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Aggregation and stability of sulfate-modified polystyrene nanoplastics in synthetic and natural waters
Summary
Researchers studied how polystyrene nanoplastics behave in different water conditions, examining aggregation and stability under varying pH, salt types, and natural organic matter concentrations. The study found that nanoplastics remain highly stable and suspended in freshwater and even wastewater, but aggregate rapidly and settle in seawater. Natural organic matter was identified as the most significant factor affecting nanoplastic aggregation in waters with high ionic strength.
Nanoplastics (NPs) are becoming emerging pollutants of global concern. Understanding the environmental behavior of NPs is crucial for their environmental and human risk assessment. In this study, the aggregation and stability of polystyrene (PS) NPs were investigated under different hydrochemical conditions such as pH, salt type (NaCl, CaCl, NaSO), ionic strength (IS), and natural organic matter (NOM). The critical coagulation concentrations of PS NPs were determined to be 158.7 mM NaCl, 12.2 mM CaCl, and 80.0 mM NaSO. Ca was more effective in destabilizing PS NPs, compared to Na, owing to its stronger charge screening effect. In the presence of monovalent ions, NOM reduced aggregation through steric repulsion, whereas in the case of divalent ions, NOM induced aggregation through cation bridging. Initial and long-term stability studies demonstrated that, in waters with high IS and NOM content, NOM was the most significant factor affecting NPs aggregation. PS NPs would be highly suspended in all freshwaters, and even in wastewater, whereas they would aggregate rapidly and deposit in seawater. Finally, a statistical model was established to evaluate the hydrodynamic diameter of NPs in different waters. The results indicated the stability of PS NPs in natural aquatic environments and their potential for long-term transport.
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