An In Situ Depolymerization and Liquid Chromatography–Tandem Mass Spectrometry Method for Quantifying Polylactic Acid Microplastics in Environmental Samples
Environmental Science & Technology2022
57 citations
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Mengqi Yan,
Mengqi Yan,
Lei Wang
Lei Wang
Junjie Zhang,
Junjie Zhang,
Junjie Zhang,
Junjie Zhang,
Junjie Zhang,
Junjie Zhang,
Junjie Zhang,
Junjie Zhang,
Junjie Zhang,
Junjie Zhang,
Lei Wang
Junjie Zhang,
Lei Wang
Mengqi Yan,
Mengqi Yan,
Tao Zhang,
Lei Wang
Junjie Zhang,
Junjie Zhang,
Junjie Zhang,
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Mengqi Yan,
Yawen Peng,
Yawen Peng,
Yawen Peng,
Yawen Peng,
Mengqi Yan,
Junjie Zhang,
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Junjie Zhang,
Junjie Zhang,
Lei Wang
Yali Xu,
Lei Wang
Mengqi Yan,
Hongwen Sun,
Hongwen Sun,
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Yali Xu,
Yali Xu,
Junjie Zhang,
Yali Xu,
Lei Wang
Hongwen Sun,
Lei Wang
Junjie Zhang,
Junjie Zhang,
Junjie Zhang,
Lei Wang
Lei Wang
Hongwen Sun,
Lei Wang
Lei Wang
Junjie Zhang,
Lei Wang
Hongwen Sun,
Hongwen Sun,
Lei Wang
Hongwen Sun,
Hongwen Sun,
Lei Wang
Lei Wang
Hongwen Sun,
Hongwen Sun,
Hongwen Sun,
Junjie Zhang,
Hongwen Sun,
Lei Wang
Tao Zhang,
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Hongwen Sun,
Hongwen Sun,
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Hongwen Sun,
Hongwen Sun,
Hongwen Sun,
Hongwen Sun,
Hongwen Sun,
Mengqi Yan,
Tao Zhang,
Mengqi Yan,
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Hongwen Sun,
Lei Wang
Lei Wang
Hongwen Sun,
Lei Wang
Lei Wang
Lei Wang
Hongwen Sun,
Lei Wang
Lei Wang
Hongwen Sun,
Lei Wang
Lei Wang
Hongwen Sun,
Lei Wang
Lei Wang
Yawen Peng,
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Hongwen Sun,
Hongwen Sun,
Yawen Peng,
Hongwen Sun,
Junjie Zhang,
Lei Wang
Hongwen Sun,
Hongwen Sun,
Lei Wang
Lei Wang
Hongwen Sun,
Lei Wang
Hongwen Sun,
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Hongwen Sun,
Lei Wang
Lei Wang
Hongwen Sun,
Lei Wang
Hongwen Sun,
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Lei Wang
Hongwen Sun,
Lei Wang
Hongwen Sun,
Lei Wang
Summary
Researchers developed an in-situ depolymerization combined with liquid chromatography-tandem mass spectrometry method to detect and quantify nanoplastics directly in complex environmental and biological samples. The approach avoided the need for physical isolation of particles and enabled sensitive identification of polymer type and abundance.
Polylactic acid (PLA) is the most commonly used biodegradable plastic with rapid growth in recent years. This leads to predictable increased pollution of PLA microplastics (MPs) in the environment. However, quantification methods for the PLA MPs are still lacking. In this study, a method based on alkali-assisted thermal depolymerization and liquid chromatography-tandem mass spectrometry (LC-MS/MS) analysis was developed to quantify PLA MPs. After the background monomer compound was removed, PLA MPs were efficiently depolymerized to lactic acid and detected by LC-MS/MS with a limit of quantification of 18.7 ng/g. The ideal recovery of spiked PLA MPs of 93% was obtained, and the PLA MPs did not need to be separated or extracted in advance from the environmental samples. Using this method, PLA MPs were detected in all the sediment samples of a reservoir at a range of 53.5-491 ng/g dw, and the concentrations decreased with the sediment depth. In addition, after soaking in water at 95 °C for 30 min, approximately 12 μg of PLA MPs was released from a single teabag.