Effect of fragmentation on the transport of polyvinyl chloride and low-density polyethylene in saturated quartz sand

Microplastics are an obstinate pollutant in terrestrial environments, posing a risk to the subsurface soil matrix and potentially to groundwater. In this study, the transport and retention behaviour of two major plastic polymers, 125-300 μm Polyvinyl chloride (PVC) plastic fragments and 300 μm Low-density polyethylene (LDPE) spherical particles, were explored in saturated quartz sand (1.6-2.0 mm) columns. The PVC used in this study represented secondary microplastics, while the LDPE represented primary microplastics. Retention profiles at different ultrapure water flow rates (2.0-3.5 ml/min) were compared and analysed. At the beginning and end of each column test, the microplastic particles were scrutinized, identified, and quantified by light microscopy. The results showed that the transport distance of microplastic particles increased with their decreasing diameter. Small-sized PVC microplastic particles, whose morphology was more 1-dimensional, were more susceptible to fragmentation within the column, promoting migration. Spherical LDPE remained at their initial position without fragmenting. Microplastic degradation into fragments appeared to play an important role in improving the movement of particles. This study offers initial indications of infiltration depths and shape-dependent fragmentation of secondary microplastics in coarse sand based on the lab experiments.