Transport of polystyrene nanoplastics with different functional groups in goethite-coated saturated porous media: Effects of low molecular weight organic acids and physicochemical properties

The influence of low molecular weight organic acids (LMWOAs) and goethite on the migration of nanoplastics in the soil environment remains poorly understood. To elucidate the mechanism of influence, the study investigated the impact of LMWOAs on the migration ability of functionalized polystyrene nanoplastics (PSNPs-NH/COOH) in quartz sand (QS) and goethite (α-FeOOH)-coated quartz sand (FOS). We investigated the effect of changes in iron valence induced by LMWOAs on the migration of PSNPs. The results revealed that the migration ability of polystyrene nanoplastics (PSNPs) declined as the ionic strength (IS) increased and the pH decreased, primarily due to the compression of the double layer and protonation reactions. The migration of PSNPs is facilitated by LMWOAs through distinct mechanisms in the two media. Specifically, LMWOAs were adsorbed on the FOS and QS surfaces through complexation and hydrogen bonding, respectively. At pH 4.0, LMWOAs exhibit redox activity, resulting in the generation of additional Fe(III). This redox process enhances the electrostatic attraction between the media and PSNPs, thereby reducing the competition at specific points and spatial resistance associated with LMWOAs. In contrast to FOS, LMWOAs at pH 4.0 reduced the migration ability of PSNPs in QS, following the trend of MA > TA > CA. This difference was attributed to the pKa of LMWOAs and the weak hydrogen bonding on the QS surface. The relevant mathematical models effectively validate the migration results. The above conclusions suggest that LMWOAs can alter the valence state of iron on the surface of goethite, thereby influencing the migration of plastic particles in environmental media.