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Adsorption of Diclofenac Sodium by Aged Degradable and Non-Degradable Microplastics: Environmental Effects, Adsorption Mechanisms
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Researchers found that UV aging of both polystyrene and biodegradable PBAT microplastics increased their surface oxidation and hydrophilicity, enhancing their capacity to adsorb the pharmaceutical pollutant diclofenac sodium through surface interaction and pore-filling mechanisms.
Microplastics (MPs) are novel pollutants, which can carry toxic contaminants and are released in biota and accumulate. The adsorption behavior of MPs and aged MPs has attracted extensive attention. In this paper, the aging process of polystyrene (PS) and poly (butyleneadipate-co-terephthalate) (PBAT) plastics under ultraviolet (UV) irradiation at a high temperature and their adsorption properties for the contaminant diclofenac sodium (DCF) before and after aging was investigated. There are many factors affecting the adsorption capacity of MPs. In this experiment, three aspects of MPs, organic pollutants, and environmental factors are explored. The Freundlich model as well as the pseudosecondary kinetic model is more applicable to the process of DCF adsorption by MPs. The main effects of adsorption of organic pollutants by MPs are electrostatic interactions, hydrogen-halogen bonds, and hydrophobic interactions. The adsorption capacity of the UV-aged MPs on DCF is significantly enhanced, and the order of adsorption capacity is Q(A-PBAT) (27.65 mg/g) > Q (A-PS) (23.91 mg/g) > Q (PBAT) (9.30 mg/g) > Q (PS) (9.21 mg/g). The results show that more active sites are generated on the surface of MPs after aging, which can enhance their adsorption capacity for organic pollutants. This adsorption mechanism will increase their role as contaminant carriers in the aquatic food chain.
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Researchers studied how environmental aging changes the physical and chemical properties of PET microplastics and their ability to absorb pharmaceutical pollutants. They found that aged microplastics had rougher surfaces and greater capacity to adsorb diclofenac, a common pain medication found in waterways. The study suggests that weathered microplastics may act as more effective carriers of pharmaceutical contaminants in the environment compared to fresh plastics.
UV and chemical aging alter the adsorption behavior of microplastics for tetracycline
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Researchers found that UV and chemical aging significantly increased microplastics' capacity to adsorb tetracycline, with biodegradable PBAT showing more dramatic changes in surface properties and adsorption behavior compared to conventional plastics like polystyrene and polyethylene.
Adsorption Behavior of Diclofenac on Polystyrene and Poly(butylene adipate-co-terephthalate) Microplastics: Influencing Factors and Adsorption Mechanism
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Researchers investigated the adsorption of the anti-inflammatory drug diclofenac onto polystyrene and poly(butylene adipate-co-terephthalate) (PBAT) microplastics, finding that PS adsorbed more diclofenac than PBAT due to differences in surface chemistry and hydrophobicity. Understanding how pharmaceuticals bind to different plastic types is essential for assessing their combined environmental risks in aquatic systems.
Effect of aging on adsorption behavior of polystyrene microplastics for pharmaceuticals: Adsorption mechanism and role of aging intermediates
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Photo-Fenton-accelerated aging of polystyrene microplastics was found to shift the dominant adsorption mechanism for pharmaceuticals from hydrophobic/π-π interactions in pristine PS to electrostatic and hydrogen bonding in aged PS, while high concentrations of aging intermediates suppressed adsorption capacity. The study reveals how environmental weathering fundamentally changes how microplastics interact with pharmaceutical pollutants.
Comparative Photo‐Induced Aging of Poly(Butylene Adipate‐co‐Terephthalate) and Polystyrene Microplastics and their Divergent Affinities for Tetracycline in Aquatic Environments
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Researchers UV-aged biodegradable PBAT and conventional polystyrene microplastics in river water for 30 days, finding that aging caused surface oxidation in PBAT while polystyrene showed minimal change, and that the two types had divergent affinities for adsorbing tetracycline.
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