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Simultaneous sorption behaviors of UV filters on the virgin and aged micro-high-density polyethylene under environmental conditions.
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Researchers studied how UV filter chemicals from sunscreens adsorb onto both virgin and aged high-density polyethylene microplastics. They found that aged, weathered microplastics had greater capacity to accumulate UV filter compounds than fresh plastic due to changes in surface chemistry. This suggests that environmental aging of plastics increases their ability to transport chemical contaminants.
The simultaneous sorption behaviors of four analytes from the UV filters group, benzophenone (BPh), 4-methylbenzylidene camphor (4MBC), benzophenone 3 (BPh3), and benzophenone 2 (BPh2) on virgin and aged high-density polyethylene (HDPE) with a particle size of 125 μm in milliQ and river water were examined in this study. The aging processes of HDPE particles were carried out with the use of simulated sunlight. Conducted research revealed that the sorption of UV filters on HDPE particles follows pseudo-second-order kinetics. A Temkin isothermal model best described the adsorption process for 4BMC, BPh, BPh3, BPh2 on aged HDPE in river water, and 4MBC, BPh, BPh3 on virgin HDPE in milliQ water. The adsorption of BPh2 onto virgin MPs in milliQ water was consistent with the Langmuir isothermal model. Environmental conditions and physicochemical properties of analytes influenced the sorption mechanism between UV filters and MPs particles. It was observed that the main mechanisms responsible for the sorption of BPh, 4MBC, BPh3, and BPh2 on the surface of HDPE are hydrophobic interactions, that may change through the involvement of electrostatic interactions.
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