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The potential of polyethylene microplastics to transport copper in aquatic systems: Adsorption and desorption studies
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Researchers investigated the adsorption and desorption of copper (II) ions onto polyethylene microplastics in aquatic systems, varying operational parameters such as equilibrium time, pH, temperature, and initial metal concentration. They found that polyethylene microplastics can act as vectors for copper transport in water, with sorption behavior governed by multiple physicochemical factors.
Heavy metals and microplastics are two types of general contaminants that can cause significant damage to water systems and organisms. However, the interaction of heavy metal ions with microplastic in aquatic systems received less attention compared with that of organic contaminants. This study aims to explore the interaction of copper (II) ions with microplastic (polyethylene) in aquatic systems. The adsorption experiments were performed by varying several operational parameters including equilibrium pH, initial Cu (II) concentrations, and contact times. The microplastic was characterized using X-ray diffraction, scanning electron microscopy, and Fourier transform infrared. The results confirmed the porous nature of the microplastic surface and the existence of various binding sites. The maximum Cu (II) uptake by microplastic was recorded as 1.23 mg/g at pH 5, according to the Langmuir adsorption isotherm. The experimental isotherm data exhibited a good fit to the Toth model, followed by the Langmuir and Freundlich equations, according to the correlation coefficient and %error values. The pseudo-first kinetics equation showed a better fit to copper (II) kinetics data compared with the pseudo-second kinetics equation. Elution of copper (II) ions from copper (II)-loaded microplastic was attempted using several elutants, and the results indicated that 0.01 M HNO3 performed well with elution efficiency over 99.5%. Thus, the elution experiments furnished proof that Cu-loaded microplastic may leach Cu (II) ions under rich acidic conditions, thereby aiding the transport of Cu (II) ions into the digestive tracts of aquatic organisms. PRACTITIONER POINTS: Polyethylene microplastics showed potential to sorb copper ions. The mechanism was electrostatic interaction between microplastics and metal ions. Maximum copper adsorption by microplastic was recorded as 1.23 mg/g. Once desorbed, Cu(II) transferred into the digestive tracts of aquatic organisms.
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