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Sustainable Reinforcement of Rubber Compound Using Recycled PET (Polyethylene Terephthalate): A Review

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A comprehensive review found that incorporating recycled PET into rubber compounds can improve tensile strength by up to 45%, enhance thermal stability by 20–30°C, and reduce energy consumption by approximately 50 MJ/kg compared to virgin PET, while advancing circular economy goals. Diverting post-consumer PET waste into high-performance rubber composites reduces the volume of plastic that would otherwise enter waste streams where it fragments into microplastics.

Polymers

Increasing environmental concerns over plastic waste and the depletion of non-renewable resources have intensified the search for sustainable alternatives in rubber reinforcement. This review comprehensively investigates the use of recycled polyethylene terephthalate (r-PET) as a green reinforcing agent in rubber compounds, replacing traditional fillers such as carbon black and silica. Experimental studies reveal that incorporating r-PET can improve tensile strength by up to 45%, enhance thermal stability by 20–30°C, and lead to energy savings of approximately 50 MJ.kg-1 compared to virgin PET. Notably, this review is the first to integrate mechanical performance analysis with life cycle assessment (LCA), providing a dual perspective on technical feasibility and environmental impacts. Processing methods, such as mechanical blending, chemical grafting, and surface modification, have been discussed to enhance r-PET compatibility with rubber matrices. Challenges such as poor dispersion, interfacial adhesion, and thermal degradation are critically analyzed, along with mitigation strategies. The findings demonstrate that r-PET not only offers performance and cost advantages but also supports circular economy initiatives by repurposing postconsumer PET waste into high-performance rubber composite. Future research directions are proposed, focusing on hybrid reinforcement systems, compatibility enhancement, and carbon-footprint reduction.

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