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Aggregation and stability of sulfate-modified polystyrene nanoplastics in synthetic and natural waters
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Researchers studied how polystyrene nanoplastics behave in different water conditions, examining aggregation and stability under varying pH, salt types, and natural organic matter concentrations. The study found that nanoplastics remain highly stable and suspended in freshwater and even wastewater, but aggregate rapidly and settle in seawater. Natural organic matter was identified as the most significant factor affecting nanoplastic aggregation in waters with high ionic strength.
Nanoplastics (NPs) are becoming emerging pollutants of global concern. Understanding the environmental behavior of NPs is crucial for their environmental and human risk assessment. In this study, the aggregation and stability of polystyrene (PS) NPs were investigated under different hydrochemical conditions such as pH, salt type (NaCl, CaCl, NaSO), ionic strength (IS), and natural organic matter (NOM). The critical coagulation concentrations of PS NPs were determined to be 158.7 mM NaCl, 12.2 mM CaCl, and 80.0 mM NaSO. Ca was more effective in destabilizing PS NPs, compared to Na, owing to its stronger charge screening effect. In the presence of monovalent ions, NOM reduced aggregation through steric repulsion, whereas in the case of divalent ions, NOM induced aggregation through cation bridging. Initial and long-term stability studies demonstrated that, in waters with high IS and NOM content, NOM was the most significant factor affecting NPs aggregation. PS NPs would be highly suspended in all freshwaters, and even in wastewater, whereas they would aggregate rapidly and deposit in seawater. Finally, a statistical model was established to evaluate the hydrodynamic diameter of NPs in different waters. The results indicated the stability of PS NPs in natural aquatic environments and their potential for long-term transport.
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Researchers investigated how natural organic matter, salt types, and other aquatic colloids affect the aggregation stability of polystyrene nanoplastics in freshwater and saltwater conditions. The study found that multivalent cations caused nanoplastics to aggregate more rapidly, with implications for predicting how nanoplastics settle or remain suspended in natural water bodies.
Mechanistic understanding of the aggregation kinetics of nanoplastics in marine environments: Comparing synthetic and natural water matrices
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Researchers investigated aggregation kinetics of polystyrene nanoplastics in marine environments, finding that organic matter type and salt concentration strongly influenced particle stability, with nanoplastics in natural seawater aggregating differently than in synthetic matrices.
Impact of natural organic matter and inorganic ions on the stabilization of polystyrene micro-particles
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Researchers investigated how natural organic matter (NOM) and inorganic ions affect the stabilization and aggregation behavior of polystyrene nanoplastics in water, finding that NOM enhanced colloidal stability while high ionic strength promoted aggregation. The results indicate that water chemistry plays a dominant role in determining nanoplastic mobility and persistence in natural freshwater environments.
[Effect of Water Components on Aggregation and Sedimentation of Polystyrene Nanoplastics].
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Researchers investigated how sodium ions (Na+) and natural organic matter (NOM) affect the aggregation and sedimentation of polystyrene nanoplastics (PS-NPs) in six water types including seawater, lake water, and domestic sewage. They found that Na+ concentrations below 80 mmol/L facilitated PS-NP sedimentation, while NOM effects varied by water type, with findings informing the environmental fate and distribution of nanoplastics.
Impact of electrolyte and natural organic matter characteristics on the aggregation and sedimentation of polystyrene nanoplastics
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Researchers examined how dissolved organic matter from different water sources affects the aggregation and sedimentation of polystyrene nanoplastics under varied salt concentrations and temperatures, finding that biopolymers form a protective 'eco-corona' around particles that strongly inhibits long-term sedimentation, while temperature influences aggregation dynamics in complex ways.
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