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Dissolved Organic Matter Enhanced the Aggregation and Oxidation of Nanoplastics under Simulated Sunlight Irradiation in Water
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Dissolved organic matter was found to enhance both the aggregation and photooxidation of nanoplastics under simulated sunlight in water, with humic substances promoting particle clustering and accelerating surface oxidation. The results indicate that organic matter content in natural waters strongly influences nanoplastic fate and transformation.
Nanoplastics (NPs) have become a new type of pollutant of high concern that is ubiquitous in aqueous environments. However, the transport and transformation of NPs in natural waters are not yet fully understood. In this study, the aggregation and photooxidation of NPs were assessed with nanosized polystyrene (PS) as an example, and the effects of dissolved organic matter (DOM) were investigated with Suwannee River fulvic acid (SRFA) as representative DOM. The results showed that simulated sunlight irradiation exhibited negligible effects on the aggregation of PS, while SRFA enhanced its heteroaggregation through hydrophobic interactions. In SRFA solutions, photooxidation of PS with a particle size of 200 nm was observed, which led to an increase in the O/C ratio on its surface at a rate of (2.20 ± 0.40) × 10-2 h-1. This indicates the promotional effect of SRFA on the oxidation of nanosized PS, which is attributed to the generation of the excited triplet state (3SRFA*), hydroxyl radicals (•OH), and singlet oxygen (1O2). Among these reactive species, 1O2 played a crucial role in the oxidation of PS. The findings in this study are helpful for an in-depth understanding of the environmental behavior of NPs in natural waters.
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Exposure Order to Photoaging and Humic Acids Significantly Modifies the Aggregation and Transformation of Nanoplastics in Aqueous Solutions
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Researchers discovered that the order in which nanoplastics are exposed to sunlight and natural organic matter significantly changes how they clump together and behave in water. Nanoplastics aged by sunlight before encountering humic acids behaved differently than those exposed in the reverse order. This finding is important for predicting how nanoplastics actually move and persist in real-world water environments.
Natural Organic Matter Stabilizes Pristine Nanoplastics but Destabilizes Photochemical Weathered Nanoplastics in Monovalent Electrolyte Solutions
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This study examined how sunlight weathering and natural organic matter coatings change the behavior of nanoplastics in water. Researchers found that organic matter stabilizes fresh nanoplastics but actually destabilizes sun-weathered ones, meaning aged nanoplastics in natural waters may clump together and settle differently than expected, affecting where they end up in aquatic environments.
Hydrophilic Fraction of Dissolved Organic Matter Largely Facilitated Microplastics Photoaging: Insights from Redox Properties and Reactive Oxygen Species
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This study investigated how dissolved organic matter in natural water affects the breakdown of microplastics by sunlight. The water-soluble fraction of organic matter was most effective at speeding up microplastic aging by generating reactive oxygen species that attack the plastic surface. This matters because faster breakdown of microplastics in the environment creates smaller, potentially more dangerous nanoplastic particles that can more easily enter living organisms.
Destabilization of photochemical weathered nanoplastics by natural organic matter in monovalent electrolyte solutions
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Researchers investigated how photochemical weathering of nanoplastics alters the adsorption of natural organic matter (NOM) and subsequent colloidal stability in monovalent electrolyte solutions, comparing pristine and photoaged polystyrene nanoplastics exposed to Suwannee River NOM. They found that photoaging modified the eco-corona structure formed by NOM adsorption, destabilizing nanoplastic aggregation behavior in aquatic environments.
Heteroaggregation of nanoplastic particles in the presence of inorganic colloids and natural organic matter
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Nanoplastics were found to heteroaggregate extensively with inorganic colloids and natural organic matter in both freshwater and marine conditions, altering their size, surface charge, and settling behavior compared to pristine particles. The study demonstrates that nanoplastic behavior in natural waters is dominated by interactions with other environmental constituents rather than the intrinsic properties of the plastic alone.
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