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The influence of various microplastics on PBDEs contaminated soil remediation by nZVI and sulfide-nZVI: Impedance, electron-accepting/-donating capacity and aging
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PVC, PS, and PP microplastics in contaminated soil inhibited the degradation of the brominated flame retardant BDE209 by nano-zero-valent iron and sulfided nZVI to varying degrees, with inhibition linked to microplastic impedance and electron-accepting capacity, while microplastics themselves showed aging and fragmentation during the remediation process.
The microplastics (MPs) existed in the environment widely has resulted in novel thinking about in-situ remediation techniques, such as nano-zero-valent iron (nZVI) and sulfided nZVI (S-nZVI), which were often compromised by various environmental factors. In this study, three common MPs such as polyvinyl chloride (PVC), polystyrene (PS), and polypropylene (PP) in soil were found to inhibit the degradation rate of decabromodiphenyl ether (BDE209) by nZVI and S-nZVI to different degrees due to MPs inhibiting of electron transfer which is the main way to degrade BDE209. The inhibition strength was related to its impedance (Z) and electron-accepting (EAC)/-donating capacity (EDC). Based on the explanation of the inhibition mechanism, the reason for different aging degrees of nZVI and S-nZVI in different MPs was illustrated, especially in PVC systems. Furthermore, the aging of reacted MPs, functionalization and fragmentation in particular, indicated that they were involved in the degradation process. Moreover, this work provided new insights into the field application of nZVI-based materials for removing persistent organic pollutants (POPs).
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This review examines how microplastics and nanoplastics interfere with nano zero-valent iron (nZVI), a widely used material for cleaning up contaminated groundwater and soil, finding that plastic particles typically reduce nZVI's effectiveness by clogging reactive sites and causing premature aging. The finding matters because it suggests that microplastic contamination at remediation sites could undermine cleanup efforts for other pollutants like heavy metals and organic compounds, requiring modified iron formulations (such as sulfidated nZVI) to maintain performance.
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Researchers developed a remediation approach for soils co-contaminated with microplastics and heavy metals using nanoscale zero-valent iron supported on palygorskite. The composite material effectively inhibited microplastic migration in soil and reduced heavy metal mobility, with the microplastic content in deeper soil layers remaining at only about 8% of initial levels after treatment.
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