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Co-transport behavior and Trojan-horse effect of colloidal microplastics with different functional groups and heavy metals in porous media
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This study examined how tiny microplastic particles travel through soil and groundwater while carrying lead, a toxic heavy metal. The researchers found a "Trojan horse" effect where microplastics transport lead to places it would not normally reach on its own. This is concerning because it means microplastics could spread heavy metal contamination further through drinking water sources.
The emerging global problems of microplastics pollution and their co-occurrence with other pollutants have presented major new challenges for environmental health and protection. This study used column experiments to investigate the co-transport behavior and Trojan-horse effect of colloidal microplastics (non-functional polystyrene microspheres (MS), carboxyl-modified polystyrene microspheres (CMS) and sulfonate-modified polystyrene microspheres (SMS)) and lead (Pb) in porous media. Results showed that a Trojan-horse effect occurred during the co-transport of colloidal microplastics and Pb. In the process of co-transport, colloidal microplastics and Pb mutually inhibited each other's transport at an ionic strength of 1 mM, which may be due to Pb absorption by microplastics, resulting in the destabilization of agglomerates and a reduction in the electronegativity of microplastics. At an ionic strength of 100 mM, colloidal microplastics and Pb promoted each other's transport, potentially due to their competition for adsorption in porous media. The functional groups present on colloidal microplastics inhibited the transport of Pb at low ionic strengths, while at high ionic strengths Pb transport was promoted. Furthermore, deposition experiments verified that quartz crystal microbalance with dissipation (QCM-D) monitoring could effectively account for and predict the transport and deposition behavior of microplastics in the presence or absence of Pb.
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Researchers studied how polystyrene microplastic fragments affect the movement of lead through saturated porous media like soil and groundwater systems. They found that microplastics generally promoted lead mobility, with the effect increasing as particle size, dosage, and flow velocity increased. The enhanced lead transport was attributed to microplastics reducing the ability of surrounding media to absorb the metal and altering pore structure, raising concerns about co-contamination risks in groundwater.
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