0
Article Tier 2 Environmental Sources Remediation Sign in to save

Microplastics influence the adsorption and desorption characteristics of Cd in an agricultural soil

Journal of Hazardous Materials 2019 374 citations

AI summary Read the abstract

Batch experiments showed that polyethylene microplastics reduced cadmium adsorption but increased desorption in farmland soil, with effects varying by MP dose, particle size, and pH. The findings indicate microplastics could increase cadmium mobility in agricultural soils, potentially raising risks of crop uptake.

Polymers

Microplastics (MPs) in terrestrial ecosystems particularly agroecosystem are attracting increasing attention worldwide. However, the influences of MPs on adsorption and desorption of contaminants in agricultural soils remain unknown. Here, batch experiments were conducted to study the effects of polyethylene MPs on Cd adsorption and desorption in a farmland soil under varying conditions. Both Cd adsorption and desorption in soils with or without MPs reached equilibrium within 120 min. Cd adsorption kinetics followed the pseudo-second order model, and the adsorption isotherm fitted to the Langmuir model more precisely than the Freundlich model. Overall, addition of MPs decreased Cd adsorption but increased desorption, and the effects varied with MPs dose and particle size, and solution pH. MPs-induced decrease in Cd adsorption and increase in Cd desorption were more pronounced at higher MPs dose and larger particle size, but varied differently from solution pH. EDS analysis confirmed Cd adsorption on MPs surface. Both MPs before and after Cd adsorption showed similar XRD patterns, indicating MPs maintained a high crystallinity and no new crystalline phases formed. In conclusion, the input of MPs into soil might enhance the mobility of Cd via mitigating soil adsorbing capacity, thereby posing additional risks of Cd to agroecosystem.

More Papers Like This

Article Tier 2

Effect of Microplastics on the Adsorption and Desorption Properties of Cadmium in Soil

AI summary Read the abstract

Polyethylene and polypropylene microplastics were found to reduce soil's capacity to adsorb cadmium, a toxic heavy metal, raising concerns that microplastic contamination in farmland soils could increase the mobility and risk of heavy metal pollutants.

Article Tier 2

Polyvinyl chloride microplastics reduce Cd(II) adsorption and enhance desorption with soil-dependent mechanisms

AI summary Read the abstract

The study investigated how polyvinyl chloride (PVC) microplastics affect cadmium adsorption and desorption in two different soil types. Researchers found that PVC reduced cadmium adsorption and promoted its release back into the soil, potentially increasing its bioavailability and environmental risk.

Article Tier 2

Microplastics in soils with contrasting texture, organic carbon and mineralogy: changes in cadmium adsorption forms and their mobility in soil columns

AI summary Read the abstract

This study investigated how high-density polyethylene microplastics alter the behavior of cadmium — a toxic heavy metal — in soils with different textures, organic carbon contents, and mineral compositions. Using soil column experiments, researchers found that microplastics changed how cadmium binds to soil particles and how easily it leaches downward, with effects varying depending on the soil type and microplastic particle size. Since cadmium is a known carcinogen and agricultural soils commonly contain both microplastics and heavy metals, understanding their interactions is critical for food safety.

Article Tier 2

Influence of polyethylene-microplastic on environmental behaviors of metals in soil

AI summary Read the abstract

Researchers investigated how polyethylene microplastics affect the adsorption, desorption, and bioavailability of heavy metals in soil. They found that adding microplastics altered how metals bind to soil particles and increased the mobility of certain metals like cadmium and lead. The study suggests that microplastic contamination in soils may change the environmental behavior of heavy metals, potentially increasing their availability to plants and soil organisms.

Article Tier 2

[Characteristics and Mechanism of Cd Release and Transport in Soil Contaminated with PE-Cd].

AI summary Read the abstract

Researchers investigated how polyethylene (PE) microplastics affect the sorption and transport of cadmium (Cd) in soil, examining the characteristics and mechanisms of Cd release under PE contamination. Their findings reveal that microplastics alter soil physicochemical properties and sorption capacity, influencing heavy metal mobility and distribution in terrestrial ecosystems.

Research digests by email

When a large batch of papers lands in the Atlas, we read through it and send a short write-up of what stood out.

Email me about

Share this paper