We can't find the internet
Attempting to reconnect
Something went wrong!
Hang in there while we get back on track
Upgrading biochar via co-pyrolyzation of agricultural biomass and polyethylene terephthalate wastes
Summary
PET plastic bottles were co-processed with rice straw at high temperatures to create biochar that can effectively absorb multiple types of pollutants from water. This study demonstrates a way to repurpose plastic waste while also creating a useful tool for environmental remediation.
Spent polyethylene terephthalate (PETE) bottles were collected and co-pyrolyzed with rice straw (RS) to examine the characteristics and performance of biochar as a sorbent for various types of U.S. EPA priority pollutants, including 2,4-dinitrotoluene (DNT), 2,4-dichlorophenol (DCP), Pb, chromate (CrO4 2-), and selenate (SeO4 2-). During sorption of contaminants to PETE/RS-derived biochar, PETE residues from pyrolysis, pH, and pyrolysis temperature greatly affected the sorption process. Depending on the types of contaminants and experimental conditions, co-pyrolysis of PETE and RS may enhance the sorption of contaminants through different sorption mechanisms, including hydrophobicity, electrostatic force, ion exchange, surface complexation, and surface precipitation. Unlike other contaminants, selenate was reductively transformed by delocalized electrons from the graphitic structure in biochar. Our results strongly suggest that co-pyrolysis of PETE and agricultural wastes may be favorable to enhance the properties of biochar. In addition to syn-gas and bio-oil from co-pyrolysis, biochar may be a valuable by-product for commercial use.