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Plasma-treated polystyrene microplastics for enhanced transport studies in porous media: A surfactant-free approach

2026
Yifan Lu, Rizwan Khaleel, Rohan Hassan Shanthakumar, Nurgül Tosun, Markus Rolf, Hannes Laermanns, Kavita Verma, Lakshminarayana Rao, Thomas Fischer, Sanjay Mathur, Christina Bogner

Summary

Scientists developed a new way to study how tiny plastic particles move through soil and groundwater without using chemicals that change how the plastics behave. This method uses oxygen plasma treatment to make plastic particles easier to track in laboratory experiments. Better understanding of how microplastics travel through soil and water systems could help us predict where these pollutants end up and how they might affect drinking water sources.

Polymers

Microplastics (MPs) are increasingly recognized as persistent contaminants in soils and groundwater systems worldwide. Polystyrene MPs are highly hydrophobic and show strong homoaggregation, which affects their mobility in porous media. Most laboratory transport studies therefore use chemical dispersants, such as Tween 20, to achieve a uniform distribution of particles during transport experiments. However, these additives coat plastic surfaces and alter plastic–soil interactions, making it difficult to assess environmentally realistic transport behavior. Here, we introduce a surfactant-free approach based on controlled radio-frequency oxygen plasma treatment to modify MP surface properties. Oxygen plasma-treated polystyrene particles (

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