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Effects of neonicotinoid insecticides on transport of non-degradable agricultural film microplastics
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Researchers investigated how neonicotinoid insecticides adsorb onto agricultural film microplastics and affect their transport through porous media, finding that neonicotinoids altered microplastic mobility in ways that could influence contaminant spread in farmland soils.
Mulch film microplastics (MPs) could act as a vector for agricultural chemicals due to their long-term presence in farmland environments. As a result, this study focuses on the adsorption mechanism of three neonicotinoids on two typical agricultural film MPs, polyethylene (PE) and polypropylene (PP), as well as the effects of neonicotinoids on the MPs transport in quartz sand saturated porous media. The findings revealed that the adsorption of neonicotinoids on PE and PP was a combination of physical and chemical processes, including hydrophobic, electrostatic and hydrogen bonding. Acidity and appropriate ionic strength (IS) were favorable conditions for neonicotinoid adsorption of on MPs. The results of column experiments showed that the presence of neonicotinoids, particularly at low concentrations (0.5 mmol L), could promote the transport of PE and PP in the column by improving the electrostatic interaction and hydrophilic repulsion of particles. The neonicotinoids would be adsorbed on MPs through hydrophobic action preferentially, whereas excessive neonicotinoids could cover the hydrophilic functional groups on the surface of MPs. Neonicotinoids reduced the response of PE and PP transport behavior to pH changes. 0.005 mol L NaCl ameliorated the migration of MPs by increasing their stability. Because of its highest hydration ability and the bridging effect of Mg, Na had the most prominent transport promoting effect on PE and PP in MPs-neonicotinoid. This study shows that the increased environmental risk caused by the coexistence of microplastic particles and agricultural chemicals is unneglectable.
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Transport of polyethylene and polypropylene microplastics under the action of agricultural chemicals: Role of pesticide adjuvants and neonicotinoid active ingredients
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Column experiments showed that pesticide adjuvants (surfactants) and neonicotinoid active ingredients both influenced the transport of polyethylene and polypropylene microplastics through saturated porous media, with surfactants generally enhancing mobility.
Interactions of traditional and biodegradable microplastics with neonicotinoid pesticides
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Researchers investigated how both traditional and biodegradable microplastics interact with neonicotinoid pesticides in agricultural environments. They found that all microplastic types could adsorb the pesticide thiacloprid, but biodegradable microplastics showed different sorption behavior and higher desorption rates compared to conventional plastics. The study suggests that biodegradable microplastics may actually increase pesticide mobility in soils, creating a previously unrecognized pathway for agricultural chemical contamination.
A comparative study on the adsorption behavior and mechanism of pesticides on agricultural film microplastics and straw degradation products
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Researchers compared how agricultural film microplastics and straw-derived cellulose particles adsorb pesticides in farmland soils, finding that both materials sorb pesticides but through different mechanisms, with microplastics showing higher affinity for hydrophobic compounds, potentially altering pesticide mobility and bioavailability.
Adsorption of neonicotinoid insecticides by mulch film-derived microplastics and their combined toxicity
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Researchers studied how microplastics from agricultural mulch films interact with common insecticides used on crops. They found that biodegradable plastic (PBAT) microplastics adsorbed more pesticide than conventional polyethylene microplastics, and that aging increased this adsorption capacity. When combined, the microplastics and insecticides were more toxic to soil organisms than either pollutant alone, suggesting an underappreciated risk in agricultural soils.
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Researchers investigated how high-density polyethylene microplastics from agricultural mulch films affect the behavior of three pesticides in tropical soil, finding that microplastics altered pesticide sorption, transport, and leaching while also increasing ecotoxicological effects on earthworms.
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