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Impact of accelerated weathering on the leaching kinetics of stabiliser additives from microplastics

Journal of Hazardous Materials 2023 48 citations

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Researchers studied how environmental weathering affects the release of chemical additives from microplastics and found that the results varied widely depending on the type of plastic and additive. Contrary to common assumptions, weathering did not always increase chemical leaching; in fact, it only significantly changed release rates for three out of nine formulations tested. This means the health risks from microplastic additives are more complex than previously thought, as different plastic types behave very differently in the environment.

The release of additives from microplastics is known to harm organisms. In the environment, microplastics are exposed to weathering processes which are suspected to influence additive leaching kinetics, the extent and mechanism of which remain poorly understood. We examined the impact of weathering on stabiliser additive leaching kinetics using environmentally relevant accelerated weathering and leaching procedures. Nine binary polymer-additive formulations were specifically prepared, weathered, analysed, and evaluated for their leaching characteristics. Cumulative additive release (Ce) varied widely between formulations, ranging from 0.009 to 1162 µg/g. Values of Ce generally increased by polymer type in the order polyethylene terephthalate < polyamide 6 < polyethylene. The change in leaching kinetics after accelerated weathering was incongruous across the nine formulations, with a significant change in Ce only observed for three out of nine formulations. Physicochemical characterisation of the microplastics demonstrated that additive blooming was the primary mechanism influencing the leaching response to weathering. These findings highlight the dependency of additive fate on the polymer type, additive chemistry, and the extent of weathering exposure. This has significant implications for risk assessment and mitigation, where the general assumption that polymer weathering increases additive leaching may be too simplistic.

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