correlation between aging properties and adsorption of hexavalent chromium Cr(VI) onto polyethylene microplastics under accelerated UV aging conditions, finding that aging-induced changes in surface chemistry increased the adsorption capacity. Aged microplastics may act as more effective vectors for toxic heavy metals in aquatic environments.
Adsorption and Desorption Behavior of Cr(VI) on Two Typical UV-Aged Microplastics in Aqueous Solution
Researchers examined how UV weathering changes the ability of two common microplastic types (polyethylene and polystyrene) to adsorb and release chromium(VI) from contaminated water. UV aging altered surface chemistry and significantly increased adsorption capacity for the toxic heavy metal.
Effects of chlorination on microplastics pollution: Physicochemical transformation and chromium adsorption
Researchers found that chlorination of polyethylene and thermoplastic polyurethane microplastics significantly altered their surface morphology and oxygen-containing functional groups, enhancing their ability to aggregate and adsorb chromium contaminants in water.
Adsorption of perfluoroalkyl substances on polyamide microplastics: Effect of sorbent and influence of environmental factors
Researchers studied how perfluoroalkyl substances (PFAS), a group of persistent industrial chemicals, bind to polyamide microplastics in water. They found that smaller microplastic particles absorbed dramatically more PFAS than larger ones, and that water chemistry conditions like pH and salinity influenced the process. The findings suggest microplastics can concentrate harmful chemicals and potentially increase human and wildlife exposure to PFAS in contaminated environments.
Aging properties of polyethylene and polylactic acid microplastics and their adsorption behavior of Cd(II) and Cr(VI) in aquatic environments
Researchers compared how polyethylene and polylactic acid (PLA) microplastics age in the environment and how that aging affects their ability to absorb heavy metals like cadmium and chromium from water. They found that aging changed the surface chemistry of both plastic types, increasing their capacity to pick up these toxic metals. The findings matter because aged microplastics in the environment may concentrate and transport more pollutants than fresh plastic particles.
Comparing the influence of humic/fulvic acid and tannic acid on Cr(VI) adsorption onto polystyrene microplastics: Evidence for the formation of Cr(OH)3 colloids
Researchers compared how humic/fulvic acid and tannic acid affect chromium(VI) adsorption onto polystyrene microplastics, finding that dissolved organic matter promotes the formation of Cr(OH)3 colloids, complicating the role of microplastics as heavy metal vectors.
Kinetics and Size Effects on Adsorption of Cu(II), Cr(III), and Pb(II) Onto Polyethylene, Polypropylene, and Polyethylene Terephthalate Microplastic Particles
Researchers investigated how copper, chromium, and lead ions adsorb onto polyethylene, polypropylene, and PET microplastic particles of different sizes. The study found that smaller microplastic particles had greater adsorption capacity for heavy metals, with lead showing the highest adsorption levels, particularly on PET particles, suggesting increased environmental risk when tiny microplastics and heavy metals coexist.
The role of photooxidation and organic matter in Cr(III) and Cr(VI) interactions with poly(lactic acid) microplastics in aqueous solution
Researchers studied how UV exposure and organic matter influence the interaction between chromium and biodegradable poly(lactic acid) microplastics in water. They found that pristine PLA has low affinity for chromium, but the presence of organic matter like humic and tannic acids increased chromium adsorption by up to 620-fold, while UV-induced photooxidation of PLA also substantially enhanced adsorption. The study provides important insights into how environmental conditions alter the ability of biodegradable microplastics to transport heavy metals in aquatic systems.
The potential of microplastics as adsorbents of sodium dodecyl benzene sulfonate and chromium in an aqueous environment
Researchers found that both PET and polystyrene microplastics can adsorb the surfactant sodium dodecyl benzene sulfonate (SDBS) and the heavy metal chromium (Cr(VI)) from water, with adsorption capacity influenced by pH, particle size, and MP dose, highlighting their role as co-pollutant vectors in aquatic environments.
The mechanism for adsorption of Cr(VI) ions by PE microplastics in ternary system of natural water environment
Researchers investigated how polyethylene microplastics adsorb hexavalent chromium (Cr(VI)) from water in the presence of the surfactant sodium dodecyl benzene sulfonate (SDBS), finding that SDBS enhanced Cr(VI) adsorption at pH below 6 but competed with chromate ions for adsorption sites at pH above 6. Increasing PE microplastic dosage raised Cr(VI) adsorption capacity substantially, providing mechanistic insight into pollutant co-transport on microplastics in natural water systems.
From cosmetics to Contamination: Microplastics in personal care products as vectors for chromium in aquatic environments
This study tested facial scrubs sold in India and found that most contained plastic microbeads, then measured how well those microbeads absorb the toxic heavy metal chromium under different environmental conditions. The microbeads readily picked up chromium from water, with absorption increasing at higher temperatures and certain pH levels. This shows that microplastics from personal care products can act as carriers for heavy metals once they reach waterways, creating a combined pollution threat.
Adsorption mechanism of hexavalent chromium on electron beam-irradiated aged microplastics: Novel aging processes and environmental factors
Researchers used electron beam irradiation as a novel method to age polypropylene microplastics and then studied how these aged particles adsorb hexavalent chromium from water. They found that aging dramatically increased the microplastics' ability to bind chromium by generating oxygen-containing functional groups on their surfaces. The study highlights that weathered microplastics in the environment may have a significantly greater capacity to concentrate heavy metal pollutants than fresh plastic particles.
Adsorption of three bivalent metals by four chemical distinct microplastics
Researchers measured the sorption of copper, cadmium, and lead onto four types of microplastic particles — including chlorinated PE, PVC, and two PE variants — finding that higher crystallinity and surface area drove greater metal adsorption, and that all four plastics had different capacities for each metal.
NaCl enhances cesium adsorption onto microplastics in seawater: A density functional theory perspective
Researchers used density functional theory (DFT) to investigate how sodium chloride (NaCl) in seawater enhances the adsorption of radioactive cesium onto microplastic surfaces, elucidating molecular-scale mechanisms by which coexisting ions modulate heavy metal-microplastic interactions.
Interaction of toxic chemicals with microplastics: A critical review
This critical review examined how toxic chemicals interact with microplastics in the environment, synthesizing evidence on adsorption, desorption, and the conditions under which microplastics either increase or decrease the bioavailability of co-occurring pollutants.
Unraveling Complexation and Contaminant Vector Potentialin Aged Polyamide-Heavy Metal Interactions
Researchers found that aged polyamide (PA) microplastics exhibited enhanced adsorption capacity for cadmium and copper compared to pristine PA, with increased surface roughness from aging promoting stronger metal binding via electrostatic interactions, and environmental factors such as pH influencing subsequent metal desorption.
Unraveling the Co-Adsorption Mechanisms of Sulfonamide Antibiotics and Cu 2+ on Microplastics in Aquatic Environments: Joint Effects and Molecular-Level Insights from Experiments and DFT Calculation
Researchers investigated the co-adsorption behavior of ten sulfonamide antibiotics and copper ions (Cu2+) on polyamide microplastics in aquatic environments, finding synergistic effects for sulfonamides and antagonistic effects for Cu2+ adsorption. Molecular-level DFT calculations revealed the mechanisms underlying these interactions, with implications for the combined transport of antibiotics and heavy metals in microplastic-contaminated water.
Metal adsorption by microplastics in aquatic environments under controlled conditions: exposure time, pH and salinity
Scientists systematically varied pH, salinity, and exposure time during metal adsorption experiments on different microplastic types, finding that pH had the greatest influence on metal uptake, with higher pH favoring adsorption of copper, lead, and cadmium onto most tested polymers.