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Influence of dissolved black carbon on the aggregation and deposition of polystyrene nanoplastics: Comparison with dissolved humic acid
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This study compared the effects of dissolved black carbon and humic acid on polystyrene nanoplastic aggregation and deposition, finding that black carbon more strongly stabilized nanoplastics in suspension, altering their environmental transport behavior.
Dissolved black carbon (DBC), widely found in soil and water environments is likely to affect the transport of nanoplastics in aquatic environments. The aggregation and deposition behaviors of fresh and aged polystyrene nanoplastics (PSs) with and without DBC in NaCl solution were investigated by time-resolved dynamic light scattering (DLS) and quartz crystal microbalance with dissipation monitoring equipment (QCM-D) techniques. The results suggest that DBC can screen the surface charges of PSs by interacting with PSs through hydrogen bonding, hydrophobic interactions and π-π interactions, although they were negatively charged. DBC promoted the aggregation of PSs under relatively low ionic strengths, and it minimally affected the stability of PSs under high ionic strength. Deposition experiments showed that both DBC in salt solution and DBC adsorption on silica surface facilitated the deposition of fresh PSs while HA inhibited both deposition processes. After aging, PSs were more stable, and the effects of DBC and HA were weakened. This study investigated the influence mechanism of DBC on the aggregation and deposition behaviors, which provides new insights into the stability and transport of PSs in complex aquatic environments.
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This study investigated how natural organic matter stabilizes fragmental polystyrene nanoplastics in aqueous environments, finding that humic and fulvic acid coatings reduce aggregation and enhance colloidal stability, affecting nanoplastic transport and bioavailability.
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Researchers studied how nanosized activated carbon interacts with positively and negatively charged nanoplastics under various water chemistry and hydrodynamic conditions. They found that aggregation behavior depended strongly on particle charge, pH, and the presence of natural organic matter like humic acid. The study suggests that interactions with engineered nanomaterials in aquatic environments can significantly influence how far nanoplastics travel, with implications for predicting their environmental fate.
Impact of electrolyte and natural organic matter characteristics on the aggregation and sedimentation of polystyrene nanoplastics
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Researchers examined how dissolved organic matter from different water sources affects the aggregation and sedimentation of polystyrene nanoplastics under varied salt concentrations and temperatures, finding that biopolymers form a protective 'eco-corona' around particles that strongly inhibits long-term sedimentation, while temperature influences aggregation dynamics in complex ways.
Impact of iron/aluminum (hydr)oxide and clay minerals on heteroaggregation and transport of nanoplastics in aquatic environment
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