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Sorption of pharmaceuticals and personal care products to polyethylene debris
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This study measured the sorption of pharmaceuticals and personal care products (PPCPs) — including carbamazepine, oxybenzone, and triclosan — onto polyethylene plastic debris. The results show that plastic debris can accumulate PPCPs from water and potentially deliver these bioactive compounds to organisms that ingest the contaminated plastic.
Presence of plastic debris in marine and freshwater ecosystems is increasingly reported. Previous research suggested plastic debris had a strong affiliation for many pollutants, such as polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), and heavy metals. In this study, the sorption behavior of pharmaceuticals and personal care products (PPCPs), including carbamazepine (CBZ), 4-methylbenzylidene camphor (4MBC), triclosan (TCS), and 17α-ethinyl estradiol (EE2), to polyethylene (PE) debris (250 to 280 μm) was investigated. The estimated linear sorption coefficients (K d) are 191.4, 311.5, 5140, and 53,225 L/kg for CBZ, EE2, TCS, and 4MBC, and are related to their hydrophobicities. Increase of salinity from 0.05 to 3.5 % did not affect the sorption of 4MBC, CBZ, and EE2 but enhanced the sorption of TCS, likely due to the salting-out effect. Increase of dissolved organic matter (DOM) content using Aldrich humic acid (HA) as a proxy reduced the sorption of 4MBC, EE2, and TCS, all of which show a relatively strong affiliation to HA. Results from this work suggest that microplastics may play an important role in the fate and transport of PPCPs, especially for those hydrophobic ones.
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Investigating the Sorption of Pharmaceutical and Personal Care Products on High-Density Polyethylene and Polypropylene Microplastics
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Researchers investigated the sorption behavior of pharmaceuticals and personal care products (PPCPs) on high-density polyethylene and polypropylene microplastics in aquatic systems. They found that microplastics adsorb PPCPs to concentrations orders of magnitude higher than the surrounding water, demonstrating that plastic particles act as concentrators and potential vectors for pharmaceutical contaminants in aquatic environments. The study adds to evidence that microplastics amplify co-contaminant exposure risks for aquatic organisms.
Mechanisms of Sorption of Pharmaceutical and Personal Care Products to Microplastics
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This thesis investigated how pharmaceutical and personal care product chemicals sorb onto high-density polyethylene microplastic fragments, and how this affects the combined toxicity to aquatic organisms. Microplastics can carry drug compounds and personal care chemicals from wastewater into aquatic environments, concentrating pollutant exposure for marine organisms.
Sorption of selected pharmaceutical compounds on polyethylene microplastics: Roles of pH, aging, and competitive sorption
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Researchers found that polyethylene microplastics adsorb pharmaceutical compounds including an antibiotic, a beta-blocker, and an antidepressant, with sorption capacity influenced by pH, aging of the plastic, and competition between compounds — raising concern about microplastics as carriers of pharmaceuticals in aquatic environments.
Sorption and desorption of selected pharmaceuticals by polyethylene microplastics
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Researchers tested the sorption and desorption of three pharmaceuticals — sulfamethoxazole, propranolol, and sertraline — onto polyethylene microplastics in water, finding that all three compounds sorbed to the plastic surface and were only partially released over time. The results suggest microplastics can act as vectors for pharmaceutical compounds in aquatic environments, potentially affecting their bioavailability.
Sorption and dissipation of current-use pesticides and personal-care products on high-density polyethylene microplastics in seawater
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Researchers characterized how three pesticides and three personal care products sorb onto high-density polyethylene microplastics in seawater. They found that more hydrophobic compounds accumulated more readily on the plastic, and that significant desorption (over 30%) occurred within 24 hours, especially at higher contaminant concentrations. The study confirms that microplastics can act as both carriers and releasers of chemical pollutants in marine environments.
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