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61,005 resultsShowing papers similar to UV-induced aging creates adsorption hotspots: Oxygen-containing functional groups on nanoplastics dictate the adsorption behavior of ciprofloxacin
ClearAdsorption performance and mechanisms of ciprofloxacin onto microplastics: effects of different textures and aging degrees.
Researchers examined ciprofloxacin adsorption onto pristine and UV-aged polypropylene, polyvinyl chloride, and polyamide 6 microplastics, finding that UV aging increased oxygen-containing surface functional groups and raised maximum adsorption capacity by up to 40%, with density functional theory calculations identifying hydrogen bonding, electrostatic attraction, and π interactions as primary binding mechanisms.
Impact of the hydrated functional zone on the adsorption of ciprofloxacin to microplastics under the influence of UV aging
Researchers investigated how UV aging of polyethylene and polystyrene microplastics affects their adsorption of the antibiotic ciprofloxacin, finding that UV-aged particles developed rougher surfaces with increased hydrophilicity due to the formation of a hydrated functional zone. Adsorption isotherm and kinetic modelling showed that this surface transformation significantly altered the binding capacity and mechanisms for ciprofloxacin, with pH also playing a key role in adsorption efficiency.
Adsorption of levofloxacin by ultraviolet aging microplastics
Researchers studied how ultraviolet aging changes the ability of common microplastics to adsorb the antibiotic levofloxacin. The study found that UV-aged polystyrene, polyamide, and polyethylene microplastics all showed significantly enhanced adsorption capacity compared to their unaged counterparts, suggesting that weathered microplastics in the environment may carry higher pollutant loads.
Adsorption-desorption behaviors of ciprofloxacin onto aged polystyrene fragments in aquatic environments
Researchers investigated how UV and chemical aging of polystyrene microplastic fragments affects their adsorption and desorption of the antibiotic ciprofloxacin in aquatic environments, finding that aging increased surface area and altered surface chemistry, thereby enhancing adsorption capacity. The study identified key physicochemical properties controlling antibiotic-microplastic interactions and their potential to affect antibiotic bioavailability in contaminated waters.
Behavior and mechanisms of ciprofloxacin adsorption on aged Polylactic Acid and Polyethylene microplastics
This study examined how aged polylactic acid (PLA) and polyethylene (PE) microplastics absorb the antibiotic ciprofloxacin in water. Aging changes the surface chemistry of microplastics, affecting how they pick up and carry antibiotics — which could deliver higher doses of these drugs to organisms that ingest the particles.
Behavior and mechanisms of ciprofloxacin adsorption on aged polylactic acid and polyethlene microplastics
Researchers investigated how aging affects the adsorption of the antibiotic ciprofloxacin on polylactic acid and polyethylene microplastics, finding that aged plastics showed significantly enhanced adsorption capacity due to physicochemical surface changes.
Adsorption characteristics of ciprofloxacin hydrochloride on polystyrene microplastics in freshwater
Researchers studied how polystyrene microplastics adsorb the antibiotic ciprofloxacin in freshwater, comparing pristine and aged particles. They found that aging treatment, particularly Fenton oxidation over seven days, significantly enhanced the adsorption capacity of the microplastics for the antibiotic. The study suggests that as microplastics weather in the environment, they may become increasingly effective carriers of pharmaceutical contaminants in water systems.
UV-photoaging of degradable microplastics in atmospheric and wastewater: Surface changes and enhanced antibiotic interaction
When biodegradable microplastics spend time in wastewater rather than open air, they age much more aggressively — developing biofilms and oxidized surfaces that dramatically increase their ability to absorb antibiotics. This study found that wastewater-aged polybutylene succinate microplastics adsorbed 2.4 times more tetracycline than fresh plastic, and outperformed air-aged plastic by 40%, driven by biofilm chemistry and increased surface area. The implication is that wastewater treatment systems — rather than solving the microplastic problem — may be transforming biodegradable plastics into potent carriers for antibiotic resistance.
New insights into adsorption mechanism of pristine and weathered polyamide microplastics towards hydrophilic organic compounds
Adsorption of four hydrophilic organic compounds including antibiotics sulfamethoxazole and ciprofloxacin onto pristine and weathered polyamide microplastics was studied, finding that weathering introduced oxygen-containing surface groups that significantly altered adsorption capacity and mechanisms. The results improve predictions of how microplastics transport co-occurring pollutants in aquatic environments.
Reduced adsorption of norfloxacin on UV aging microplastics in anoxic environment
UV aging of four common microplastics (PS, PP, PA, PE) in anoxic conditions reduced their adsorption capacity for the antibiotic norfloxacin, with decreases attributed to reduced hydrophobicity and increased crystallinity, while adsorption capacity decreased with increasing temperature.
Sorption behavior and mechanism of hydrophilic organic chemicals to virgin and aged microplastics in freshwater and seawater
UV-accelerated aging of polystyrene and PVC microplastics increased surface oxidation and introduced microcracks, and aged MPs showed significantly increased adsorption of the hydrophilic antibiotic ciprofloxacin compared to virgin MPs. The findings demonstrate that even hydrophilic organic chemicals can accumulate on aged microplastics, expanding the range of compounds that microplastics may carry and deliver to organisms.
Adsorption behavior of levofloxacin hydrochloride on non‐degradable microplastics aging with H 2 O 2
This study explored how microplastics act as carriers for the antibiotic levofloxacin in water, finding that chemically aged plastics (simulating environmental weathering) adsorb significantly more of the drug than fresh plastics. All three plastics tested — PVC, polystyrene, and PET — showed increased drug-binding capacity after aging, primarily through pore-filling. This matters because microplastics in rivers and lakes don't just pose a physical hazard; they can pick up and concentrate pharmaceutical contaminants, potentially delivering them to aquatic organisms at higher doses.
Enhanced biotoxicity by co-exposure of aged polystyrene and ciprofloxacin: the adsorption and its influence factors
This study found that polystyrene microplastics aged by sunlight absorbed significantly more of the antibiotic ciprofloxacin than fresh microplastics, and the combination was more toxic to organisms than either pollutant alone. The aging process created more surface area and chemical binding sites on the plastic particles. This is important because it means weathered microplastics in the real world can concentrate antibiotics and deliver higher toxic doses to organisms, potentially contributing to both direct toxicity and antibiotic resistance.
Influencing Mechanisms of Exogenous and Endogenous Dissolved Organic Matter on the Adsorption of Tetracycline on UV ‐Light Aged Microplastics
Researchers investigated how humic acid and microplastic-derived dissolved organic matter (MP-DOM) influence tetracycline adsorption onto UV-aged polyethylene and polystyrene microplastics, finding that UV aging increased surface area and functional groups on the plastics while dissolved organic matter altered adsorption capacity through competitive and facilitative mechanisms.
Impact of sequential UV-aging of microplastics on the fate of antibiotic (tetracycline) in riverine, estuarine, and marine systems
Researchers studied how sequential UV aging of polystyrene, polypropylene, and polyethylene microplastics, which mimics natural weathering, affects their ability to adsorb the antibiotic tetracycline under different water chemistry conditions. They found that aged microplastics adsorbed significantly more tetracycline than pristine particles, with the effect varying by water type and plastic polymer. The study suggests that as microplastics weather in the environment, they may become increasingly effective at carrying antibiotic contaminants.
[Effect of Aging on Adsorption of Tetracycline by Microplastics and the Mechanisms].
Researchers aged polyethylene and polystyrene microplastics under UV-254 irradiation and analyzed changes in color, surface morphology, and functional groups, finding that UV aging altered the physical and chemical properties of both MPs and significantly affected their adsorption capacity and mechanism for the antibiotic tetracycline.
Aged microplastics enhance their interaction with ciprofloxacin and joint toxicity on Escherichia coli
Researchers found that aged microplastics showed enhanced adsorption of the antibiotic ciprofloxacin compared to pristine particles, and that their combined exposure produced greater toxicity to E. coli at the molecular level than either pollutant alone.
UV and chemical aging alter the adsorption behavior of microplastics for tetracycline
Researchers found that UV and chemical aging significantly increased microplastics' capacity to adsorb tetracycline, with biodegradable PBAT showing more dramatic changes in surface properties and adsorption behavior compared to conventional plastics like polystyrene and polyethylene.
Influence of UV wavelength variations on tetracycline adsorption by polyethylene microplastics in aquatic environments
Exposure to UVC, UVB, and UVA light at different wavelengths differentially altered the surface chemistry of polyethylene microplastics and their subsequent adsorption capacity for the antibiotic tetracycline. Shorter UV wavelengths caused more extensive surface oxidation, increasing tetracycline adsorption by up to several fold and changing the antibiotic's environmental fate.
Adsorption of Macrolide Antibiotics by Aged Microplastics of Different Sizes: Mechanisms and Effects
Researchers investigated how aging affects the ability of polystyrene microplastics to adsorb macrolide antibiotics in water, testing two particle sizes under simulated natural aging conditions. They found that aging increased surface roughness and oxygen-containing functional groups on the microplastics, significantly enhancing their ability to adsorb azithromycin, clarithromycin, and erythromycin. The findings suggest that weathered microplastics in the environment may carry higher loads of antibiotic contaminants than pristine particles.
Investigation on the adsorption and desorption behaviors of antibiotics by degradable MPs with or without UV ageing process
Scientists compared how original and UV-aged polylactic acid (PLA) — a biodegradable plastic — adsorbs and desorbs the antibiotics tetracycline and ciprofloxacin relative to PVC, finding that UV aging changed PLA's surface more dramatically and increased its capacity to carry and release these drugs.
Photoaging processes of polyvinyl chloride microplastics enhance the adsorption of tetracycline and facilitate the formation of antibiotic resistance
Researchers found that UV photoaging of PVC microplastics significantly enhanced their ability to adsorb the antibiotic tetracycline and facilitated the development of antibiotic resistance in surrounding microorganisms, raising concerns about aged microplastics in aquatic environments.
Aging characteristics of degradable and non-biodegradable microplastics and their adsorption mechanism for sulfonamides
Researchers investigated how aging processes affect the ability of degradable and non-biodegradable microplastics to adsorb sulfonamide antibiotics in aquatic environments. The study found that aging increased the hydrophilicity and polarity of microplastics, boosting the adsorption capacity of polylactic acid by up to 3.18 times, suggesting that weathered microplastics may pose greater ecological risks as carriers of co-existing contaminants.
Photoaged microplastics enhanced the antibiotic resistance dissemination in WWTPs by altering the adsorption behavior of antibiotic resistance plasmids
Researchers found that microplastics exposed to UV light become significantly better at attracting and holding antibiotic resistance genes, increasing their capacity by 43 to 48 percent compared to unaged particles. This enhanced adsorption was linked to increased surface roughness and chemical changes on the plastic surface. The study suggests that UV-treated wastewater discharge may inadvertently accelerate the spread of antibiotic resistance in the environment through aged microplastics.