We can't find the internet
Attempting to reconnect
Something went wrong!
Hang in there while we get back on track
Development of Films from Spent Coffee Grounds’ Polysaccharides Crosslinked with Calcium Ions and 1,4-Phenylenediboronic Acid: A Comparative Analysis of Film Properties and Biodegradability
Summary
Researchers developed biodegradable films from polysaccharides extracted from spent coffee grounds crosslinked with calcium ions, demonstrating a pathway to convert a high-volume food industry byproduct into sustainable packaging materials.
Most polymeric materials are synthetic and derived from petroleum, hence they accumulate in landfills or the ocean, and recent studies have focused on alternatives to replace them with biodegradable materials from renewable sources. Biodegradable wastes from food and agroindustry, such as spent coffee grounds (SCGs), are annually discarded on a large scale and are rich in organic compounds, such as polysaccharides, that could be used as precursors to produce films. Around 6.5 million tons of SCGs are discarded every year, generating an environmental problem around the world. Therefore, it was the aim of this work to develop films from the SCGs polysaccharide fraction, which is comprised of cellulose, galactomannans and arabinogalactans. Two types of crosslinking were performed: the first forming coordination bonds of calcium ions with polysaccharides; and the second through covalent bonds with 1,4-phenylenediboronic acid (PDBA). The films with Ca2+ ions exhibited a greater barrier to water vapor with a reduction of 44% of water permeability vapor and 26% greater tensile strength than the control film (without crosslinkers). Films crosslinked with PDBA presented 55-81% higher moisture contents, 85-125% greater permeability to water vapor and 67-150% larger elongations at break than the films with Ca2+ ions. Film biodegradability was demonstrated to be affected by the crosslinking density, with the higher the crosslinking density, the longer the time for the film to fully biodegrade. The results are promising and suggest that future research should focus on enhancing the properties of these films to expand the range of possible applications.
Sign in to start a discussion.
More Papers Like This
Utilizing the Antioxidant Properties of Coffee By-Products to Stabilize Bioplastics
This study developed bioplastic films stabilized with antioxidants from coffee production byproducts, improving their resistance to oxidation and light degradation. Bioplastics that resist premature degradation while remaining fully biodegradable are important for reducing microplastic generation from compostable packaging.
Utilization of spent coffee grounds as fillers to prepare polypropylene composites for food packaging applications
Researchers used waste coffee grounds as filler material in polypropylene plastic composites to improve sustainability and reduce reliance on virgin plastic. Adding natural biomass waste to plastic formulations can reduce the total plastic content in consumer products, though the composites still produce microplastic fragments during use.
Valorization of Cork Stoppers, Coffee-Grounds and Walnut Shells in the Development and Characterization of Pectin-Based Composite Films: Physical, Barrier, Antioxidant, Genotoxic, and Biodegradation Properties
Researchers developed biodegradable composite films using pectin combined with waste materials from cork stoppers, coffee grounds, and walnut shells as a sustainable alternative to plastic packaging. The films showed antioxidant properties, were non-genotoxic, and biodegraded effectively in both soil and seawater within weeks. The study demonstrates that food industry and agricultural waste can be repurposed into functional, environmentally friendly packaging materials.
Low-Quality Coffee Beans Used as a Novel Biomass Source of Cellulose Nanocrystals: Extraction and Application in Sustainable Packaging
Researchers developed bio-based methylcellulose films reinforced with cellulose nanocrystals (CNCs) extracted from low-quality coffee beans as a sustainable alternative to petroleum-based plastic food packaging. The extracted CNCs showed needle-like morphology (~221 nm length), 65.75% crystallinity, and good thermal stability, providing a promising path to reduce microplastic accumulation in food chains.
Extraction and Application in Sustainable Packaging
Researchers developed bio-based methylcellulose films reinforced with cellulose nanocrystals (CNCs) extracted from low-quality coffee beans as a sustainable alternative to petroleum-based plastic food packaging. The extracted CNCs showed needle-like morphology (~221 nm length), 65.75% crystallinity, and good thermal stability, providing a promising path to reduce microplastic accumulation in trophic chains.