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61,005 resultsShowing papers similar to Photochemical transformation and interaction of octachlorodibenzofuran (OCDF) with microplastics in suspended particulate matter-water system
ClearInfluence of polyethylene microplastics on the photocatalytic degradation of dibutyl phthalate and bisphenol A in an aqueous medium
Researchers examined how polyethylene microplastics influence the photocatalytic degradation of dibenzofuran in seawater using hydrogen peroxide, assessing whether plastic particles alter the phototransformation of hydrophobic organic pollutants. Microplastics modified the photocatalytic process, changing the rate and products of dibenzofuran degradation and potentially affecting aquatic toxicity.
Phototransformation and photoreactivity of MPs-DOM in aqueous environment: Key role of MPs structure decoded by optical and molecular signatures
Researchers investigated how dissolved organic matter released from microplastics behaves during light-driven transformation in water. They found that organic matter from benzene-containing polymers showed distinctly different photoreactivity compared to matter from polyolefin-based plastics. The study reveals that the chemical structure of the parent microplastic plays a key role in determining how its dissolved byproducts react and generate reactive species in aquatic environments.
Influence of polyethylene microplastics on the photocatalytic degradation of dibutyl phthalate and bisphenol A in an aqueous medium
Researchers investigated how the presence of polyethylene microplastics affects the photocatalytic degradation of dibenzothiophene, a common marine pollutant, under simulated sunlight. Microplastics altered the phototransformation pathway of the organic pollutant, potentially changing its bioavailability and toxicity in marine systems.
Enhanced malachite green photolysis at the colloidal-aqueous interface
This study found that microplastic particles in water can accelerate the breakdown of certain organic pollutants at the particle surface. The research suggests that microplastics play an underappreciated role in the environmental fate of chemical contaminants.
Studies of the Photo-transformation of Emerging Contaminants Adsorbed onto Plastic in an Aqueous Environment
This thesis investigated how light exposure transforms chemical contaminants adsorbed onto microplastics in water, examining how UV-driven photo-transformation changes the toxicity of pollutants like PCBs and PAHs attached to plastic surfaces. Understanding these transformations is important for assessing the true environmental risk of chemical-laden microplastics.
Roles of microplastic-derived dissolved organic matter on the photodegradation of organic micropollutants
Researchers discovered that dissolved organic matter released from weathered microplastics significantly inhibits the photodegradation of the antibiotic sulfamethoxazole in water, primarily through light screening effects, suggesting microplastic pollution may slow the natural breakdown of pharmaceutical contaminants.
Photochemistry of microplastics-derived dissolved organic matter: Reactive species generation and organic pollutant degradation
Researchers investigated how dissolved organic matter released from degrading polystyrene and PVC microplastics behaves when exposed to sunlight in water. They found that sunlight breaks down the aromatic compounds in this plastic-derived material and generates reactive chemical species, though at lower rates than natural organic matter. Despite this, these reactive species significantly accelerated the breakdown of co-existing pollutants, suggesting that degrading microplastics may act as unexpected natural catalysts in aquatic environments.
Progress on the photo aging mechanism of microplastics and related impact factors in water environment
This review examined the photo-aging mechanisms of microplastics in aquatic environments, finding that solar UV radiation drives oxidation reactions that alter surface chemistry, fragment particles further, and enhance their capacity to adsorb and release co-occurring pollutants.
Insight into the dynamic transformation properties of microplastic-derived dissolved organic matter and its contribution to the formation of chlorination disinfection by-products
Researchers studied how dissolved organic matter released from microplastics transforms under UV light and how it contributes to the formation of harmful disinfection byproducts during water chlorination. They found that UV exposure changed the chemical composition of the microplastic-derived organic matter, affecting its reactivity during disinfection. The findings suggest that microplastics in water sources may indirectly increase the formation of potentially harmful chemicals during standard water treatment.
Research progress on environmental occurrence of microplastics and their interaction mechanism with organic pollutants
This review summarizes how microplastics in the environment interact with organic pollutants—adsorbing, carrying, and releasing them. Microplastics act as mobile carriers for persistent organic chemicals, altering their distribution and toxicity in ecosystems and the organisms, including humans, that consume them.
The photochemical behaviors of microplastics through the lens of reactive oxygen species: Photolysis mechanisms and enhancing photo-transformation of pollutants
This review re-examines the photochemical degradation mechanisms of microplastics through the lens of reactive oxygen species, identifying defects in the traditional autoxidation model and exploring how microplastics can enhance the photo-transformation of co-existing pollutants.
Microplastic PropertiesGovern the Photodegradationof Sorbed Anthracene in Aquatic Environments
Researchers investigated how microplastic properties govern the photodegradation of anthracene, a model hydrophobic organic contaminant, in aquatic environments, finding that polymer type, surface characteristics, and aging state significantly influenced degradation rates. The study highlights that microplastics can both facilitate and inhibit contaminant photodegradation depending on their physicochemical properties.
Photoreactivity of microplastic-derived dissolved organic matter governed by its oxygen-containing functional groups in hydrophobic/hydrophilic fractions rather than molecular weights
This study investigated the photoreactivity of dissolved organic matter (DOM) released by degrading microplastics, analyzing how its molecular structure governs how it responds to light. The researchers found that oxygen-containing functional groups in hydrophobic and hydrophilic fractions — rather than molecular weight — were the key drivers of photoreactivity.
Photochemical reactivity of water-soluble dissolved organic matter from microplastics and microfibers
When microplastics and microfibers sit in water, they leach dissolved organic matter (DOM) that can react with sunlight to produce reactive chemicals. This study found that the type and amount of DOM released depends heavily on polymer chemistry, with aromatic plastics like PET and polystyrene releasing more light-absorbing DOM, and microfibers releasing more DOM overall than microplastic particles. Understanding how plastic-derived DOM breaks down in sunlight is important because these chemical by-products can interact with other aquatic pollutants and affect aquatic ecosystems in ways not yet fully understood.
Insights into the photosensitivity and photobleaching of dissolved organic matter from microplastics: Structure-activity relationship and transformation mechanism
This study investigated the photosensitivity and photobleaching behavior of dissolved organic matter released from microplastics (MPDOM), examining how physicochemical properties of different plastics influence photoactivation and transformation. The structure-activity analysis revealed that MPDOM composition strongly determines its photoreactivity, affecting how microplastic-derived organic compounds interact with sunlight and generate reactive oxygen species in aquatic environments.
Microplastic Properties Govern the Photodegradation of Sorbed Anthracene in Aquatic Environments
Researchers found that microplastic properties — including polymer type, surface chemistry, and aging state — govern the rate and pathway of solar photodegradation of sorbed anthracene in aquatic environments, with sorption to microplastics altering contaminant photochemical fate compared to free solution.
Effects of microplastic sorption on microbial degradation of halogenated polycyclic aromatic hydrocarbons in water
Researchers investigated how microplastics act as carriers for halogenated polycyclic aromatic hydrocarbons (HPAHs) in water and whether this sorption affects microbial degradation of these dioxin-like compounds. They found that microplastic-sorbed HPAHs had reduced bioavailability to degrading bacteria, potentially slowing natural breakdown of these toxic pollutants.
The environmental effects of microplastics and microplastic derived dissolved organic matter in aquatic environments: A review
This review examines how microplastics interact with other pollutants in water and how aging from sunlight and weathering changes their behavior. As microplastics break down, they release dissolved organic matter and develop surface changes that increase their ability to carry harmful chemicals like pesticides and pharmaceuticals. The findings suggest that weathered microplastics in real-world environments may be more dangerous than fresh plastics used in most lab studies.
Process analysis of microplastic aging during the photochemical oxidation process and its effect on the adsorption behavior of dissolved organic matter
Accelerated UV/persulfate and UV/chlorine oxidation experiments showed that both processes aged microplastics in distinct ways — altering surface chemistry and morphology — which in turn changed how the MPs adsorb dissolved organic matter (DOM) from water. Because aged MPs in real environments bind organic contaminants differently than pristine plastics, these findings are essential for predicting the long-range transport and ecological risk of weathered microplastics in natural water systems.
Size and Structure-Dependent Molecular Fingerprint Transformation of Microplastic-Derived Dissolved Organic Matter in Sunlit Seawater: Implication for Marine Carbon Cycles
This study examined how the size and structure of microplastics influence the photochemical transformation of MP-derived dissolved organic matter under UV irradiation, finding that inherent plastic properties determine the molecular character of DOM released and its effects on ocean carbon cycling.
Photochemical dissolution of buoyant microplastics to dissolved organic carbon: Rates and microbial impacts
Common ocean surface microplastics (PE, PP, EPS) were irradiated under simulated sunlight, which fragmented and oxidized the polymers and produced dissolved organic carbon as a significant byproduct. The study identifies sunlight-driven photochemical dissolution as an important but poorly quantified removal mechanism for buoyant microplastics from the ocean surface.
Transport of persistent organic pollutants: Another effect of microplastic pollution?
This review examines how microplastics act as vectors for persistent organic pollutants (POPs) in aquatic environments, covering the physical and chemical factors governing pollutant adsorption and desorption. The authors discuss how interactions between microplastics and POPs vary with polymer type, particle properties, and environmental conditions, and when these interactions may result in toxic effects on aquatic organisms.
Characteristics and mechanisms of dissolved organic matter leached by photodegradation of polyethylene microplastics: role of adsorbed antibiotics
Researchers investigated how UV-driven photoaging of polyethylene microplastics and their interactions with the antibiotic ofloxacin affect the release of dissolved organic matter in water. They found that UV exposure significantly increased DOM release from pristine microplastics, while antibiotic-adsorbed microplastics initially released different molecular weight compounds before converging to similar patterns. The study reveals that aging microplastics and their co-contaminants create complex secondary pollution dynamics in aquatic environments.
Hydrophilic Fraction of Dissolved Organic Matter Largely Facilitated Microplastics Photoaging: Insights from Redox Properties and Reactive Oxygen Species
This study investigated how dissolved organic matter in natural water affects the breakdown of microplastics by sunlight. The water-soluble fraction of organic matter was most effective at speeding up microplastic aging by generating reactive oxygen species that attack the plastic surface. This matters because faster breakdown of microplastics in the environment creates smaller, potentially more dangerous nanoplastic particles that can more easily enter living organisms.