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New fast compostable polymer without leaving any traces of microplastic

Zenodo (CERN European Organization for Nuclear Research) 2022
Seema Agarwal, Elmar Sehl, Dipannita Ghosh, Dipannita Ghosh

Summary

Researchers developed a new fast-compostable polymer designed to break down completely in industrial composting without leaving any microplastic residues, addressing a major shortcoming of current compostable packaging materials. Unlike many plastics marketed as biodegradable, this material demonstrated complete degradation without leaving polymer fragments. If scaled up, this type of material could reduce microplastic contamination from food packaging waste in composting and natural environments.

Polymers

New material solutions to the microplastics (MP) problem originating from packaging are urgently needed as they reach industrial compost plants when disposed of together with food waste and reach the natural environment in huge amounts when carelessly disposed of by people worldwide. We present one of the fastest composting aliphatic-aromatic polyesters with a good balance of mechanical and barrier properties, making it a promising alternative for low-density polyethylene in packaging. The new polyesters are prepared by melt polycondensation reactions. One of the compositions exhibited a tensile strength of 20 ± 2 MPa, modulus of 150 ± 8 MPa, and a very high elongation at a break of 581 ± 46 %. The low oxygen transmission rate (152 cm3m−2day−1bar−1) measured at 65% relative humidity and 23 °C confirms excellent barrier performance. Enzyme-catalyzed hydrolysis under controlled conditions, the full fragmentation, assimilation, and mineralization in thermophilic, aerobic composting could be confirmed in less than five weeks using a combination of different analytical methods. The mechanism of degradation was proven to be bulk degradation. The presentation will cover synthetic, structural characterization, and detailed degradation studies showing the MP-free compost after the degradation of the polymer. Also see: https://micro2022.sciencesconf.org/428007/document

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