We can't find the internet
Attempting to reconnect
Something went wrong!
Hang in there while we get back on track
Subterranean transport of microplastics as evidenced in karst springs and their characterization using Raman spectroscopy
AI summary Read the abstract
Raman micro-spectroscopy confirmed the presence of microplastics in karst spring water from rural Romania, with concentrations of 0.034-0.06 fragments or fibres per liter, demonstrating subterranean transport of microplastics through karst aquifer systems.
The increasing use of plastic materials has led to accumulation of large amounts of plastic waste in environment and a global challenge to be tackled with. The natural process of macro-plastics aging generates a multitude of secondary microplastic fragments accumulating in all areas of the planet. The pollution with microplastics of large water bodies, such as rivers, seas and oceans was already proven, but the presence of microplastics even in karst spring water was not reported yet. In this study, Raman micro-spectroscopy was used to confirm the presence of microplastics in the spring water samples collected from two rural karst springs in the Apuseni Mountains (Țarina and Josani), North-Western Romania. Two sets of water samples of 1000 L collected in spring time 2021 and one in autumn 2021 were filtered and analyzed. Using the Python programming language and combining two separate Raman databases, one for plastics and the other for pigments, we established a customized database to unambiguously identify the type of plastic and pigment present in the discovered micro-fragments. The generated reference pigment-plastic spectra were compared to those of potential microplastics found on filters and Pearson's coefficient was used to measure the level of similarity. The presence of microplastics in karst spring waters was confirmed and a quantitative estimation expressed as number of fragments or fibers per liter was 0.034 in Josani and 0.06 in Țarina karst spring. Five months later sampling (autumn 2021) revealed 0.05 microplastics per liter. The spectral results revealed that most microplastics found were dominated by polyethylene terephthalate (PET), followed by polypropylene and interestingly, abundant blue micro-fragments were identified according to their copper phthalocyanine pigments (pigment Blue 15) or indigo carmine (pigment Blue 63) characteristic spectral fingerprints, which surpassed the inherent spectral background level characteristic for the Raman spectra of naturally contaminated waste micro-samples. Their origin in mountain karst spring waters and potential decrease in time is discussed.
More Papers Like This
Preliminary investigations of microplastic pollution in karst systems, from surface watercourses to cave waters
AI summary Read the abstract
This study collected water samples from surface streams and connected cave waters in a karst system in Italy to document microplastic pollution in groundwater-linked environments. Microplastics including fibers and fragments were detected throughout the karst system, demonstrating that plastics infiltrate even protected underground aquifers.
Analysis of microplastics in selected surface and underground karst waters
AI summary Read the abstract
This Slovenian study sampled microplastics in surface waters and groundwater of the Postojna and Skocjan karst regions, including cave rivers, finding plastic particles even in underground water systems and demonstrating that microplastics penetrate into sensitive and hard-to-reach freshwater environments.
Microplastic pollution in vulnerable karst environments: case study from the Slovenian classical karst region
AI summary Read the abstract
Researchers sampled karst springs, caves, and other habitats in Slovenia's classical karst region and detected microplastics across multiple sites, including springs used for drinking water, raising concerns about plastic contamination of these ecologically sensitive and hydrologically connected underground environments.
Microplastic Contamination in Karst Groundwater Systems
AI summary Read the abstract
Springs and wells from two karst aquifers in Illinois were found to contain microplastics exclusively as fibers (up to 15.2 particles/L), with their presence correlated with phosphate, chloride, and triclosan, suggesting septic effluent as the source. The study demonstrates that karst groundwater systems used for drinking water are vulnerable to microplastic contamination infiltrating through their open, conduit-dominated architecture.
The invisible problem of microplastics and microfibres in karst systems and aquifers: a multidisciplinary approach
AI summary Read the abstract
This thesis investigates how microplastics and microfibres move through karst (limestone) systems and underground aquifers using a multidisciplinary approach, a concern because karst aquifers supply drinking water to roughly a quarter of the global population and are particularly vulnerable to contamination given their direct hydraulic connections to the surface.
Research digests by email
When a large batch of papers lands in the Atlas, we read through it and send a short write-up of what stood out.