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Effect of cadmium on the sorption of tylosin by polystyrene microplastics
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Researchers found that cadmium ions significantly influence the sorption of the antibiotic tylosin onto polystyrene microplastics, with competitive and cooperative interactions depending on concentration ratios, highlighting that co-contamination with heavy metals alters microplastic-mediated antibiotic transport in aquatic environments.
Microplastics are widespread in the environment and might transport readily by ocean currents, wind and atmospheric deposition. Simultaneously, antibiotics and heavy metals could often be detected in the environment. They are both positively charged, it is necessary to clarify the interactions of these pollutants with microplastics when they were coexist. In this study, the most commonly used polystyrene (PS) was selected as a representative microplastic. This study investigated the effect of Cd(II) on the sorption of TYL by PS in different coexistence systems. The results showed that: in the composite system, when TYL and Cd(II) coexist, the presence of Cd(II) could inhibit the sorption of TYL by PS, and the inhibitory effect increases with the increase of the concentration of Cd(II), indicating that competitive sorption dominates the sorption. When PS adsorbed Cd(II) first and then adsorbed TYL, the presence of Cd(II) was conducive to the sorption of TYL, and the sorption strengthened with the increase of Cd(II) concentration, indicating that the complexation between TYL and Cd(II) enhanced the sorption of TYL. In addition, initial pH values and ionic strength were essential in the sorption process. Therefore, this study could provide an important basis for evaluating the environmental behavior and ecological risk of microplastics in the process of compound pollution.
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This study tested the sorption of the antibiotic tylosin onto four types of microplastics, finding that sorption capacity varied significantly by plastic type, with implications for how microplastics may transport antibiotics through aquatic environments.
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Researchers studied how heavy metals in water affect the ability of polyethylene microplastics to absorb the antibiotic ciprofloxacin. They found that heavy metals competed with the antibiotic for binding sites on the microplastic surface, changing how much of each pollutant the plastic could carry. This is important because it shows microplastics in real-world environments may transport different combinations of pollutants, potentially delivering both antibiotics and heavy metals into the food chain.
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Researchers studied how the antibiotic levofloxacin sticks to PVC microplastics in water and how the presence of heavy metals affects this process. They found that certain metals like copper, zinc, and chromium increased the amount of antibiotic absorbed by the plastic, while cadmium and lead reduced it. The findings reveal that microplastics can act as carriers for both antibiotics and metals in polluted water, potentially creating complex contamination scenarios.
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Researchers investigated how antibiotics affect the adsorption of copper and chromium onto aged polystyrene and PVC microplastics, finding that antibiotic co-contamination alters heavy metal binding behavior on weathered plastics in aqueous environments.
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Researchers systematically investigated how three common microplastic types adsorb tetracycline antibiotics. The study found that polystyrene had the highest adsorption capacity at 178.57 micrograms per gram, followed by PVC and polyethylene, and that PVC and polystyrene strongly retained the antibiotics with minimal desorption, raising concerns about compound pollution from microplastic-antibiotic combinations in the environment.
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