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Sorption of representative organic contaminants on microplastics: Effects of chemical physicochemical properties, particle size, and biofilm presence
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This study examined how organic pollutants like flame retardants and industrial chemicals attach to microplastics in saltwater conditions. Smaller microplastic particles absorbed more contaminants per unit weight, and natural biofilms growing on the plastic surfaces changed how much pollution they could carry. The findings help explain how microplastics act as carriers of toxic chemicals through the environment and potentially into the food chain.
Microplastic pollution has attracted mounting concerns worldwide. Microplastics may concentrate organic and metallic contaminants; thus, affecting their transport, fate and organismal exposure. To better understand organic contaminant-microplastic interactions, our study explored the sorption of selected polychlorinated biphenyls (PCBs), polybrominated diphenyl ethers (PBDEs), α-hexabromocyclododecane (α-HBCDD), and organophosphate flame retardants (OPFRs) on high-density polyethylene (HDPE) and polyvinylchloride (PVC) microplastics under saline conditions. Sorption isotherms determined varied between chemicals and between HDPE and PVC microplastics. Log Freundlich sorption coefficients (Log K) for the targeted chemicals ranged from 2.01 to 5.27 L kg for HDPE, but were significantly lower for PVC, i.e., ranging from Log K data (2.84 - 8.58 L kg). Significant correlations between chemicals' Log K and Log K (octanol-water partition coefficient) indicate that chemical-dependent sorption was largely influenced by their hydrophobicity. Sorption was evaluated using three size classes (< 53, 53 - 300, and 300 - 1000 µm) of lab-fragmented microplastics. Particle size did not significantly affect sorption isotherms, but influenced the time to reach equilibrium and the predicted maximum sorption, likely related to microplastic surface areas. The presence of biofilms on HDPE particles significantly enhanced contaminant sorption capacity, indicating more complex sorption dynamics in the chemical-biofilm-microplastic system. Our findings offer new insights into the chemical-microplastic interactions in marine environment.
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Partitioning of chemical contaminants to microplastics: Sorption mechanisms, environmental distribution and effects on toxicity and bioaccumulation
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This review critically examines how chemical contaminants like persistent organic pollutants and heavy metals sorb onto microplastic surfaces in the environment. Researchers found that while microplastics can concentrate pollutants at levels far above surrounding water, the actual contribution of microplastics to contaminant transfer into organisms may be less significant than direct exposure from water and food. The study calls for more realistic experimental designs to clarify the true risk.
The chemical behaviors of microplastics in marine environment: A review
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This review summarized interactions between microplastics and organic pollutants and metals in the marine environment, covering sorption behavior across polymer types, the role of degradation in altering sorption capacity, and global monitoring data on pollutant concentrations on marine plastics. The authors conclude that microplastic type, pollutant properties, and environmental conditions all strongly influence chemical accumulation on plastic surfaces.
Adsorption behavior of organic pollutants and metals on micro/nanoplastics in the aquatic environment
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This review examines how micro- and nanoplastics in aquatic environments adsorb organic pollutants and metals onto their surfaces, effectively acting as carriers for other contaminants. Researchers found that environmental factors like pH, salinity, and aging of the plastic significantly influence this sorption behavior. The findings raise concerns that microplastics may increase the bioavailability and toxicity of chemical pollutants in waterways.
Investigation of sorption of environmental pollutants to virgin and aged microplastics
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This research investigated how environmental pollutants such as persistent organic chemicals adsorb onto virgin and weathered plastic particles in natural systems, examining factors such as plastic type, surface aging, and chemical properties. The study contributes to understanding how microplastics act as carriers for toxic contaminants in aquatic environments.
Influence of biofilms on the adsorption behavior of nine organic emerging contaminants on microplastics in field-laboratory exposure experiments
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Researchers studied how natural biofilms that form on microplastics in lake water affect the adsorption of nine emerging organic contaminants. The study found that biofilm colonization on microplastic surfaces can significantly alter how these particles interact with pollutants, in some cases increasing and in others decreasing contaminant uptake compared to clean microplastics.
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